Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

Hsieh, Peter Y.; Kwong, Kyei-Sing; Bennett, James

doi:10.1016/j.fuproc.2015.09.019

Title: Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

Journal Article · Sun Sep 27 00:00:00 EDT 2015 · Fuel Processing Technology

DOI:https://doi.org/10.1016/j.fuproc.2015.09.019· OSTI ID:1240881

^[1]; Kwong, Kyei-Sing ^[1]; Bennett, James ^[1]

National Energy Technology Lab. (NETL), Albany, OR (United States). Structural Materials Development Division

Coal gasification yields synthesis gas, an important intermediate in chemical manufacturing. It is also vital to the production of liquid fuels through the Fischer-Tropsch process and electricity in Integrated Gasification Combined Cycle power generation. Minerals naturally present in coal become molten in entrained-flow slagging gasifiers. Molten coal ash slag penetrates and dissolves refractory bricks, leading to costly plant shutdowns. The extent of coal ash slag penetration and refractory brick dissolution depends on the slag viscosity, the gasification temperature, and the composition of slag and bricks. We measured the viscosity of several synthetic coal ash slags with a high-temperature rotary viscometer and their ash fusion temperatures through optical image analysis. All measurements were made in a carbon monoxide-carbon dioxide reducing atmosphere that approximates coal gasification conditions. Empirical correlation models based on ash fusion temperatures were used to calculate critical viscosity temperatures based on the coal ash compositions. These values were then compared with those obtained from thermodynamic phase-transition models. An understanding of slag viscosity as a function of ash composition is important to reducing refractory wear in slagging coal gasifiers, which would help to reduce the cost and environmental impact of coal for chemical and electricity production.

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Research Organization:: National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research

Sponsoring Organization:: USDOE

OSTI ID:: 1240881

Report Number(s):: NETL-PUB-20045; PII: S0378382015301727

Journal Information:: Fuel Processing Technology, Vol. 142, Issue C; ISSN 0378-3820

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 49 works

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References (104)

