skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Nanoporous ionic organic networks: stablizing and supporting gold nanoparticles for catalysis

Abstract

In this article, nanoporous ionic organic networks (PIONs) with a high ionic density (three cation–anion pairs per unit) have been synthesized by a facile SN2 nucleophilic substitution reaction. Owing to the electrostatic and steric effect, those ionic networks with porous channels can stabilize and support gold (Au) nanoparticles (NPs) in 1–2 nm. We find the Au@PION hybrid materials used as a heterogeneous catalyst are highly active, selective, and stable in the aerobic oxidation of saturated alcohols.

Authors:
 [1];  [1];  [2];  [3];  [4]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  2. Univ. of Tennessee, Knoxville, TN (United States). Department of Chemistry
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Department of Chemistry
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1265360
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nano Letters
Additional Journal Information:
Journal Volume: 15; Journal Issue: 2; Journal ID: ISSN 1530-6984
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Zhang, Pengfei, Qiao, Zhen-An, Jiang, Xueguang, Veith, Gabriel M., and Dai, Sheng. Nanoporous ionic organic networks: stablizing and supporting gold nanoparticles for catalysis. United States: N. p., 2015. Web. doi:10.1021/nl504780j.
Zhang, Pengfei, Qiao, Zhen-An, Jiang, Xueguang, Veith, Gabriel M., & Dai, Sheng. Nanoporous ionic organic networks: stablizing and supporting gold nanoparticles for catalysis. United States. https://doi.org/10.1021/nl504780j
Zhang, Pengfei, Qiao, Zhen-An, Jiang, Xueguang, Veith, Gabriel M., and Dai, Sheng. 2015. "Nanoporous ionic organic networks: stablizing and supporting gold nanoparticles for catalysis". United States. https://doi.org/10.1021/nl504780j. https://www.osti.gov/servlets/purl/1265360.
@article{osti_1265360,
title = {Nanoporous ionic organic networks: stablizing and supporting gold nanoparticles for catalysis},
author = {Zhang, Pengfei and Qiao, Zhen-An and Jiang, Xueguang and Veith, Gabriel M. and Dai, Sheng},
abstractNote = {In this article, nanoporous ionic organic networks (PIONs) with a high ionic density (three cation–anion pairs per unit) have been synthesized by a facile SN2 nucleophilic substitution reaction. Owing to the electrostatic and steric effect, those ionic networks with porous channels can stabilize and support gold (Au) nanoparticles (NPs) in 1–2 nm. We find the Au@PION hybrid materials used as a heterogeneous catalyst are highly active, selective, and stable in the aerobic oxidation of saturated alcohols.},
doi = {10.1021/nl504780j},
url = {https://www.osti.gov/biblio/1265360}, journal = {Nano Letters},
issn = {1530-6984},
number = 2,
volume = 15,
place = {United States},
year = {Tue Jan 27 00:00:00 EST 2015},
month = {Tue Jan 27 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 124 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation
journal, March 2004


Stop-and-go, stepwise and “ligand-free” nucleation, nanocrystal growth and formation of Au-NPs in ionic liquids (ILs)
journal, January 2010


Size-Selective Synthesis of Gold and Platinum Nanoparticles Using Novel Thiol-Functionalized Ionic Liquids
journal, February 2004


Gold nanocages covered by smart polymers for controlled release with near-infrared light
journal, November 2009


State of the art in gold nanoparticle synthesis
journal, February 2013


Quantum sized, thiolate-protected gold nanoclusters
journal, January 2010


Effect of Electronic Structures of Au Clusters Stabilized by Poly( N -vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis
journal, May 2009


Hydrophobicity/hydrophilicity tunable hyperbranched polystyrenes as novel supports for transition-metal nanoparticles
journal, January 2012


Supported Gold Catalyzes the Homocoupling of Phenylboronic Acid with High Conversion and Selectivity
journal, April 2005


Catalysis by metallic nanoparticles in aqueous solution: model reactions
journal, January 2012


Size- and Structure-specificity in Catalysis by Gold Clusters
journal, April 2014


Catalysis by Supported Gold Nanoparticles: Beyond Aerobic Oxidative Processes
journal, May 2012


Supported Gold Catalysis: From Small Molecule Activation to Green Chemical Synthesis
journal, December 2013


Transition-metal nanocluster stabilization for catalysis: A critical review of ranking methods and putative stabilizers
journal, May 2007


N-Heterocyclic carbene-stabilized gold nanoparticles and their assembly into 3D superlattices
journal, January 2009


Synthesis and Characterization of Gold Nanoparticles with Surface Ligands Derived from a Primary Phosphine
journal, May 2008


Synthesis and Characterization of Phosphido-Monolayer-Protected Gold Nanoclusters
journal, November 2004


Molecular-Scale Surface Chemistry of a Common Metal Nanoparticle Capping Agent: Triphenylphosphine on Au(111)
journal, March 2012


First enantioseparation and circular dichroism spectra of Au38 clusters protected by achiral ligands
journal, January 2012


Synergy between Pt and Au in Pt-on-Au Nanostructures for Chemoselective Hydrogenation Catalysis
journal, September 2011


