Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries

Asakura, Daisuke; Hosono, Eiji; Nanba, Yusuke; Zhou, Haoshen; Okabayashi, Jun; Ban, Chunmei; Glans, Per -Anders; Guo, Jinghua; Mizokawa, Takashi; Chen, Gang; Achkar, Andrew J.; Hawthron, David G.; Regier, Thomas Z.; Wadati, Hiroki

doi:10.1063/1.4943673

Title: Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries

Journal Article · Mon Mar 07 00:00:00 EST 2016 · AIP Advances

DOI:https://doi.org/10.1063/1.4943673· OSTI ID:1329991

Asakura, Daisuke ^[1]; Hosono, Eiji ^[1]; Nanba, Yusuke ^[2]; Zhou, Haoshen ^[1]; Okabayashi, Jun ^[3]; Ban, Chunmei ^[4]; Glans, Per -Anders ^[5]; Guo, Jinghua ^[6]; Mizokawa, Takashi ^[7]; Chen, Gang ^[8]; Achkar, Andrew J. ^[9];

^[9]; Regier, Thomas Z. ^[10]; Wadati, Hiroki ^[11]

National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan)
National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan); Kyushu Univ., Fukuoka (Japan)
The Univ. of Tokyo, Tokyo (Japan)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Santa Cruz, CA (United States)
The Univ. of Tokyo, Chiba (Japan); Waseda Univ., Tokyo (Japan)
Jilin Univ., Changchun (People's Republic of China)
Univ. of Waterloo, Waterloo, ON (Canada)
Univ. of Saskatchewan, Saskatoon, SK (Canada)
The Univ. of Tokyo, Chiba (Japan)

© 2016 Author(s). We evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathode materials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi 0.5 Mn 1.5 O 4 , the line shape of the Mn L 3 -edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the Ni L 3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathode materials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are useful enough for the Ni L edge which is far from the O K edge.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: NREL Laboratory Directed Research and Development (LDRD); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308; AC02-05CH11231

OSTI ID:: 1329991

Alternate ID(s):: OSTI ID: 1378978

Report Number(s):: NREL/JA-5900-67327; AAIDBI

Journal Information:: AIP Advances, Vol. 6, Issue 3; ISSN 2158-3226

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 41 works

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Title: Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries

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