Graphene-supported metal oxide monolith

Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; Biener, Monika A.; Wang, Yinmin; Ye, Jianchao; Tylski, Elijah

Title: Graphene-supported metal oxide monolith

Patent · Tue Jan 10 00:00:00 EST 2017

OSTI ID:1338586

Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; Biener, Monika A.; Wang, Yinmin; Ye, Jianchao; Tylski, Elijah

A composition comprising at least one graphene-supported metal oxide monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds, wherein the graphene sheets are coated by at least one metal oxide such as iron oxide or titanium oxide. Also provided is an electrode comprising the aforementioned graphene-supported metal oxide monolith, wherein the electrode can be substantially free of any carbon-black and substantially free of any binder.

View Patent

Cite

Export

Save

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC52-07NA27344

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

Patent Number(s):: 9,543,569

Application Number:: 13/844,175

OSTI ID:: 1338586

Resource Relation:: Patent File Date: 2013 Mar 15

Country of Publication:: United States

Language:: English

References (57)

Process for preparing monoliths of aerogels of metal oxides Cogliati, Guido; Bezzi, Giovanni https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5207814 US Patent Document 5,207,814	patent	May 1993
Method of manufacturing aerogel composites Cao, Wanqing; Hunt, Arlon J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5879744 US Patent Document 5,879,744	patent	March 1999
Chemical composition Jadesjo, Gunilla; Jonsson, Gustav https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5885953 US Patent Document 5,885,953	patent	March 1999
Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel Struthers, Ralph C.; Chang, David B.; Toossi, Reza https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7378188 US Patent Document 7,378,188	patent	May 2008
Aerogel and xerogel composites for use as carbon anodes Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7410718 US Patent Document 7,410,718	patent	August 2008
Aerogel and xerogel composites for use as carbon anodes Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7811711 US Patent Document 7,811,711	patent	October 2010
Graphene and graphene oxide aerogels Wang, Jian; Ellsworth, Mark W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100144904 US Patent Application 12/315701; 20100144904	patent-application	June 2010
Mechanically Robust, Electrically Conductive Ultralow-Density Carbon Nanotude-Based Aerogels Worsley, Marcus A.; Kucheyev, Sergei O.; Baumann, Theodore F. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100187484 US Patent Application 12/652616; 20100187484	patent-application	July 2010
Process for the Continuous Production of a Catalyst Scheab, Ekkehard; Kotrel, Stefan; Panchenko, Alexander https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110177938 US Patent Application 13/061040; 20110177938	patent-application	July 2011
Carbon Nanotube or Graphene-based Aerogels Zhai, Lei; Zou, Jianhua https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110224376 US Patent Application 13/048040; 20110224376	patent-application	September 2011
Graphene Aerogels Pauzauskie, Peter; Worsley, Marcus; Baumann, Theodore https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120034442 US Patent Application 13/204277; 20120034442	patent-application	February 2012
Interpenetrating Networks Of Carbon Nanostructures And Nano-Scale Electroactive Materials Gruner, George; Duan, Xiangfeng; Dunn, Bruce https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140042390 US Patent Application 13/963973; 20140042390	patent-application	February 2014
Aerogel Based On Doped Graphene Schwab, Matthias; Muellen, Klaus; Feng, Xinliang https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150030968 US Patent Application 14/384095; 20150030968	patent-application	January 2015
Modular Bioelectrochemical Systems and Methods Ren, Zhiyong; Forrestal, Casey; Xu, Pei https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150064501 US Patent Application 14/345104; 20150064501	patent-application	March 2015
Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels Al-Muhtaseb, S. A.; Ritter, J. A. Advanced Materials, Vol. 15, Issue 2, p. 101-114 https://doi.org/10.1002/adma.200390020	journal	January 2003
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
