Short- and long-range magnetic order in LaMnAsO
Abstract
The magnetic properties of the layered oxypnictide LaMnAsO have been revisited using neutron scattering and magnetization measurements. The present measurements identify the Néel temperature TN = 360(1) K. Below TN the critical exponent describing the magnetic order parameter is β=0.33–0.35 , consistent with a three-dimensional Heisenberg model. Above this temperature, diffuse magnetic scattering indicative of short-range magnetic order is observed, and this scattering persists up to TSRO = 650(10) K. Morevoer, the magnetic susceptibility shows a weak anomaly at TSRO and no anomaly at TN. Analysis of the diffuse scattering data using a reverse Monte Carlo algorithm indicates that above TN nearly two-dimensional, short-range magnetic order is present with a correlation length of 9.3(3) Å within the Mn layers at 400 K. The inelastic scattering data reveal a spin gap of 3.5 meV in the long-range ordered state, and strong, low-energy (quasielastic) magnetic excitations emerging in the short-range ordered state. When we compared it with other related compounds correlates the distortion of the Mn coordination tetrahedra to the sign of the magnetic exchange along the layer-stacking direction, and suggests that short-range order above TN is a common feature in the magnetic behavior of layered Mn-based pnictides and oxypnictides.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1237161
- Alternate Identifier(s):
- OSTI ID: 1236727
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 93; Journal Issue: 5; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS
Citation Formats
McGuire, Michael A., and Garlea, Vasile Ovidiu. Short- and long-range magnetic order in LaMnAsO. United States: N. p., 2016.
Web. doi:10.1103/PhysRevB.93.054404.
McGuire, Michael A., & Garlea, Vasile Ovidiu. Short- and long-range magnetic order in LaMnAsO. United States. https://doi.org/10.1103/PhysRevB.93.054404
McGuire, Michael A., and Garlea, Vasile Ovidiu. 2016.
"Short- and long-range magnetic order in LaMnAsO". United States. https://doi.org/10.1103/PhysRevB.93.054404. https://www.osti.gov/servlets/purl/1237161.
@article{osti_1237161,
title = {Short- and long-range magnetic order in LaMnAsO},
author = {McGuire, Michael A. and Garlea, Vasile Ovidiu},
abstractNote = {The magnetic properties of the layered oxypnictide LaMnAsO have been revisited using neutron scattering and magnetization measurements. The present measurements identify the Néel temperature TN = 360(1) K. Below TN the critical exponent describing the magnetic order parameter is β=0.33–0.35 , consistent with a three-dimensional Heisenberg model. Above this temperature, diffuse magnetic scattering indicative of short-range magnetic order is observed, and this scattering persists up to TSRO = 650(10) K. Morevoer, the magnetic susceptibility shows a weak anomaly at TSRO and no anomaly at TN. Analysis of the diffuse scattering data using a reverse Monte Carlo algorithm indicates that above TN nearly two-dimensional, short-range magnetic order is present with a correlation length of 9.3(3) Å within the Mn layers at 400 K. The inelastic scattering data reveal a spin gap of 3.5 meV in the long-range ordered state, and strong, low-energy (quasielastic) magnetic excitations emerging in the short-range ordered state. When we compared it with other related compounds correlates the distortion of the Mn coordination tetrahedra to the sign of the magnetic exchange along the layer-stacking direction, and suggests that short-range order above TN is a common feature in the magnetic behavior of layered Mn-based pnictides and oxypnictides.},
doi = {10.1103/PhysRevB.93.054404},
url = {https://www.osti.gov/biblio/1237161},
journal = {Physical Review B},
issn = {2469-9950},
number = 5,
volume = 93,
place = {United States},
year = {Tue Feb 02 00:00:00 EST 2016},
month = {Tue Feb 02 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Materials with ZrCuSiAs-type Structure
journal, October 2008
- Pöttgen, Rainer; Johrendt, Dirk
- Zeitschrift für Naturforschung B, Vol. 63, Issue 10
Quaternary rare earth transition metal arsenide oxides RTAsO (T=Fe, Ru, Co) with ZrCuSiAs type structure
journal, April 2000
- Quebe, P.; Terbüchte, L. J.; Jeitschko, W.
