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Title: Vapor space characterization of waste Tank 241-SX-103: Results from samples collected on 3/23/95

Technical Report ·
DOI:https://doi.org/10.2172/125023· OSTI ID:125023

This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage tank 241-SX-103 (referred to as Tank SX-103). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH{sub 3}), nitrogen dioxide (NO{sub 2}), nitric oxide (NO), and water vapor (H{sub 2}O). Sampling for hydrogen cyanide (HCN) and sulfur oxides (SO{sub x}) was not requested. In addition, quantitative results were obtained for the 39 TO-14 compounds plus an additional 14 analytes. Of these, two were observed above the 5-ppbv reporting cutoff. Two tentatively identified compounds (TICs) were observed above the reporting cutoff of (ca.) 10 ppbv and are reported with concentrations that are semiquantitative estimates based on internal-standard response factors. The four organic analytes identified are listed in Table 1 and account for approximately 100% of the total organic components in Tank SX-103. Carbon dioxide (CO{sub 2}) was the only permanent gas detected in the tank-headspace samples. Tank SX-103 is on the Hydrogen Watch List.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
125023
Report Number(s):
PNL-10814; ON: DE96002057; TRN: AHC29528%%58
Resource Relation:
Other Information: PBD: Nov 1995
Country of Publication:
United States
Language:
English