Advances in Coal Gasification, Hydrogenation, and Gas Treating for the Production of Chemicals and Fuels Higman, Christopher; Tam, Samuel Chemical Reviews, Vol. 114, Issue 3, p. 1673-1708 https://doi.org/10.1021/cr400202m	journal	October 2013
Reactions of synthesis gas Wender, Irving Fuel Processing Technology, Vol. 48, Issue 3 https://doi.org/10.1016/S0378-3820(96)01048-X	journal	September 1996
Combustion processes for carbon capture Wall, Terry F. Proceedings of the Combustion Institute, Vol. 31, Issue 1 https://doi.org/10.1016/j.proci.2006.08.123	journal	January 2007
Assessment of oxy-fuel, pre- and post-combustion-based carbon capture for future IGCC plants Kunze, Christian; Spliethoff, Hartmut Applied Energy, Vol. 94 https://doi.org/10.1016/j.apenergy.2012.01.013	journal	June 2012
Techno-economic assessment of fossil fuel power plants with CO2 capture – Results of EU H2-IGCC project Mansouri Majoumerd, Mohammad; Assadi, Mohsen International Journal of Hydrogen Energy, Vol. 39, Issue 30 https://doi.org/10.1016/j.ijhydene.2014.08.020	journal	October 2014
Process design and optimization of state-of-the-art carbon capture technologies Zhou, Zhijun; You, Zhuo; Wang, Zhihua Environmental Progress & Sustainable Energy, Vol. 33, Issue 3 https://doi.org/10.1002/ep.11837	journal	September 2013
Wear Mechanisms of Chromia Refractories in Slagging Gasifiers: Wear Mechanisms of Chromia Refractories Kwong, Kyeising; Petty, Art; Bennett, James International Journal of Applied Ceramic Technology, Vol. 4, Issue 6 https://doi.org/10.1111/j.1744-7402.2007.02175.x	journal	December 2007
Advanced Hot Gas Cleaning System for Coal Gasification Processes Newby, R. A.; Bannister, R. L. Journal of Engineering for Gas Turbines and Power, Vol. 116, Issue 2 https://doi.org/10.1115/1.2906825	journal	April 1994
Ash and slag qualities of Australian bituminous coals for use in slagging gasifiers Patterson, J. Fuel, Vol. 79, Issue 13 https://doi.org/10.1016/S0016-2361(00)00032-6	journal	October 2000
Expanding the range of suitable gasification fuels Brannon, Michael J.; Ollis, G. Wayne; Shoaf, Glenn L. Fuel Processing Technology, Vol. 99 https://doi.org/10.1016/j.fuproc.2012.01.028	journal	July 2012
Improvement of ash flow properties of low-rank coal for entrained flow gasifier Kong, Lingxue; Bai, Jin; Bai, Zongqing Fuel, Vol. 120 https://doi.org/10.1016/j.fuel.2013.12.001	journal	March 2014
Acid–base properties of molten oxides and metallurgical slags Duffy, John A.; Ingram, Malcolm D.; Sommerville, Iain D. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 74, Issue 0 https://doi.org/10.1039/f19787401410	journal	January 1978
Viscosity measurements on liquid slags in the system CaO-FeO-Fe2O3-SiO2. Seki, Kazumi; Oeters, Franz Transactions of the Iron and Steel Institute of Japan, Vol. 24, Issue 6 https://doi.org/10.2355/isijinternational1966.24.445	journal	January 1984
The Influence of Structure on the Physico-chemical Properties of Slags. Mills, Kenneth C. ISIJ International, Vol. 33, Issue 1 https://doi.org/10.2355/isijinternational.33.148	journal	January 1993
Viscosities of ironmaking and steelmaking slags Mills, K. C.; Sridhar, S. Ironmaking & Steelmaking, Vol. 26, Issue 4 https://doi.org/10.1179/030192399677121	journal	August 1999
Application of optical basicity to viscosity of high alumina blast furnace slags Ghosh, D.; Krishnamurthy, V. A.; Sankaranarayanan, S. R. Journal of Mining and Metallurgy, Section B: Metallurgy, Vol. 46, Issue 1 https://doi.org/10.2298/JMMB1001041G	journal	January 2010
Establishment of an optical scale for Lewis basicity in inorganic oxyacids, molten salts, and glasses Duffy, J. A.; Ingram, M. D. Journal of the American Chemical Society, Vol. 93, Issue 24 https://doi.org/10.1021/ja00753a019	journal	December 1971
A review of optical basicity and its applications to oxidic systems Duffy, John A. Geochimica et Cosmochimica Acta, Vol. 57, Issue 16 https://doi.org/10.1016/0016-7037(93)90346-X	journal	August 1993