Superior Thermal Conductivity of Single-Layer Graphene Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong Nano Letters, Vol. 8, Issue 3, p. 902-907 https://doi.org/10.1021/nl0731872	journal	March 2008
Raman validity for crystallite size L_a determination on reticulated vitreous carbon with different graphitization index Baldan, M. R.; Almeida, E. C.; Azevedo, A. F. Applied Surface Science, Vol. 254, Issue 2, p. 600-603 https://doi.org/10.1016/j.apsusc.2007.06.038	journal	November 2007
Carbon 1s near-edge-absorption fine structure in graphite Batson, P. E. Physical Review B, Vol. 48, Issue 4, p. 2608-2610 https://doi.org/10.1103/PhysRevB.48.2608	journal	July 1993
Facile Synthesis of a Crystalline, High-Surface-Area SnO₂ Aerogel Baumann, T. F.; Kucheyev, S. O.; Gash, A. E. Advanced Materials, Vol. 17, Issue 12, p. 1546-1548 https://doi.org/10.1002/adma.200500074	journal	June 2005
Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition Chen, Zongping; Ren, Wencai; Gao, Libo Nature Materials, Vol. 10, Issue 6, p. 424-428 https://doi.org/10.1038/nmat3001	journal	April 2011
Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite Cote, Laura J.; Cruz-Silva, Rodolfo; Huang, Jiaxing Journal of the American Chemical Society, Vol. 131, Issue 31, p. 11027-11032 https://doi.org/10.1021/ja902348k	journal	August 2009
Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material Eda, Goki; Fanchini, Giovanni; Chhowalla, Manish Nature Nanotechnology, Vol. 3, Issue 5, p. 270-274 https://doi.org/10.1038/nnano.2008.83	journal	April 2008
Interpretation of Raman spectra of disordered and amorphous carbon Ferrari, A. C.; Robertson, J. Physical Review B, Vol. 61, Issue 20, p. 14095-14107 https://doi.org/10.1103/PhysRevB.61.14095	journal	May 2000
Raman Spectrum of Graphene and Graphene Layers Ferrari, A. C.; Meyer, J. C.; Scardaci, V. Physical Review Letters, Vol. 97, Issue 18, Article No. 187401 https://doi.org/10.1103/PhysRevLett.97.187401	journal	October 2006
Strong Akaganeite Aerogel Monoliths Using Epoxides: Synthesis and Characterization Gash, Alexander E.; Satcher, Joe H.; Simpson, Randall L. Chemistry of Materials, Vol. 15, Issue 17, p. 3268-3275 https://doi.org/10.1021/cm034211p	journal	August 2003
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
Extremely high thermal conductivity of graphene: Prospects for thermal management applications in silicon nanoelectronics Balandin, A.; Ghosh, S.; Teweldebrhan, D. https://doi.org/10.1109/SNW.2008.5418404	conference	June 2008
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene Graf, D.; Molitor, F.; Ensslin, K. Nano Letters, Vol. 7, Issue 2, p. 238-242 https://doi.org/10.1021/nl061702a	journal	February 2007
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Carrier Transport in Two-Dimensional Graphene Layers Hwang, E. H.; Adam, S.; Sarma, S. Das Physical Review Letters, Vol. 98, Issue 18, Article No. 186806 https://doi.org/10.1103/PhysRevLett.98.186806	journal	May 2007
Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe₂O₃Compound Jain, Gaurav; Balasubramanian, Mahalingam; Xu, Jun John Chemistry of Materials, Vol. 18, Issue 2, p. 423-434 https://doi.org/10.1021/cm052014f	journal	January 2006
Depth-sensing indentation of low-density brittle nanoporous solids Kucheyev, S. O.; Hamza, A. V.; Satcher Jr., J. H. Acta Materialia, Vol. 57, Issue 12, p. 3472-3480 https://doi.org/10.1016/j.actamat.2009.04.003	journal	July 2009
In situ infrared observation of the pyrolysis process of carbon aerogels Kuhn, J.; Brandt, R.; Mehling, H. Journal of Non-Crystalline Solids, Vol. 225, p. 58-63 https://doi.org/10.1016/S0022-3093(98)00009-X	journal	April 1998
On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential Laruelle, S.; Grugeon, S.; Poizot, P. Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634 https://doi.org/10.1149/1.1467947	journal	January 2002
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Lee, C.; Wei, X.; Kysar, J. W. Science, Vol. 321, Issue 5887, p. 385-388 https://doi.org/10.1126/science.1157996	journal	July 2008
Highly conducting graphene sheets and Langmuir–Blodgett films Li, Xiaolin; Zhang, Guangyu; Bai, Xuedong Nature Nanotechnology, Vol. 3, Issue 9, p. 538-542 https://doi.org/10.1038/nnano.2008.210	journal	August 2008
A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films Liu, Fei; Seo, Tae Seok Advanced Functional Materials, Vol. 20, Issue 12, p. 1930-1936 https://doi.org/10.1002/adfm.201000287	journal	May 2010
Thermal and electrical conductivity of monolithic carbon aerogels Lu, Xianping; Nilsson, Ove; Fricke, Jochen Journal of Applied Physics, Vol. 73, Issue 2, p. 581-584 https://doi.org/10.1063/1.353367	journal	January 1993
