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Title: Self-consistent theory of nanodomain formation on non-polar surfaces of ferroelectrics

Journal Article · · Physical Review B
 [1];  [2];  [1];  [3];  [4];  [5];  [6]
  1. National Academy of Sciences of Ukraine (NASU), Kiev (Ukraine). Inst. for Problems of Materials Science
  2. Taras Shevchenko National Univ. (Ukraine)
  3. Kiev Univ. (Ukraine)
  4. Ural Federal Univ., Ekaterinburg (Russia)
  5. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  6. National Academy of Sciences of Ukraine (NASU), Kiev (Ukraine)

We propose a self-consistent theoretical approach capable of describing the features of the anisotropic nanodomain formation induced by a strongly inhomogeneous electric field of a charged scanning probe microscopy tip on nonpolar cuts of ferroelectrics. We obtained that a threshold field, previously regarded as an isotropic parameter, is an anisotropic function that is specified from the polar properties and lattice pinning anisotropy of a given ferroelectric in a self-consistent way. The proposed method for the calculation of the anisotropic threshold field is not material specific, thus the field should be anisotropic in all ferroelectrics with the spontaneous polarization anisotropy along the main crystallographic directions. The most evident examples are uniaxial ferroelectrics, layered ferroelectric perovskites, and low-symmetry incommensurate ferroelectrics. Obtained results quantitatively describe the differences at several times in the nanodomain length experimentally observed on X and Y cuts of LiNbO3 and can give insight into the anisotropic dynamics of nanoscale polarization reversal in strongly inhomogeneous electric fields.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1261369
Alternate ID(s):
OSTI ID: 1249796
Journal Information:
Physical Review B, Vol. 93, Issue 16; ISSN 2469-9950
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 9 works
Citation information provided by
Web of Science

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Cited By (3)

Toward High-Quality Epitaxial LiNbO 3 and LiTaO 3 Thin Films for Acoustic and Optical Applications journal March 2017
Surface-screening mechanisms in ferroelectric thin films and their effect on polarization dynamics and domain structures journal January 2018
Domain Diversity and Polarization Switching in Amino Acid β-Glycine journal April 2019

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