Rheological properties of high-temperature melts of coal ashes and other silicates Vargas, S.; Frandsen, F. J.; Dam-Johansen, K. Progress in Energy and Combustion Science, Vol. 27, Issue 3 https://doi.org/10.1016/S0360-1285(00)00023-X	journal	March 2001
An Empirical Method for the Prediction of Coal Ash Slag Viscosity Browning, G. J.; Bryant, G. W.; Hurst, H. J. Energy & Fuels, Vol. 17, Issue 3 https://doi.org/10.1021/ef020165o	journal	May 2003
Local structure of a lignitic coal ash slag and its effect on viscosity Nowok, Jan W.; Hurley, John P.; Stanley, Daniel C. Energy & Fuels, Vol. 7, Issue 6 https://doi.org/10.1021/ef00042a063	journal	November 1993
Effects of Atmosphere on Viscosity of Selected Bituminous and Low-Rank Coal Ash Slags Folkedahl, Bruce C.; Schobert, Harold H. Energy & Fuels, Vol. 19, Issue 1 https://doi.org/10.1021/ef040013o	journal	January 2005
Measuring the viscous flow of molten coal ash Stanmore, Brian R.; Budd, Stuart Fuel, Vol. 75, Issue 12 https://doi.org/10.1016/0016-2361(96)00129-9	journal	October 1996
Measurement of the Viscosity of Coal-Derived Slag Using Thermomechanical Analysis Buhre, Bart J. P.; Browning, Gregory J.; Gupta, Rajender P. Energy & Fuels, Vol. 19, Issue 3 https://doi.org/10.1021/ef0497311	journal	May 2005
Failure Mechanisms in High Chrome Oxide Gasifier Refractories Bennett, James P.; Kwong, Kyei-Sing Metallurgical and Materials Transactions A, Vol. 42, Issue 4 https://doi.org/10.1007/s11661-011-0635-x	journal	March 2011
A Non-Newtonian Flow Model for Coal-Ash Slag Johnson, E. K. Journal of Engineering for Gas Turbines and Power, Vol. 106, Issue 4 https://doi.org/10.1115/1.3239638	journal	October 1984
Rheological Properties of Magmas McBirney, A. R.; Murase, T. Annual Review of Earth and Planetary Sciences, Vol. 12, Issue 1 https://doi.org/10.1146/annurev.ea.12.050184.002005	journal	May 1984
Methods of determining the rheological properties of magmas at sub-liquidus temperatures Pinkerton, H.; Stevenson, R. J. Journal of Volcanology and Geothermal Research, Vol. 53, Issue 1-4 https://doi.org/10.1016/0377-0273(92)90073-M	journal	November 1992
Rheology and microstructure of magmatic emulsions: theory and experiments Stein, Daniel J.; Spera, Frank J. Journal of Volcanology and Geothermal Research, Vol. 49, Issue 1-2 https://doi.org/10.1016/0377-0273(92)90011-2	journal	January 1992
Rheological properties of basaltic lavas at sub-liquidus temperatures: laboratory and field measurements on lavas from Mount Etna Pinkerton, Harry; Norton, Gill Journal of Volcanology and Geothermal Research, Vol. 68, Issue 4 https://doi.org/10.1016/0377-0273(95)00018-7	journal	November 1995
Viscosity of microlite-bearing rhyolitic obsidians: an experimental study Stevenson, R. J.; Dingwell, D. B.; Webb, S. L. Bulletin of Volcanology, Vol. 58, Issue 4 https://doi.org/10.1007/s004450050141	journal	November 1996
Rheological Transitions During Partial Melting and Crystallization with Application to Felsic Magma Segregation and Transfer Vigneresse, Jean Louis; Barbey, Pierre; Cuney, Michel Journal of Petrology, Vol. 37, Issue 6 https://doi.org/10.1093/petrology/37.6.1579	journal	January 1996
Viscosity measurement of subliquidus magmas: 1707 basalt of Fuji volcano Sato, Hiroaki Journal of Mineralogical and Petrological Sciences, Vol. 100, Issue 4 https://doi.org/10.2465/jmps.100.133	journal	January 2005
Viscosity measurements of subliquidus magmas: Alkali olivine basalt from the Higashi-Matsuura district, Southwest Japan Ishibashi, Hidemi; Sato, Hiroaki Journal of Volcanology and Geothermal Research, Vol. 160, Issue 3-4 https://doi.org/10.1016/j.jvolgeores.2006.10.001	journal	February 2007