Core excitons and vibronic coupling in diamond and graphite Ma, Y.; Skytt, P.; Wassdahl, N. Physical Review Letters, Vol. 71, Issue 22, p. 3725-3728 https://doi.org/10.1103/PhysRevLett.71.3725	journal	November 1993
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H. Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404 https://doi.org/10.1021/cm0630800	journal	September 2007
Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells Morales, Julian; Sanchez, Luis; Martin, Francisco Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1748-A1754 https://doi.org/10.1149/1.1972812	journal	January 2005
Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer Morozov, S. V.; Novoselov, K. S.; Katsnelson, M. I. Physical Review Letters, Vol. 100, Issue 1, Article No. 016602 https://doi.org/10.1103/PhysRevLett.100.016602	journal	January 2008
Electric Field Effect in Atomically Thin Carbon Films Novoselov, K. S. Science, Vol. 306, Issue 5696, p. 666-669 https://doi.org/10.1126/science.1102896	journal	October 2004
An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments Oliver, W. C.; Pharr, G. M. Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583 https://doi.org/10.1557/JMR.1992.1564	journal	June 1992
Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene Pacile, D.; Papagno, M.; Rodríguez, A. Fraile Physical Review Letters, Vol. 101, Issue 6, Article No. 066806 https://doi.org/10.1103/PhysRevLett.101.066806	journal	August 2008
Specific surface area of carbon nanotubes and bundles of carbon nanotubes Peigney, A.; Laurent, Ch.; Flahaut, E. Carbon, Vol. 39, Issue 4, p. 507-514 https://doi.org/10.1016/S0008-6223(00)00155-X	journal	April 2001
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries Poizot, P.; Laruelle, S.; Grugeon, S. Nature, Vol. 407, Issue 6803, p. 496-499 https://doi.org/10.1038/35035045	journal	September 2000
Functionalized graphene sheets for polymer nanocomposites Ramanathan, T.; Abdala, A. A.; Stankovich, S. Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331 https://doi.org/10.1038/nnano.2008.96	journal	May 2008
Detection of individual gas molecules adsorbed on graphene Schedin, F.; Geim, A. K.; Morozov, S. V. Nature Materials, Vol. 6, Issue 9, p. 652-655 https://doi.org/10.1038/nmat1967	journal	July 2007
Graphene Based Electrochemical Sensors and Biosensors: A Review Shao, Yuyan; Wang, Jun; Wu, Hong Electroanalysis, Vol. 22, Issue 10, p. 1027-1036 https://doi.org/10.1002/elan.200900571	journal	March 2010
High surface area carbon nanotube-supported titanium carbonitride aerogels Worsley, Marcus A.; Kuntz, Joshua D.; Pauzauskie, Peter J. Journal of Materials Chemistry, Vol. 19, Issue 31, p. 5503-5506 https://doi.org/10.1039/B908284K	journal	January 2009
Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation Wu, Zhong-Shuai; Ren, Wencai; Gao, Libo ACS Nano, Vol. 3, Issue 2, p. 411-417 https://doi.org/10.1021/nn900020u	journal	February 2009
Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process Xu, Yuxi; Sheng, Kaixuan; Li, Chun ACS Nano, Vol. 4, Issue 7, p. 4324-4330 https://doi.org/10.1021/nn101187z	journal	July 2010
Assembly of Graphene Sheets into 3D Macroscopic Structures Yin, Shengyan; Niu, Zhiqiang; Chen, Xiaodong Small, Vol. 8, Issue 16, p. 2458-2463 https://doi.org/10.1002/smll.201102614	journal	May 2012
Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji Nano Letters, Vol. 8, Issue 8, p. 2277-2282 https://doi.org/10.1021/nl800957b	journal	August 2008
Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel Zu, Sheng-Zhen; Han, Bao-Hang The Journal of Physical Chemistry C, Vol. 113, Issue 31, p. 13651-13657 https://doi.org/10.1021/jp9035887	journal	August 2009

Similar Records

High-density 3D graphene-based monolith and related materials, methods, and devices

Patent · Tue Mar 21 00:00:00 EDT 2017 · OSTI ID:1338586

Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; +5 more

High surface area graphene-supported metal chalcogenide assembly

Patent · Tue Apr 19 00:00:00 EDT 2016 · OSTI ID:1338586

Worsley, Marcus A.; Kuntz, Joshua; Orme, Christine A.

High surface area graphene-supported metal chalcogenide assembly

Patent · Tue Apr 25 00:00:00 EDT 2017 · OSTI ID:1338586

Worsley, Marcus A.; Kuntz, Joshua D.; Orme, Christine A.

Related Subjects

36 MATERIALS SCIENCE

Title: Graphene-supported metal oxide monolith

Citation Formats

References (57)

Similar Records

Related Subjects