Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4

Poudel, N.; Lorenz, B.; Lv, B.; Wang, Y. Q.; Ye, F.; Wang, Jinchen; Fernandez-baca, J. A.; Chu, C. W.

doi:10.1080/10584587.2015.1102565

Title: Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO ₄

Journal Article · Tue Dec 15 00:00:00 EST 2015 · Integrated Ferroelectrics

DOI:https://doi.org/10.1080/10584587.2015.1102565· OSTI ID:1324156

Poudel, N. ^[1]; Lorenz, B. ^[1]; Lv, B. ^[1]; Wang, Y. Q. ^[1]; Ye, F. ^[2]; Wang, Jinchen ^[3]; Fernandez-baca, J. A. ^[4]; Chu, C. W. ^[5]

Univ. of Houston, TX (United States). Texas Center for Superconductivity and Dept. of Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Kentucky, Lexington, KY (United States). Center for Advanced Materials
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Kentucky, Lexington, KY (United States). Center for Advanced Materials; Renmin Univ. of China, Beijing (China). Dept. of Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy
Univ. of Houston, TX (United States). Texas Center for Superconductivity and Dept. of Physics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

There are various orders in multiferroic materials with a frustrated spiral spin modulation inducing a ferroelectric state are extremely sensitive to small perturbations such as magnetic and electric fields, external pressure, or chemical substitutions. A classical multiferroic, the mineral Hubnerite with chemical formula MnWO₄, shows three different magnetic phases at low temperature. The intermediate phase between 7.5K < T < 12.7K is multiferroic and ferroelectricity is induced by an inversion symmetry breaking spiral Mn-spin order and strong spin-lattice interactions. Furthermore, the substitution of Ni²⁺ (spin 1) for Mn²⁺ (spin 5/2) in MnWO₄ and its effects on the magnetic and multiferroic phases are studied. The ferroelectric phase is stabilized for low Ni content (up to 10%). Upon further Ni doping, the polarization in the ferroelectric phase is quickly suppressed while a collinear and commensurate magnetic phase, characteristic of the magnetic structure in NiWO₄, appears first at higher temperature, gradually extends to lower temperature, and becomes the ground state above 30% doping. Between 10% and 30%, the multiferroic phase coexists with the collinear commensurate phase. In this concentration region, the spin spiral plane is close to the a-b plane which explains the drop of the ferroelectric polarization. Finally, the phase diagram of Mn_1-xNi_xWO₄ is derived by a combination of magnetic susceptibility, specific heat, electric polarization, and neutron scattering measurements.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1324156

Journal Information:: Integrated Ferroelectrics, Vol. 166, Issue 1; ISSN 1058-4587

Publisher:: Taylor & FrancisCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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