Non-Newtonian behavior of plagioclase-bearing basaltic magma: Subliquidus viscosity measurement of the 1707 basalt of Fuji volcano, Japan Ishibashi, Hidemi Journal of Volcanology and Geothermal Research, Vol. 181, Issue 1-2 https://doi.org/10.1016/j.jvolgeores.2009.01.004	journal	March 2009
The rheological transition in plagioclase-bearing magmas: RHEOLOGICAL TRANSITION IN MAGMAS Picard, D.; Arbaret, L.; Pichavant, M. Journal of Geophysical Research: Solid Earth, Vol. 118, Issue 4 https://doi.org/10.1002/jgrb.50091	journal	April 2013
Viscosity changes during crystallization of a shoshonitic magma: new insights on lava flow emplacement Vetere, Francesco; Sato, Hiroaki; Ishibashi, Hidemi Journal of Mineralogical and Petrological Sciences, Vol. 108, Issue 3 https://doi.org/10.2465/jmps.120724	journal	January 2013
Viscosity of Highly Basic Slags Seok, Seong-Ho; Jung, Sung-Mo; Lee, Young-Seok ISIJ International, Vol. 47, Issue 8 https://doi.org/10.2355/isijinternational.47.1090	journal	January 2007
The effect of particle shape on suspension viscosity and implications for magmatic flows: PARTICLE SHAPE AND SUSPENSION VISCOSITY Mueller, S.; Llewellin, E. W.; Mader, H. M. Geophysical Research Letters, Vol. 38, Issue 13 https://doi.org/10.1029/2011GL047167	journal	July 2011
Rheological evolution and crystallization response of molten coal ash slag at high temperatures Song, Wenjia; Tang, Lihua; Zhu, Zibin AIChE Journal, Vol. 59, Issue 8 https://doi.org/10.1002/aic.14052	journal	March 2013
Viscosity measurements of slags from pulverized western Canadian coals in a pilot-scale research boiler Quon, David H. H.; Wang, Schubert S. B.; Chen, Tzong T. Fuel, Vol. 63, Issue 7 https://doi.org/10.1016/0016-2361(84)90314-4	journal	July 1984
Prediction of ash fusion temperature from ash composition for some New Zealand coals Gray, V. Fuel, Vol. 66, Issue 9 https://doi.org/10.1016/0016-2361(87)90061-5	journal	September 1987
Physico-chemical properties and petrographic characteristics of the Kapurdi lignite deposit, Barmer Basin, Rajasthan, India Mukherjee, A. K.; Alam, M. M.; Mazumdar, S. K. International Journal of Coal Geology, Vol. 21, Issue 1-2 https://doi.org/10.1016/0166-5162(92)90034-T	journal	June 1992
Influence of mineral and chemical composition of coal ashes on their fusibility Vassilev, Stanislav V.; Kitano, Kunihiro; Takeda, Shohei Fuel Processing Technology, Vol. 45, Issue 1 https://doi.org/10.1016/0378-3820(95)00032-3	journal	October 1995
The influences of mineral behaviour on blended coal ash fusion characteristics Qiu, J. -R.; Li, F.; Zheng, Y. Fuel, Vol. 78, Issue 8 https://doi.org/10.1016/S0016-2361(99)00005-8	journal	June 1999
The Fusibility of Blended Coal Ash Bryant, G. W.; Browning, G. J.; Emanuel, H. Energy & Fuels, Vol. 14, Issue 2 https://doi.org/10.1021/ef990093+	journal	February 2000
Geochemistry, mineralogy, and technological properties of the main Stephanian (Carboniferous) coal seams from the Puertollano Basin, Spain Alastuey, A.; Jiménez, A.; Plana, F. International Journal of Coal Geology, Vol. 45, Issue 4 https://doi.org/10.1016/S0166-5162(00)00036-7	journal	February 2001
Correlation between ash fusion temperatures and chemical composition in Albanian coal ashes☆ Lolja, Saimir A.; Haxhi, Hajri; Dhimitri, Rolanda Fuel, Vol. 81, Issue 17 https://doi.org/10.1016/S0016-2361(02)00194-1	journal	December 2002
Behaviour of inorganic matter during heating of Bulgarian coals Vassileva, Christina G.; Vassilev, Stanislav V. Fuel Processing Technology, Vol. 86, Issue 12-13 https://doi.org/10.1016/j.fuproc.2005.01.024	journal	August 2005
Behaviour of inorganic matter during heating of Bulgarian coals Vassileva, Christina G.; Vassilev, Stanislav V. Fuel Processing Technology, Vol. 87, Issue 12 https://doi.org/10.1016/j.fuproc.2006.08.006	journal	December 2006
Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type Hackley, Paul C.; Martinez, Manuel International Journal of Coal Geology, Vol. 71, Issue 4 https://doi.org/10.1016/j.coal.2006.05.002	journal	August 2007
