High Pressure Properties of a Ba-Cu-Zn-P Clathrate-I

Dolyniuk, Juli -Anna; Kovnir, Kirill

doi:10.3390/ma9080692

Title: High Pressure Properties of a Ba-Cu-Zn-P Clathrate-I

Journal Article · Fri Aug 12 00:00:00 EDT 2016 · Materials

DOI:https://doi.org/10.3390/ma9080692· OSTI ID:1326102

Dolyniuk, Juli -Anna ^[1]; Kovnir, Kirill ^[1]

Univ. of California, Davis, CA (United States)

Here, the high pressure properties of the novel tetrel-free clathrate, Ba₈Cu_13.1Zn_3.3P_29.6, were investigated using synchrotron powder X-ray diffraction. The pressure was applied using a diamond anvil cell. No structural transitions or decomposition were detected in the studied pressure range of 0.1–7 GPa. The calculated bulk modulus for Ba₈Cu_13.1Zn_3.3P_29.6 using a third-order Birch-Murnaghan equation of state is 65(6) GPa at 300 K. This bulk modulus is comparable to the bulk moduli of Ge- and Sn-based clathrates, like A₈Ga₁₆Ge₃₀ (A = Sr, Ba) and Sn_19.3Cu_4.7P₂₂I₈, but lower than those for the transition metal-containing silicon-based clathrates, Ba₈T_xSi46–x, T = Ni, Cu; 3 ≤ x ≤ 5.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1326102

Journal Information:: Materials, Vol. 9, Issue 8; ISSN 1996-1944

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 2 works

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clathrate
high pressure
powder X-ray diffraction
bulk modulus

Title: High Pressure Properties of a Ba-Cu-Zn-P Clathrate-I

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