- Journal of Alloys and Compounds, Vol. 302, Issue 1-2
Iron-Based Layered Superconductor La[O 1- x F x ]FeAs ( x = 0.05−0.12) with T c = 26 K
journal, March 2008
- Kamihara, Yoichi; Watanabe, Takumi; Hirano, Masahiro
- Journal of the American Chemical Society, Vol. 130, Issue 11
Superconductivity at 41 K and Its Competition with Spin-Density-Wave Instability in Layered
journal, June 2008
- Chen, G. F.; Li, Z.; Wu, D.
- Physical Review Letters, Vol. 100, Issue 24
Superconductivity at 55 K in Iron-Based F-Doped Layered Quaternary Compound Sm[O 1- x F x ] FeAs
journal, May 2008
- Zhi-An, Ren; Wei, Lu; Jie, Yang
- Chinese Physics Letters, Vol. 25, Issue 6
Thorium-doping–induced superconductivity up to 56 K in Gd 1−x Th x FeAsO
journal, September 2008
- Wang, Cao; Li, Linjun; Chi, Shun
- EPL (Europhysics Letters), Vol. 83, Issue 6
Structural and 121Sb Mössbauer Spectroscopic Investigations of the Antimonide Oxides REMnSbO (RE = La, Ce, Pr, Nd, Sm, Gd, Tb) and REZnSbO (RE = La, Ce, Pr)
journal, July 2008
- Schellenberg, Inga; Nilges, Tom; Pöttgen, Rainer
- Zeitschrift für Naturforschung B, Vol. 63, Issue 7
Iron-Based Layered Superconductor: LaOFeP
journal, August 2006
- Kamihara, Yoichi; Hiramatsu, Hidenori; Hirano, Masahiro
- Journal of the American Chemical Society, Vol. 128, Issue 31
Evidence for a Nodal-Line Superconducting State in LaFePO
journal, April 2009
- Fletcher, J. D.; Serafin, A.; Malone, L.
- Physical Review Letters, Vol. 102, Issue 14
Synthesis, crystal structure and spin-density-wave anomaly of the iron arsenide-fluoride SrFeAsF
journal, December 2008
- Tegel, M.; Johansson, S.; Weiß, V.
- EPL (Europhysics Letters), Vol. 84, Issue 6
Cobalt-Substitution-Induced Superconductivity in a New Compound with ZrCuSiAs-Type Structure, SrFeAsF
journal, November 2008
- Matsuishi, Satoru; Inoue, Yasunori; Nomura, Takatoshi
- Journal of the Physical Society of Japan, Vol. 77, Issue 11
Superconductivity Induced by Co-Doping in Quaternary Fluoroarsenide CaFeAsF
journal, November 2008
- Matsuishi, Satoru; Inoue, Yasunori; Nomura, Takatoshi
- Journal of the American Chemical Society, Vol. 130, Issue 44
SrFeAsF as a parent compound for iron pnictide superconductors
journal, November 2008
- Han, Fei; Zhu, Xiyu; Mu, Gang
- Physical Review B, Vol. 78, Issue 18
Superconductivity in
journal, September 2008
- Sefat, Athena S.; Huq, Ashfia; McGuire, Michael A.
- Physical Review B, Vol. 78, Issue 10
Nd-induced Mn spin-reorientation transition in NdMnAsO
journal, November 2010
- Marcinkova, A.; Hansen, T. C.; Curfs, C.
- Physical Review B, Vol. 82, Issue 17
Giant magnetoresistance in oxypnictides (La,Nd)OMnAs
journal, January 2010
- Emery, Nicolas; Wildman, Eve J.; Skakle, Janet M. S.