Coal and coal ash characteristics to understand mineral transformations and slag formation Van Dyk, J. C.; Benson, S. A.; Laumb, M. L. Fuel, Vol. 88, Issue 6 https://doi.org/10.1016/j.fuel.2008.11.034	journal	June 2009
Behavior of Mineral Matters in Chinese Coal Ash Melting during char-CO ₂ /H ₂ O Gasification Reaction Wu, Xiaojiang; Zhang, Zhongxiao; Piao, Guilin Energy & Fuels, Vol. 23, Issue 5 https://doi.org/10.1021/ef801002n	journal	May 2009
Criteria selection for the assessment of Serbian lignites tendency to form deposits on power boilers heat transfer surfaces Mladenovic, Milica; MladenoviC, Rastko; Manovic, Vasilije Thermal Science, Vol. 13, Issue 4 https://doi.org/10.2298/TSCI0904061M	journal	January 2009
Effect of Key Minerals on the Ash Melting Behavior in a Reducing Atmosphere Wang, Haigang; Qiu, Penghua; Shi, Xu Energy & Fuels, Vol. 25, Issue 8 https://doi.org/10.1021/ef200542n	journal	August 2011
Mineral melting behavior of chinese blended coal ash under gasification condition Wu, Xiaojiang; Zhou, Tuo; Chen, Yushuang Asia-Pacific Journal of Chemical Engineering, Vol. 6, Issue 2 https://doi.org/10.1002/apj.425	journal	March 2011
Ash Quality of a Beneficiated Lignite from Ptolemais Basin, Northern Greece Vamvuka, D.; Mistakidou, E.; Drakonaki, S. Energy & Fuels, Vol. 15, Issue 5 https://doi.org/10.1021/ef0100193	journal	September 2001
The effects of leaching and floatation on the ash fusion temperatures of three selected lignites Li, Feng-hai; Huang, Jie-jie; Fang, Yi-tian Fuel, Vol. 90, Issue 7 https://doi.org/10.1016/j.fuel.2011.03.020	journal	July 2011
Crystallization of Coal Ash Slags at High Temperatures and Effects on the Viscosity Yuan, Haiping; Liang, Qinfeng; Gong, Xin Energy & Fuels, Vol. 26, Issue 6 https://doi.org/10.1021/ef201894p	journal	May 2012
Relationship between coal ash composition and ash fusion temperatures Liu, Bo; He, Qihui; Jiang, Zihao Fuel, Vol. 105 https://doi.org/10.1016/j.fuel.2012.06.046	journal	March 2013
Gasification perspective of Pakistani coal Naveed, S.; Malik, A.; Akram, M. Journal of the Energy Institute, Vol. 86, Issue 1 https://doi.org/10.1179/1743967112Z.00000000021	journal	February 2013
Improvement of the Coal Ash Slagging Tendency by Coal Washing and Additive Blending with Mullite Generation Huang, Zhenyu; Li, Yan; Lu, Dan Energy & Fuels, Vol. 27, Issue 4 https://doi.org/10.1021/ef400045y	journal	March 2013
Explaining the relationship between common coal analyses and Afghan coal parameters using statistical modeling methods Chehreh Chelgani, S.; Makaremi, S. Fuel Processing Technology, Vol. 110 https://doi.org/10.1016/j.fuproc.2012.11.005	journal	June 2013
Effect of temperature and pressure on the mineralogical and fusion characteristics of Jincheng coal ash in simulated combustion and gasification environments Jing, Nijie; Wang, Qinhui; Cheng, Leming Fuel, Vol. 104 https://doi.org/10.1016/j.fuel.2012.05.040	journal	February 2013
Fate of inorganic matter in entrained-flow slagging gasifiers: Fuel characterization Duchesne, Marc A.; Hall, Ajae D.; Hughes, Robin W. Fuel Processing Technology, Vol. 118 https://doi.org/10.1016/j.fuproc.2013.09.004	journal	February 2014
Composition, mineral matter characteristics and ash fusion behavior of some Indian coals Chakravarty, S.; Mohanty, Ashok; Banerjee, Amit Fuel, Vol. 150 https://doi.org/10.1016/j.fuel.2015.02.015	journal	June 2015
A Study on Coal Properties and Combustion Characteristics of Blended Coals in Northwestern China Wang, Chang’an; Liu, Yinhe; Zhang, Xiaoming Energy & Fuels, Vol. 25, Issue 8 https://doi.org/10.1021/ef200686d	journal	August 2011
The Influence Of Calcite On The Ash Flow Temperature For Semi-Anthracite Coal From Donbas District Čarnogurská, Mária; Příhoda, Miroslav; Pyszko, René Chemical and Process Engineering, Vol. 35, Issue 4 https://doi.org/10.2478/cpe-2014-0038	journal	December 2014