Pd Nanoparticles Immobilized on Molecular Sieves by Ionic Liquids: Heterogeneous Catalysts for Solvent-Free Hydrogenation
journal, March 2004


Recent advances in polymer protected gold nanoparticles: synthesis, properties and applications
journal, January 2007


Ether- and alcohol-functionalized task-specific ionic liquids: attractive properties and applications
journal, January 2012


Rhodium-Phosphite SILP Catalysis for the Highly Selective Hydroformylation of Mixed C4 Feedstocks
journal, April 2011


Supported Ionic Liquid Catalysis − A New Concept for Homogeneous Hydroformylation Catalysis
journal, November 2002


Synthesis of Gold Nanoparticle Catalysts Based on a New Water-Soluble Ionic Polymer
journal, September 2011


Palladium nanoparticles entrapped in polymeric ionic liquid microgels as recyclable hydrogenation catalysts
journal, November 2013


Poly(ionic liquid) Complex with Spontaneous Micro-/Mesoporosity: Template-Free Synthesis and Application as Catalyst Support
journal, July 2012


An Anionic Microporous Polymer Network Prepared by the Polymerization of Weakly Coordinating Anions
journal, October 2013


Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus
journal, March 2012


In situ formation of well-dispersed palladium nanoparticles immobilized in imidazolium-based organic ionic polymers
journal, January 2014


Hydrosilylation of Ketone and Imine over Poly-N-Heterocyclic Carbene Particles
journal, June 2009


Efficient Aerobic Oxidation of Alcohols using a Hydrotalcite-Supported Gold Nanoparticle Catalyst
journal, August 2009


Ordered, extra-large mesopores with highly loaded gold nanoparticles: a new sintering- and coking-resistant catalyst system
journal, January 2013


Design and Preparation of Porous Polymers
journal, April 2012


Enhanced Carbon Dioxide Adsorption by a Mesoporous Poly(ionic liquid)
journal, July 2012


Selective oxidation of alcohols and aldehydes over supported metal nanoparticles
journal, January 2013


Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO 2 Catalysts
journal, January 2006


Triazine-Based Polymers as Nanostructured Supports for the Liquid-Phase Oxidation of Alcohols
journal, November 2010


Water- and Organo-Dispersible Gold Nanoparticles Supported by Using Ammonium Salts of Hyperbranched Polystyrene: Preparation and Catalysis
journal, September 2013


Solvent-Free Aerobic Oxidation of Alcohols Catalyzed by an Efficient and Recyclable Palladium Heterogeneous Catalyst
journal, August 2005


Turnover Numbers and Soluble Metal Nanoparticles
journal, June 2011


Stability of Superoxide Ion in Imidazolium Cation-Based Room-Temperature Ionic Liquids
journal, January 2009


Works referencing / citing this record:

Ionic organic cage-encapsulating phase-transferable metal clusters
journal, January 2019


Gold nanoparticles anchored onto the magnetic poly(ionic-liquid) polymer as robust and recoverable catalyst for reduction of Nitroarenes
journal, May 2017


Three birds, one stone – photo-/piezo-/chemochromism in one conjugated nanoporous ionic organic network
journal, January 2018


A monomer-assembly template-directed synthesis of conjugated porous polymer microtubular bundles
journal, January 2020


Heterogeneous viologen catalysts for metal-free and selective oxidations
journal, January 2019


A succinct strategy for construction of nanoporous ionic organic networks from a pyrylium intermediate
journal, January 2019


Synthesis of Porous Sulfonamide Polymers by Capturing Atmospheric Sulfur Dioxide
journal, May 2018


Polymerized Ionic Networks with High Charge Density: Quasi-Solid Electrolytes in Lithium-Metal Batteries
journal, November 2015


Selective oxidation of alcohols by supported gold nanoparticles: recent advances
journal, January 2016


Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO 2 conversion
journal, January 2018


Ionized aromatization approach to charged porous polymers as exceptional absorbents
journal, January 2019


Engineering nanoporous organic frameworks to stabilize naked Au clusters: a charge modulation approach
journal, January 2018


In situ study of nucleation and growth dynamics of Au nanoparticles on MoS 2 nanoflakes
journal, January 2018


Function-oriented ionic polymers having high-density active sites for sustainable carbon dioxide conversion
journal, January 2018


Gold-Nanoparticle Decorated Monosized Magnetic Polymer Based Catalyst: Reduction of 4-Nitrophenol
journal, June 2018


Nanoporous ionic organic networks: from synthesis to materials applications
journal, January 2016


Porous ionic liquids: synthesis and application
journal, January 2015


Ionic liquid/H 2 O-mediated synthesis of mesoporous organic polymers and their application in methylation of amines
journal, January 2017


Synthesis of a hypercrosslinked, ionic, mesoporous polymer monolith and its application in deep oxidative desulfurization
journal, February 2018


Ordered fragmentation of oxide thin films at submicron scale
journal, October 2016


Porous ionic liquids: synthesis and application
journal, January 2015


Advances in Organic and Organic-Inorganic Hybrid Polymeric Supports for Catalytic Applications
journal, September 2016