Multilayer graphane synthesized under high hydrogen pressure

Antonov, V. E.; Bashkin, I. O.; Bazhenov, A. V.; Bulychev, B. M.; Fedotov, V. K.; Fursova, T. N.; Kolesnikov, A. I.; Kulakov, V. I.; Lukashev, R. V.; Matveev, D. V.; Sakharov, M. K.; Shulga, Y. M.

doi:10.1016/j.carbon.2015.12.051

Title: Multilayer graphane synthesized under high hydrogen pressure

Journal Article · Sat Dec 19 00:00:00 EST 2015 · Carbon

DOI:https://doi.org/10.1016/j.carbon.2015.12.051· OSTI ID:1265908

Antonov, V. E. ^[1]; Bashkin, I. O. ^[1]; Bazhenov, A. V. ^[1]; Bulychev, B. M. ^[2]; Fedotov, V. K. ^[1]; Fursova, T. N. ^[1]; Kolesnikov, A. I. ^[3]; Kulakov, V. I. ^[1]; Lukashev, R. V. ^[4]; Matveev, D. V. ^[1]; Sakharov, M. K. ^[1]; Shulga, Y. M. ^[5]

Inst. of Solid State Physics, Moscow District (Russia)
Moscow State Univ., Moscow (Russian Federation)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Inst. of Problems of Chemical Physics RAS, Moscow District (Russia)
National Univ. of Science and Technology, Moscow (Russia)

A new hydrocarbon – hydrographite – with the composition close to CH is shown to form from graphite and gaseous hydrogen at pressures above 2 GPa and temperatures from 450 to 700 °C. Hydrographite is a black solid thermally stable under ambient conditions. When heated in vacuum, it decomposes into graphite and molecular hydrogen at temperatures from 500 to 650 °C. Powder X-ray diffraction characterizes hydrographite as a multilayer “graphane II” phase predicted by ab initio calculations [Wen X-D et al. PNAS 2011; 108:6833] and consisting of graphane sheets in the chair conformation stacked along the hexagonal c axis in the -ABAB- sequence. The crystal structure of the synthesized phase belongs to the P63mc space group. Moreover, the unit cell parameters are a = 2.53(1) Å and c = 9.54(1) Å and therefore exceed the corresponding parameters of graphite by 2.4(2)% and 42.0(3)%. Stretching vibrations of C–H groups on the surface of the hydrographite particles are examined by infrared spectroscopy.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; 11-02-00401

OSTI ID:: 1265908

Alternate ID(s):: OSTI ID: 1266404

Journal Information:: Carbon, Vol. 100, Issue C; ISSN 0008-6223

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 19 works

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Pressure-Induced Diels-Alder Reactions in C ₆ H ₆ -C ₆ F ₆ Cocrystal towards Graphane Structure Wang, Yajie; Dong, Xiao; Tang, Xingyu Angewandte Chemie International Edition, Vol. 58, Issue 5 https://doi.org/10.1002/anie.201813120	journal	January 2019
Emerging chemical strategies for imprinting magnetism in graphene and related 2D materials for spintronic and biomedical applications Tuček, Jiří; Błoński, Piotr; Ugolotti, Juri Chemical Society Reviews, Vol. 47, Issue 11 https://doi.org/10.1039/c7cs00288b	journal	January 2018
Bulk graphanes synthesized from benzene and pyridine Kondrin, M. V.; Nikolaev, N. A.; Boldyrev, K. N. CrystEngComm, Vol. 19, Issue 6 https://doi.org/10.1039/c6ce02327d	journal	January 2017

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