- Chemical Communications, Vol. 46, Issue 36
A Magnetic Transition Probed by the Ce Ion in Square-Lattice Antiferromagnet CeMnAsO
journal, September 2011
- Tsukamoto, Yuto; Okamoto, Yoshihiko; Matsuhira, Kazuyuki
- Journal of the Physical Society of Japan, Vol. 80, Issue 9
Colossal Magnetoresistance in Mn 2+ Oxypnictides NdMnAsO 1– x F x
journal, May 2012
- Wildman, Eve J.; Skakle, Janet M. S.; Emery, Nicolas
- Journal of the American Chemical Society, Vol. 134, Issue 21
Itinerant ferromagnetism in the layered crystals
journal, June 2008
- Yanagi, Hiroshi; Kawamura, Ryuto; Kamiya, Toshio
- Physical Review B, Vol. 77, Issue 22
Magnetic properties of
journal, November 2009
- Ohta, Hiroto; Yoshimura, Kazuyoshi
- Physical Review B, Vol. 80, Issue 18
Magnetic phase transitions in NdCoAsO
journal, March 2010
- McGuire, Michael A.; Gout, Delphine J.; Garlea, V. Ovidiu
- Physical Review B, Vol. 81, Issue 10
Superconductivity in and rare-earth magnetic ordering in NdCoAsO
journal, February 2010
- Marcinkova, Andrea; Grist, David A. M.; Margiolaki, Irene
- Physical Review B, Vol. 81, Issue 6
Nickel-based layered superconductor, LaNiOAs
journal, August 2008
- Watanabe, Takumi; Yanagi, Hiroshi; Kamihara, Yoichi
- Journal of Solid State Chemistry, Vol. 181, Issue 8
Strong-coupling superconductivity in the nickel-based oxypnictide
journal, August 2008
- Li, Zheng; Chen, Gengfu; Dong, Jing
- Physical Review B, Vol. 78, Issue 6
Hydrogen substitution effect on the superconductivity of LnNiAsO (Ln = La–Nd)
journal, July 2012
- Matsuishi, Satoru; Nakamura, Atsushi; Muraba, Yoshinori
- Superconductor Science and Technology, Vol. 25, Issue 8
CeNiAsO: an antiferromagnetic dense Kondo lattice
journal, April 2011
- Luo, Yongkang; Han, Han; Tan, Hao
- Journal of Physics: Condensed Matter, Vol. 23, Issue 17
Competing magnetic phases and field-induced dynamics in DyRuAsO
journal, July 2014
- McGuire, Michael A.; Garlea, V. Ovidiu; May, Andrew F.
- Physical Review B, Vol. 90, Issue 1
Insulator-to-metal transition and large thermoelectric effect in La 1−x Sr x MnAsO
journal, April 2012
- Sun, Yun-Lei; Bao, Jin-Ke; Luo, Yong-Kang
- EPL (Europhysics Letters), Vol. 98, Issue 1
From antiferromagnetic insulator to ferromagnetic metal: Effects of hydrogen substitution in LaMnAsO
journal, January 2013
- Hanna, Taku; Matsuishi, Satoru; Kodama, Katsuaki
- Physical Review B, Vol. 87, Issue 2
Absence of Colossal Magnetoresistance in the Oxypnictide PrMnAsO 0.95 F 0.05
journal, February 2015
- Wildman, Eve J.; Sher, Falak; Mclaughlin, Abbie C.
- Inorganic Chemistry, Vol. 54, Issue 6
Epitaxial film growth and optoelectrical properties of layered semiconductors, LaMnXO (X=P, As, and Sb)
journal, April 2009
- Kayanuma, Kentaro; Hiramatsu, Hidenori; Kamiya, Toshio
- Journal of Applied Physics, Vol. 105, Issue 7
Control of spin in a La(Mn,Zn)AsO alloy by carrier doping
journal, January 2013
- Li, Xingxing; Wu, Xiaojun; Yang, Jinlong
- Journal of Materials Chemistry C, Vol. 1, Issue 43
Gap states in insulating LaMnPO F ( –0.3)
journal, October 2011
- Simonson, J. W.; Post, K.; Marques, C.
- Physical Review B, Vol. 84, Issue 16
Origin of the charge gap in LaMnPO
journal, November 2014
- McNally, D. E.; Simonson, J. W.; Post, K. W.