Relationship of Coal-Ash Viscosity to Chemical Composition Sage, W. L.; McIlroy, J. B. Journal of Engineering for Power, Vol. 82, Issue 2 https://doi.org/10.1115/1.3672737	journal	April 1960
Empirical correlations of the ash fusion temperatures and temperature of critical viscosity for coal and biomass ashes Seggiani, M. Fuel, Vol. 78, Issue 9 https://doi.org/10.1016/S0016-2361(99)00031-9	journal	July 1999
Quantification of fusion in ashes from solid fuel combustion Hansen, Lone A.; Frandsen, Flemming J.; Dam-Johansen, Kim Thermochimica Acta, Vol. 326, Issue 1-2 https://doi.org/10.1016/S0040-6031(98)00596-6	journal	February 1999
Origins of concentric cylinders viscometry Dontula, Prasannarao; Macosko, Christopher W.; Scriven, L. E. Journal of Rheology, Vol. 49, Issue 4 https://doi.org/10.1122/1.1940640	journal	July 2005
The viscosity of blast-furnace slag and its relation to iron metallurgy, including a description of a new method of measuring slag viscosity at high temperatures Feild, Alexander L. Transactions of the Faraday Society, Vol. 13, Issue December https://doi.org/10.1039/tf9171300003	journal	January 1917
Flow properties of low-rank coal ash slags Schobert, Harold H.; Streeter, Robert C.; Diehl, Erle K. Fuel, Vol. 64, Issue 11 https://doi.org/10.1016/0016-2361(85)90380-1	journal	November 1985
Viscosity and Phase Transformation in Coal Ash Slags near and below the Temperature of Critical Viscosity Nowok, Jan W. Energy & Fuels, Vol. 8, Issue 6 https://doi.org/10.1021/ef00048a022	journal	November 1994
Effect of crystalline phase formation on coal slag viscosity Oh, M. S.; Brooker, D. D.; de Paz, E. F. Fuel Processing Technology, Vol. 44, Issue 1-3 https://doi.org/10.1016/0378-3820(95)00012-V	journal	September 1995
Viscosity measurements and empirical predictions for some model gasifier slags Hurst, H. J.; Novak, F.; Patterson, J. H. Fuel, Vol. 78, Issue 4 https://doi.org/10.1016/S0016-2361(98)00162-8	journal	March 1999
Viscosity measurements and empirical predictions for fluxed Australian bituminous coal ashes Hurst, H. J.; Novak, F.; Patterson, J. H. Fuel, Vol. 78, Issue 15 https://doi.org/10.1016/S0016-2361(99)00094-0	journal	December 1999
Viscosity measurements and empirical predictions for some model gasifier slags—II Hurst, H. J.; Patterson, J. H.; Quintanar, A. Fuel, Vol. 79, Issue 14 https://doi.org/10.1016/S0016-2361(00)00043-0	journal	November 2000
Fusibility and flow properties of coal ash and slag Song, Wenjia; Tang, Lihua; Zhu, Xuedong Fuel, Vol. 88, Issue 2 https://doi.org/10.1016/j.fuel.2008.09.015	journal	February 2009
Flow properties and rheology of slag from coal gasification Song, Wenjia; Tang, Lihua; Zhu, Xuedong Fuel, Vol. 89, Issue 7 https://doi.org/10.1016/j.fuel.2009.07.013	journal	July 2010
Prediction of temperature of critical viscosity for coal ash slag Song, Wenjia; Dong, Yanhe; Wu, Yongqiang AIChE Journal, Vol. 57, Issue 10 https://doi.org/10.1002/aic.12500	journal	March 2011
Viscosity of High-Iron Slags from Australian Coals Ilyushechkin, Alexander Y.; Hla, San Shwe Energy & Fuels, Vol. 27, Issue 7 https://doi.org/10.1021/ef400593k	journal	June 2013
The rheology of crystal-bearing basaltic magmas from Stromboli and Etna Vona, A.; Romano, C.; Dingwell, D. B. Geochimica et Cosmochimica Acta, Vol. 75, Issue 11 https://doi.org/10.1016/j.gca.2011.03.031	journal	June 2011
Viscosity measurements of crystallizing andesite from T ungurahua volcano ( E cuador) Chevrel, Magdalena Oryaëlle; Cimarelli, Corrado; deBiasi, Lea Geochemistry, Geophysics, Geosystems, Vol. 16, Issue 3 https://doi.org/10.1002/2014GC005661	journal	March 2015
Improved prediction of coal ash slag viscosity by thermodynamic modeling of liquid-phase composition Jung, Bongjin; Schobert, Harold H. Energy & Fuels, Vol. 6, Issue 4 https://doi.org/10.1021/ef00034a007	journal	July 1992
A brief history of CALPHAD Spencer, P. J. Calphad, Vol. 32, Issue 1 https://doi.org/10.1016/j.calphad.2007.10.001	journal	March 2008
