Electrochemical force microscopy
Abstract
A system and method for electrochemical force microscopy are provided. The system and method are based on a multidimensional detection scheme that is sensitive to forces experienced by a biased electrode in a solution. The multidimensional approach allows separation of fast processes, such as double layer charging, and charge relaxation, and slow processes, such as diffusion and faradaic reactions, as well as capturing the bias dependence of the response. The time-resolved and bias measurements can also allow probing both linear (small bias range) and non-linear (large bias range) electrochemical regimes and potentially the de-convolution of charge dynamics and diffusion processes from steric effects and electrochemical reactivity.
- Inventors:
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1338917
- Patent Number(s):
- 9,541,576
- Application Number:
- 14/810,605
- Assignee:
- UT-Battelle, LLC (Oak Ridge, TN)
- DOE Contract Number:
- AC05-00OR22725
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Jul 28
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Kalinin, Sergei V., Jesse, Stephen, Collins, Liam F., and Rodriguez, Brian J. Electrochemical force microscopy. United States: N. p., 2017.
Web.
Kalinin, Sergei V., Jesse, Stephen, Collins, Liam F., & Rodriguez, Brian J. Electrochemical force microscopy. United States.
Kalinin, Sergei V., Jesse, Stephen, Collins, Liam F., and Rodriguez, Brian J. 2017.
"Electrochemical force microscopy". United States. https://www.osti.gov/servlets/purl/1338917.
@article{osti_1338917,
title = {Electrochemical force microscopy},
author = {Kalinin, Sergei V. and Jesse, Stephen and Collins, Liam F. and Rodriguez, Brian J.},
abstractNote = {A system and method for electrochemical force microscopy are provided. The system and method are based on a multidimensional detection scheme that is sensitive to forces experienced by a biased electrode in a solution. The multidimensional approach allows separation of fast processes, such as double layer charging, and charge relaxation, and slow processes, such as diffusion and faradaic reactions, as well as capturing the bias dependence of the response. The time-resolved and bias measurements can also allow probing both linear (small bias range) and non-linear (large bias range) electrochemical regimes and potentially the de-convolution of charge dynamics and diffusion processes from steric effects and electrochemical reactivity.},
doi = {},
url = {https://www.osti.gov/biblio/1338917},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 10 00:00:00 EST 2017},
month = {Tue Jan 10 00:00:00 EST 2017}
}
Works referenced in this record:
Electrochemical identification of molecules in a scanning probe microscope
patent, February 1996
- Lindsay, Stuart; Jing, Tianwei
- US Patent Document 5,495,109
Scanning probe potentiometer
patent, December 1999
- Manalis, Scott; Minne, Stephen C.; Quate, Calvin F.
- US Patent Document 6,002,131
Method for analyzing sample in liquid
patent, October 2011
- Ota, Masahiro; Oyabu, Noriaki; Adachi, Hiroaki
- US Patent Document 8,037,739
Bias-Dependent Molecular-Level Structure of Electrical Double Layer in Ionic Liquid on Graphite
journal, November 2013
- Black, Jennifer M.; Walters, Deron; Labuda, Aleksander
- Nano Letters, Vol. 13, Issue 12, p. 5954-5960
Double Layer Structure of Ionic Liquids at the Au(111) Electrode Interface: An Atomic Force Microscopy Investigation
journal, March 2011
- Hayes, Robert; Borisenko, Natalia; Tam, Matthew K.
- The Journal of Physical Chemistry C, Vol. 115, Issue 14, p. 6855-6863
Atomic force microscopy of local compliance at solid—liquid interfaces
journal, June 1994
- O'Shea, S. J.; Welland, M. E.; Pethica, J. B.
- Chemical Physics Letters, Vol. 223, Issue 4, p. 336-340
In situ electrochemical studies of lithium-ion battery cathodes using atomic force microscopy
journal, March 2014
- Ramdon, Sanjay; Bhushan, Bharat; Nagpure, Shrikant C.
- Journal of Power Sources, Vol. 249, p. 373-384
Time Resolved in Situ Liquid Atomic Force Microscopy and Simultaneous Acoustic Impedance Electrochemical Quartz Crystal Microbalance Measurements: A Study of Zn Deposition
journal, October 2009
- Smith, Emma L.; Barron, John C.; Abbott, Andrew P.
- Analytical Chemistry, Vol. 81, Issue 20, p. 8466-8471