- Physical Review B, Vol. 90, Issue 18
Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO
journal, February 2015
- Zhang, Qiang; Tian, Wei; Peterson, Spencer G.
- Physical Review B, Vol. 91, Issue 6
Variable temperature study of the crystal and magnetic structures of the giant magnetoresistant materials MnAsO( La, Nd)
journal, April 2011
- Emery, N.; Wildman, E. J.; Skakle, J. M. S.
- Physical Review B, Vol. 83, Issue 14
Magnetic, transport, and thermal properties of single crystals of the layered arsenide
journal, March 2009
- Singh, Yogesh; Ellern, A.; Johnston, D. C.
- Physical Review B, Vol. 79, Issue 9
Magnetic order in from neutron diffraction measurements
journal, September 2009
- Singh, Yogesh; Green, M. A.; Huang, Q.
- Physical Review B, Vol. 80, Issue 10
Magnetic exchange interactions in : A case study of the - - Heisenberg model
journal, September 2011
- Johnston, D. C.; McQueeney, R. J.; Lake, B.
- Physical Review B, Vol. 84, Issue 9
New diluted ferromagnetic semiconductor with Curie temperature up to 180 K and isostructural to the ‘122’ iron-based superconductors
journal, February 2013
- Zhao, K.; Deng, Z.; Wang, X. C.
- Nature Communications, Vol. 4, Issue 1
Les points de transformation des composés définis MnAs, MnBi en relation avec un mécanisme probable d'antiferromagnétisme
journal, January 1951
- Guillaud, Charles
- Journal de Physique et le Radium, Vol. 12, Issue 3
Relation between Structural and Magnetic Properties of Compound MnAs 1- x P x (0≦ x ≦0.275)
journal, October 1982
- Suzuki, Takanobu; Ido, Hideaki
- Journal of the Physical Society of Japan, Vol. 51, Issue 10
Giant magnetocaloric effect of MnAs1−xSbx
journal, November 2001
- Wada, H.; Tanabe, Y.
- Applied Physics Letters, Vol. 79, Issue 20
Recent progress on HYSPEC, and its polarization analysis capabilities
journal, January 2015
- Winn, Barry; Filges, Uwe; Garlea, V. Ovidiu
- EPJ Web of Conferences, Vol. 83
spinvert: a program for refinement of paramagnetic diffuse scattering data
journal, October 2013
- Paddison, Joseph A. M.; Ross Stewart, J.; Goodwin, Andrew L.
- Journal of Physics: Condensed Matter, Vol. 25, Issue 45
Quaternary Equiatomic Manganese Pnictide Oxides AMnPO (A = La-Nd, Sm, Gd-Dy), AMnAsO (A = Y, La-Nd, Sm, Gd-Dy, U), and AMnSbO (A = La-Nd, Sm, Gd) with ZrCuSiAs Type Structure
journal, May 1997
- Nientiedt, Andre T.; Jeitschko, Wolfgang; Pollmeier, Peter G.
- Zeitschrift für Naturforschung B, Vol. 52, Issue 5
Phase transitions in LaFeAsO: Structural, magnetic, elastic, and transport properties, heat capacity and Mössbauer spectra
journal, September 2008
- McGuire, Michael A.; Christianson, Andrew D.; Sefat, Athena S.
- Physical Review B, Vol. 78, Issue 9
Antiferromagnetic bipolar semiconductor LaMnPO with ZrCuSiAs-type structure
journal, May 2009
- Yanagi, Hiroshi; Watanabe, Takumi; Kodama, Katsuaki
- Journal of Applied Physics, Vol. 105, Issue 9
Local moments and symmetry breaking in metallic PrMnSbO
journal, September 2010
- Kimber, Simon A. J.; Hill, Adrian H.; Zhang, Yu-Zhong
- Physical Review B, Vol. 82, Issue 10
Crystal, magnetic and electronic structures and properties of new BaMnPnF (Pn = As, Sb, Bi)
journal, July 2013
- Saparov, Bayrammurad; Singh, David J.; Garlea, Vasile O.