FactSage thermochemical software and databases Bale, C. W.; Chartrand, P.; Degterov, S. A. Calphad, Vol. 26, Issue 2 https://doi.org/10.1016/S0364-5916(02)00035-4	journal	June 2002
FactSage thermochemical software and databases — recent developments Bale, C. W.; Bélisle, E.; Chartrand, P. Calphad, Vol. 33, Issue 2 https://doi.org/10.1016/j.calphad.2008.09.009	journal	June 2009
Prediction of coal ash fusion temperatures with the F∗A∗C∗T thermodynamic computer package Jak, Evgueni Fuel, Vol. 81, Issue 13 https://doi.org/10.1016/S0016-2361(02)00091-1	journal	August 2002
Viscosity predictions of the slag composition of gasified coal, utilizing FactSage equilibrium modelling van Dyk, J. C.; Waanders, F. B.; Benson, S. A. Fuel, Vol. 88, Issue 1 https://doi.org/10.1016/j.fuel.2008.07.034	journal	January 2009
The effect of solids and phase compositions on viscosity behaviour and TCV of slags from Australian bituminous coals Ilyushechkin, Alexander Y.; Hla, San S.; Roberts, Daniel G. Journal of Non-Crystalline Solids, Vol. 357, Issue 3 https://doi.org/10.1016/j.jnoncrysol.2010.12.004	journal	February 2011
Viscosity Determination of Molten Ash from Low-Grade US Coals Zhu, Jingxi; Nakano, Jinichiro; Kaneko, Tetsuya Kenneth High Temperature Materials and Processes, Vol. 31, Issue 4-5 https://doi.org/10.1515/htmp-2012-0094	journal	October 2012
Flow behaviour of slags from coal and petroleum coke blends Duchesne, Marc A.; Ilyushechkin, Alexander Y.; Hughes, Robin W. Fuel, Vol. 97 https://doi.org/10.1016/j.fuel.2012.02.019	journal	July 2012
Effects of CaCO3 on slag flow properties at high temperatures Kong, Lingxue; Bai, Jin; Bai, Zongqing Fuel, Vol. 109 https://doi.org/10.1016/j.fuel.2012.11.014	journal	July 2013
Coal blend combustion: fusibility ranking from mineral matter composition☆ Goñi, Ch.; Helle, S.; Garcia, X. Fuel, Vol. 82, Issue 15-17 https://doi.org/10.1016/S0016-2361(03)00156-X	journal	October 2003
Predicted mineral melt formation by BCURA Coal Sample Bank coals: Variation with atmosphere and comparison with reported ash fusion test data Thompson, D. Fuel, Vol. 89, Issue 8 https://doi.org/10.1016/j.fuel.2009.11.027	journal	August 2010
Measurement and simulation of flow properties of coal ash slag in coal gasification Song, Wenjia; Sun, Yimin; Wu, Yongqiang AIChE Journal, Vol. 57, Issue 3 https://doi.org/10.1002/aic.12293	journal	May 2010
Effects of Measurement Materials and Oxygen Partial Pressure on the Viscosity of Synthetic Eastern and Western United States Coal Slags Zhu, Jingxi; Kaneko, Tetsuya Kenneth; Mu, Haoyuan Energy & Fuels, Vol. 26, Issue 7 https://doi.org/10.1021/ef300632x	journal	July 2012
Effect of cooling rate and alumina dissolution on the determination of temperature of critical viscosity of molten slag Kim, Y.; Oh, M. S. Fuel Processing Technology, Vol. 91, Issue 8 https://doi.org/10.1016/j.fuproc.2010.02.006	journal	August 2010
The measurement and estimation of the physical properties of slags formed during coal gasification Mills, Kenneth C.; Rhine, Jeffrey M. Fuel, Vol. 68, Issue 2 https://doi.org/10.1016/0016-2361(89)90322-0	journal	February 1989
Comments on the use of molybdenum components for slag viscosity measurements French, D.; Hurst, H. J.; Marvig, P. Fuel Processing Technology, Vol. 72, Issue 3 https://doi.org/10.1016/S0378-3820(01)00188-6	journal	September 2001
Correlation between ash-fusion temperatures and ternary equilibrium phase diagrams Huggins, Frank E.; Kosmack, Deborah A.; Huffman, Gerald P. Fuel, Vol. 60, Issue 7 https://doi.org/10.1016/0016-2361(81)90157-5	journal	July 1981
Slagging of petroleum coke ash using Korean anthracites Park, Woosung; Oh, Myongsook S. Journal of Industrial and Engineering Chemistry, Vol. 14, Issue 3 https://doi.org/10.1016/j.jiec.2007.12.004	journal	May 2008

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