Quasicrystals at extreme conditions: The role of pressure in stabilizing icosahedral Al63Cu24Fe13 at high temperature
- Carnegie Institution of Washington, Washington, D.C. (United States); Ehime Univ., Matsuyama (Japan); Tokyo Institute of Technology, Tokyo (Japan)
- Univ. di Firenze, Florence (Italy)
- Carnegie Inst. of Washington, Argonne, IL (United States)
- The Univ. of Chicago, Chicago, IL (United States)
- Carnegie Institution of Washington, Washington, D.C. (United States); Center for High Pressure Science and Technology Advanced Research, Shanghai (People's Republic of China)
- Carnegie Institution of Washington, Washington, D.C. (United States)
- Princeton Univ., Princeton, NJ (United States)
Icosahedrite, the first natural quasicrystal with composition Al63Cu24Fe13, was discovered in several grains of the Khatyrka meteorite, a unique CV3 carbonaceous chondrite. The presence in the meteorite fragments of icosahedrite strictly associated with high-pressure phases like ahrensite and stishovite indicates a formation conditions at high pressures and temperatures, likely during an impact-induced shock occurred in contact with the reducing solar nebula gas. In contrast, previous experimental studies on the stability of synthetic icosahedral AlCuFe, which were limited to ambient pressure, indicated incongruent melting at ~1123 K, while high-pressure experiments carried out at room temperature showed structural stability up to about 35 GPa. These data are insufficient to experimentally constrain the formation and stability of icosahedrite under extreme conditions. Here we present the results of in situ high pressure experiments using diamond anvil cells of the compressional behavior of synthetic icosahedrite up to ~50 GPa at room temperature. Simultaneous high P-T experiments have been also carried out using both laser-heated diamond anvil cells combined with in situ synchrotron X-ray diffraction (at ~42 GPa) and multi-anvil apparatus (at 21 GPa) to investigate the structural evolution of icosahedral Al63Cu24Fe13 and crystallization of possible coexisting phases. The results demonstrate that the quasiperiodic symmetry of icosahedrite is retained over the entire experimental pressure range explored. In addition, we show that pressure acts to stabilize the icosahedral symmetry at temperatures much higher than previously reported. Based on our experimental study, direct crystallization of Al-Cu-Fe quasicrystals from an unusual Al-Cu-rich melt would be possible but limited to a narrow temperature range beyond which crystalline phases would form, like those observed in the Khatyrka meteorite. Here, an alternative mechanism would consist in late formation of the quasicrystal after crystallization and solid-solid reaction of Al-rich phases. In both cases, linking our results with observations in nature, quasicrystals are expected to preserve their structure even after hypervelocity impacts that involve simultaneous high pressures and temperatures, thus proving their cosmic stability.
- Research Organization:
- Carnegie Institution of Washington, Washington, D.C. (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)
- Sponsoring Organization:
- USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- NA0002006; SC0001057
- OSTI ID:
- 1335512
- Journal Information:
- American Mineralogist, Vol. 100, Issue 11-12; ISSN 0003-004X
- Publisher:
- Mineralogical Society of AmericaCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
Previously unknown quasicrystal periodic approximant found in space
|
journal | November 2018 |
A unique CO-like micrometeorite hosting an exotic Al-Cu-Fe-bearing assemblage – close affinities with the Khatyrka meteorite
|
journal | August 2019 |
Collisions in outer space produced an icosahedral phase in the Khatyrka meteorite never observed previously in the laboratory
|
journal | December 2016 |
Evidence of cross-cutting and redox reaction in Khatyrka meteorite reveals metallic-Al minerals formed in outer space
|
journal | May 2017 |
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