Transforming MOFs for energy applications using the guest@MOF concept

Ullman, Andrew M.; Brown, Jonathan W.; Foster, Michael E.; Leonard, Francois; Leong, Kirsty; Stavila, Vitalie; Allendorf, Mark D.

doi:10.1021/acs.inorgchem.6b00909

Title: Transforming MOFs for energy applications using the guest@MOF concept

Journal Article · Mon Jul 11 00:00:00 EDT 2016 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.6b00909· OSTI ID:1329627

Ullman, Andrew M. ^[1]; Brown, Jonathan W. ^[1]; Foster, Michael E. ^[1]; Leonard, Francois ^[1]; Leong, Kirsty ^[1]; Stavila, Vitalie ^[1]; Allendorf, Mark D. ^[1]

Sandia National Lab. (SNL-CA), Livermore, CA (United States)

As the world transitions from fossil fuels to clean energy sources in the coming decades, many technological challenges will require chemists and material scientists to develop new materials for applications related to energy conversion, storage, and efficiency. Because of their unprecedented adaptability, metal–organic frameworks (MOFs) will factor strongly in this portfolio. By utilizing the broad synthetic toolkit provided by the fields of organic and inorganic chemistry, MOF pores can be customized to suit a particular application. Of particular importance is the ability to tune the strength of the interaction between the MOF pores and guest molecules. By cleverly controlling these MOF–guest interactions, the chemist may impart new function into the Guest@MOF materials otherwise lacking in vacant MOF. Herein, we highlight the concept of the Guest@MOF as it relates to our efforts to develop these materials for energy-related applicatons. Additionally, our work in the areas of H₂ and noble gas storage, hydrogenolysis of biomass, light-harvesting, and conductive materials will be discussed. Of relevance to light-harvesting applications, we report for the first time a postsynthetic modification strategy for increasing the loading of a light-sensitive electron-donor molecule in the pores of a functionalized MIL-101 structure. Through the demonstrated versatility of these approaches, we show that, by treating guest molecules as integral design elements for new MOF constructs, MOF science can have a significant impact on the advancement of clean energy technologies.

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Research Organization:: Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1329627

Report Number(s):: SAND-2016-10197J; 648198

Journal Information:: Inorganic Chemistry, Vol. 55, Issue 15; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 62 works

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