Calcium-Iron Oxide as Energy Storage Medium in Rechargeable Oxide Batteries

Berger, Cornelius M.; Mahmoud, Abdelfattah; Hermann, Raphaël P.; Braun, Waldemar; Yazhenskikh, Elena; Sohn, Yoo Jung; Menzler, Norbert H.; Guillon, Olivier; Bram, Martin

doi:10.1111/jace.14439

Title: Calcium-Iron Oxide as Energy Storage Medium in Rechargeable Oxide Batteries

Journal Article · Mon Aug 08 00:00:00 EDT 2016 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.14439· OSTI ID:1338567

Berger, Cornelius M. ^[1]; Mahmoud, Abdelfattah ^[2]; Hermann, Raphaël P. ^[3]; Braun, Waldemar ^[4]; Yazhenskikh, Elena ^[4]; Sohn, Yoo Jung ^[1]; Menzler, Norbert H. ^[1]; Guillon, Olivier ^[1]; Bram, Martin ^[1]

Forschungszentrum Julich GmbH, Julich (Germany). Inst. of Energy and Climate Research (IEK); Julich-Aachen Research Alliance (JARA), Julich (Germany)
Forschungszentrum Julich GmbH, Julich (Germany). Julich Centre for Neutron Science (JCNS). Peter Grunberg Inst. (PGI); Liege Univ. (Belgium). LCIS/GREENMAT. Inst. of Chemistry
Forschungszentrum Julich GmbH, Julich (Germany). Julich Centre for Neutron Science (JCNS). Peter Grunberg Inst. (PGI); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Forschungszentrum Julich GmbH, Julich (Germany). Inst. of Energy and Climate Research (IEK)

Rechargeable oxide batteries (ROB) comprise a regenerative solid oxide cell (rSOC) and a storage medium for oxygen ions. A sealed ROB avoids pumping loss, heat loss, and gas purity expenses in comparison with conventional rSOC. However, the iron oxide base storage medium degrades during charging–discharging cycles. In comparison, CaFe₃O₅ has improved cyclability and a high reversible oxygen storage capacity of 22.3 mol%. In this paper, we analyzed the redox mechanism of this compound. After a solid-state synthesis of CaFe₃O₅, we verified the phase composition and studied the redox reaction by means of X-ray diffraction, Mössbauer spectrometry, and scanning electron microscopy. Finally, results show a great potential to operate the battery with this storage material during multiple charging–discharging cycles.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Forschungszentrum Julich GmbH, Julich (Germany); Julich-Aachen Research Alliance (JARA), Julich (Germany)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); German Federal Ministry of Education and Research (BMBF)

Contributing Organization:: Liege Univ. (Belgium)

Grant/Contract Number:: AC05-00OR22725; 03EK3017

OSTI ID:: 1338567

Journal Information:: Journal of the American Ceramic Society, Vol. 99, Issue 12; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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Single phase charge ordered stoichiometric CaFe3O5 with commensurate and incommensurate trimeron ordering Cassidy, Simon J.; Orlandi, Fabio; Manuel, Pascal Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13450-5	journal	December 2019

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