Conversion of alkanes to organoseleniums and organotelluriums
Patent
·
OSTI ID:1333819
The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.
- Research Organization:
- The Scripps Research Inst., La Jolla, CA (United States)
- Sponsoring Organization:
- USDOE
- Assignee:
- The Scripps Research Institute (La Jolla, CA)
- Patent Number(s):
- 9,505,714
- Application Number:
- 14/910,275
- OSTI ID:
- 1333819
- Resource Relation:
- Patent File Date: 2014 Aug 06
- Country of Publication:
- United States
- Language:
- English
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