- Scientific Reports, Vol. 3, Issue 1
Resistivity and Magnetism of AMn2P2 (A = Sr, Ba): The Effect of Structure Type on Physical Properties
journal, December 1994
- Brock, Stephanie L.; Greedan, J. E.; Kauzlarich, Susan M.
- Journal of Solid State Chemistry, Vol. 113, Issue 2
Magnetic properties of mixed crystals with NiAs‐type structure
journal, April 1985
- Ido, H.
- Journal of Applied Physics, Vol. 57, Issue 8
The Magnetic Susceptibility of MnO as a Function of the Temperature
journal, November 1933
- Tyler, Rayen Welch
- Physical Review, Vol. 44, Issue 9
Persistence of local-moment antiferromagnetic order in Ba K Mn As
journal, April 2013
- Lamsal, J.; Tucker, G. S.; Heitmann, T. W.
- Physical Review B, Vol. 87, Issue 14
From antiferromagnetic insulator to correlated metal in pressurized and doped LaMnPO
journal, May 2012
- Simonson, J. W.; Yin, Z. P.; Pezzoli, M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 27
Iron-Based Layered Superconductor: LaOFeP.
journal, November 2006
- Kamihara, Yoichi; Hiramatsu, Hidenori; Hirano, Masahiro
- ChemInform, Vol. 37, Issue 45
Cobalt-substitution-induced Superconductivity in a New Compound with ZrCuSiAs-type Structure, SrFeAsF
text, January 2008
- Matsuishi, Satoru; Inoue, Yasunori; Nomura, Takatoshi
- arXiv
Electronic structure and Magnetism in BaMn$_2$As$_2$ and BaMn$_2$Sb$_2$
text, January 2009
- an, J.; Sefat, A. S.; Singh, D. J.
- arXiv
Magnetic Phase Transitions in NdCoAsO
text, January 2009
- McGuire, Michael A.; Gout, Delphine J.; Garlea, V. Ovidiu
- arXiv
Local moments and symmetry breaking in metallic PrMnSbO
text, January 2010
- Kimber, Simon A. J.; Hill, Adrian H.; Zhang, Yu-Zhong
- arXiv
Nd induced Mn spin-reorientation transition in NdMnAsO
text, January 2010
- Marcinkova, A.; Hansen, T. C.; Curfs, C.
- arXiv
A Magnetic Transition Probed by the Ce Ion in Square-Lattice Antiferromagnet CeMnAsO
text, January 2011
- Tsukamoto, Yuto; Okamoto, Yoshihiko; Matsuhira, Kazuyuki
- arXiv
Insulator-to-metal transition and large thermoelectric effect in La$_{1-x}$Sr$_{x}$MnAsO
text, January 2011
- Sun, Yunlei; Bao, Jinke; Feng, Chunmu
- arXiv
Crystal, magnetic, and electronic structures, and properties of new BaMnPnF (Pn = As, Sb, Bi)
text, January 2013
- Saparov, Bayrammurad; Singh, David J.; Garlea, V. Ovidiu
- arXiv
Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO
text, January 2014
- Zhang, Qiang; Tian, Wei; Peterson, Spencer G.
- arXiv
Works referencing / citing this record:
Magnetolattice coupling, magnetic frustration, and magnetoelectric effect in the Cr-doped multiferroic material and their correlation with structural phase transitions
journal, July 2019
- Bera, Ganesh; Surampalli, Akash; Mishra, Aradhya
- Physical Review B, Vol. 100, Issue 1
Long- and short-range magnetism in the frustrated double perovskite
journal, January 2020
- Mutch, Heather; Mustonen, Otto; Walker, Helen C.
- Physical Review Materials, Vol. 4, Issue 1
Detecting magnetic ordering with atomic size electron probes
journal, May 2016
- Idrobo, Juan Carlos; Rusz, Ján; Spiegelberg, Jakob
- Advanced Structural and Chemical Imaging, Vol. 2, Issue 1