Magnetic ordering-induced multiferroic behavior in [CH3NH3][Co(HCOO)3] metal-organic framework.

Gomez-Aguirre, Lilian Claudia; Zapf, Vivien S.; Pato-Doldan, Breogan; Mira, Jorge; Castro-Garcia, Socorro; Senaris-Rodriguez, Maria Antonia; Sanchez-Andujara, Manuel; Singleton, John

doi:10.1021/jacs.5b11688

Title: Magnetic ordering-induced multiferroic behavior in [CH₃NH₃][Co(HCOO)₃] metal-organic framework.

Journal Article · Wed Dec 30 00:00:00 EST 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b11688· OSTI ID:1296677

Gomez-Aguirre, Lilian Claudia ^[1]; Zapf, Vivien S. ^[2]; Pato-Doldan, Breogan ^[1]; Mira, Jorge ^[3]; Castro-Garcia, Socorro ^[1]; Senaris-Rodriguez, Maria Antonia ^[1]; Sanchez-Andujara, Manuel ^[1]; Singleton, John ^[2]

Univ. of Coruna, Coruna (Spain)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Santiago de Compostela, Santiago de Compostela (Spain)

Here, we present the first example of magnetic ordering-induced multiferroic behavior in a metal–organic framework magnet. This compound is [CH₃NH₃][Co(HCOO)₃] with a perovskite-like structure. The A-site [CH₃NH₃]⁺ cation strongly distorts the framework, allowing anisotropic magnetic and electric behavior and coupling between them to occur. This material is a spin canted antiferromagnet below 15.9 K with a weak ferromagnetic component attributable to Dzyaloshinskii–Moriya (DM) interactions and experiences a discontinuous hysteretic magnetic-field-induced switching along [010] and a more continuous hysteresis along [101]. Coupling between the magnetic and electric order is resolved when the field is applied along this [101]: a spin rearrangement occurs at a critical magnetic field in the ac plane that induces a change in the electric polarization along [101] and [10-1]. The electric polarization exhibits an unusual memory effect, as it remembers the direction of the previous two magnetic-field pulses applied. The data are consistent with an inverse-DM mechanism for multiferroic behavior.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1296677

Report Number(s):: LA-UR-15-28719

Journal Information:: Journal of the American Chemical Society, Vol. 138, Issue 4; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 156 works

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Theoretical investigation of multiferroic metal–organic framework magnet [CH ₃ NH ₃ ][Co(HCOO) ₃ ]: Green’s function method Li, Yin; Yao, Kailun Journal of Physics: Condensed Matter, Vol. 30, Issue 40 https://doi.org/10.1088/1361-648x/aadc80	journal	September 2018
Low-magnetic-field controlled magnetodielectric coupling at room temperature in a chiral layered diphenylalanine-based 1D-coordination-polymer Zhang, Jinlei; Wu, Shuyi; Zhu, Xiaobin Journal of Physics D: Applied Physics, Vol. 53, Issue 15 https://doi.org/10.1088/1361-6463/ab6bed	journal	February 2020
Magnetic layered perovskites of [CH ₃ C(NH ₂ ) ₂ ] ₂ [M(HCOO) ₄ ] (M = Co ²⁺ and Ni ²⁺ ): synthesis, structures and properties Liu, Shu; Wang, Bing-Wu; Wang, Zhe-Ming Dalton Transactions, Vol. 47, Issue 34 https://doi.org/10.1039/c8dt01729h	journal	January 2018
Pressure dependence of spin canting in ammonium metal formate antiferromagnets Collings, Ines; Manna, Rudra Sekhar; Tsirlin, Alexander A. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-00174	text	January 2018
Coupling of Magnetic and Elastic Domains in the Organic-Inorganic Layered Perovskite-Like (C ₆ H ₅ C ₂ H ₄ NH ₃ ) ₂ Fe ^II Cl ₄ Crystal Nakayama, Yuki; Nishihara, Sadafumi; Inoue, Katsuya Angewandte Chemie, Vol. 129, Issue 32 https://doi.org/10.1002/ange.201703898	journal	July 2017
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Disorder–order transitions in the perovskite metal–organic frameworks $[(CH_{3})_{2}NH_{2} ][M(HCOO)_{3}]$ at high pressure Collings, Ines; Bykov, Maxim; Bykova, Elena Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-00414	text	January 2018
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Giant barocaloric effect in the ferroic organic-inorganic hybrid [TPrA][Mn(dca)3] perovskite under easily accessible pressures Bermúdez-García, Juan M.; Sánchez-Andújar, Manuel; Castro-García, Socorro Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15715	journal	June 2017

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Title: Magnetic ordering-induced multiferroic behavior in [CH₃NH₃][Co(HCOO)₃] metal-organic framework.