Thermally triggered phononic gaps in liquids at THz scale

Bolmatov, Dima; Zhernenkov, Mikhail; Zavyalov, Dmitry; Stoupin, Stanislav; Cunsolo, Alessandro; Cai, Yong Q.

doi:10.1038/srep19469

Title: Thermally triggered phononic gaps in liquids at THz scale

Journal Article · Thu Jan 14 00:00:00 EST 2016 · Scientific Reports

DOI:https://doi.org/10.1038/srep19469· OSTI ID:1240873

Bolmatov, Dima ^[1]; Zhernenkov, Mikhail ^[1]; Zavyalov, Dmitry ^[2]; Stoupin, Stanislav ^[3]; Cunsolo, Alessandro ^[1]; Cai, Yong Q. ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Volgograd State Technical Univ., Volgograd (Russia)
Argonne National Lab. (ANL), Argonne, IL (United States)

In this study we present inelastic X-ray scattering experiments in a diamond anvil cell and molecular dynamic simulations to investigate the behavior of phononic excitations in liquid Ar. The spectra calculated using molecular dynamics were found to be in a good agreement with the experimental data. Furthermore, we observe that, upon temperature increases, a low-frequency transverse phononic gap emerges while high-frequency propagating modes become evanescent at the THz scale. The effect of strong localization of a longitudinal phononic mode in the supercritical phase is observed for the first time. The evidence for the high-frequency transverse phononic gap due to the transition from an oscillatory to a ballistic dynamic regimes of motion is presented and supported by molecular dynamics simulations. This transition takes place across the Frenkel line thermodynamic limit which demarcates compressed liquid and non-compressed fluid domains on the phase diagram and is supported by calculations within the Green-Kubo phenomenological formalism. These results are crucial to advance the development of novel terahertz thermal devices, phononic lenses, mirrors, and other THz metamaterials.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1240873

Journal Information:: Scientific Reports, Vol. 6, Issue 108; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 26 works

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Emergence and Evolution of the $k$ Gap in Spectra of Liquid and Supercritical States Yang, C.; Dove, M. T.; Brazhkin, V. V. Physical Review Letters, Vol. 118, Issue 21 https://doi.org/10.1103/physrevlett.118.215502	journal	May 2017
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