Current Thoughts on Reactive Element Effects in Alumina-Forming Systems: In Memory of John Stringer

Naumenko, D.; Pint, B. A.; Quadakkers, W. J.

doi:10.1007/s11085-016-9625-0

Title: Current Thoughts on Reactive Element Effects in Alumina-Forming Systems: In Memory of John Stringer

Journal Article · Fri May 06 00:00:00 EDT 2016 · Oxidation of Metals

DOI:https://doi.org/10.1007/s11085-016-9625-0· OSTI ID:1279402

Naumenko, D. ^[1]; Pint, B. A. ^[2]; Quadakkers, W. J. ^[1]

Julich Research Centre (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

In memory of John Stringer (1934–2014), one of the leaders in studying the reactive element (RE) effects, this paper reviews the current status of understanding of the effect of RE dopants on high-temperature oxidation behavior, with an emphasis on recent research related to deploying alumina-forming alloys and coatings with optimal performance in commercial systems. Additionally, to the well-known interaction between indigenous sulfur and RE additions, effects have been observed with C, N, and O found in commercial alloys and coatings. While there are many similarities between alumina-forming alloys and coatings, the latter bring additional complicating factors such as the effects of O incorporation during thermal spraying MCrAlY coatings, coating roughness, and heat treatments that must be considered in optimizing the beneficial dopant addition. We can see analogies between RE effects in alloys and in the substrates beneath diffusion M–Al coatings. Recently, there has been more interest in the influence of mixed oxidant environments, since these may modify the manifestation of the RE effect. Some thoughts are provided on optimizing the RE benefit and modeling oxidation of RE-doped alloys.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office

Grant/Contract Number:: AC05-00OR22725; NA 615-2

OSTI ID:: 1279402

Journal Information:: Oxidation of Metals, Vol. 86, Issue 1-2; ISSN 0030-770X

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 149 works

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Interplay of water and reactive elements in oxidation of alumina-forming alloys Mortazavi, N.; Geers, C.; Esmaily, M. Nature Materials, Vol. 17, Issue 7 https://doi.org/10.1038/s41563-018-0105-6	journal	June 2018
Coupled oxidation resistance and thermal stability in sputter deposited nanograined alloys Shetty, Pralav P.; Emigh, Megan G.; Krogstad, Jessica A. Journal of Materials Research, Vol. 34, Issue 1 https://doi.org/10.1557/jmr.2018.403	journal	November 2018
The Effect of Ti on the Early Stages of Oxidation of an Alumina-Forming NiCrAl Alloy Barth, Talia L.; Marquis, Emmanuelle A. Oxidation of Metals, Vol. 92, Issue 1-2 https://doi.org/10.1007/s11085-019-09911-3	journal	May 2019
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