A high performance hybrid battery based on aluminum anode and LiFePO4 cathode

Sun, Xiao-Guang; Bi, Zhonghe; Liu, Hansan; Bridges, Craig A.; Paranthaman, Mariappan Parans; Dai, Sheng; Brown, Gilbert M.

doi:10.1039/C5CC09019A

Title: A high performance hybrid battery based on aluminum anode and LiFePO₄ cathode

Journal Article · Mon Dec 07 00:00:00 EST 2015 · ChemComm

DOI:https://doi.org/10.1039/C5CC09019A· OSTI ID:1237159

Sun, Xiao-Guang ^[1]; Bi, Zhonghe ^[1]; Liu, Hansan ^[1]; Bridges, Craig A. ^[1]; Paranthaman, Mariappan Parans ^[1]; Dai, Sheng ^[2]; Brown, Gilbert M. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

A unique battery hybrid utilizes an aluminum anode, a LiFePO₄ cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl ₃) (EMImCl-AlCl ₃, 1-1.1 in molar ratio) with or without LiAlCl₄ is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g^-1 at a current rate of C/5. It also shows good rate capability and cycling performance.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1237159

Journal Information:: ChemComm, Vol. 52, Issue 8; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 45 works

Citation information provided by
Web of Science

References (37)

Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Sodium and sodium-ion energy storage batteries Ellis, Brian L.; Nazar, Linda F. Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177 https://doi.org/10.1016/j.cossms.2012.04.002	journal	August 2012
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan Energy & Environmental Science, Vol. 6, Issue 8 https://doi.org/10.1039/c3ee40847g	journal	January 2013
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721 https://doi.org/10.1002/aenm.201200026	journal	May 2012
Research Development on Sodium-Ion Batteries Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500192f	journal	October 2014
Rechargeable magnesium battery: Current status and key challenges for the future Saha, Partha; Datta, Moni Kanchan; Velikokhatnyi, Oleg I. Progress in Materials Science, Vol. 66 https://doi.org/10.1016/j.pmatsci.2014.04.001	journal	October 2014
Magnesium batteries: Current state of the art, issues and future perspectives Mohtadi, Rana; Mizuno, Fuminori Beilstein Journal of Nanotechnology, Vol. 5 https://doi.org/10.3762/bjnano.5.143	journal	January 2014
Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500049y	journal	October 2014
Mg rechargeable batteries: an on-going challenge Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279 https://doi.org/10.1039/c3ee40871j	journal	January 2013
An ultrafast rechargeable aluminium-ion battery Lin, Meng-Chang; Gong, Ming; Lu, Bingan Nature, Vol. 520, Issue 7547 https://doi.org/10.1038/nature14340	journal	April 2015
Aluminum as anode for energy storage and conversion: a review Li, Qingfeng; Bjerrum, Niels J. Journal of Power Sources, Vol. 110, Issue 1, p. 1-10 https://doi.org/10.1016/S0378-7753(01)01014-X	journal	July 2002
A concept of dual-salt polyvalent-metal storage battery Yagi, Shunsuke; Ichitsubo, Tetsu; Shirai, Yoshimasa J. Mater. Chem. A, Vol. 2, Issue 4 https://doi.org/10.1039/C3TA13668J	journal	January 2014
Electrodeposition of Aluminum from the Aluminum Chloride-1-Methyl-3-ethylimidazolium Chloride Room Temperature Molten Salt + Benzene Liao, Qing Journal of The Electrochemical Society, Vol. 144, Issue 3 https://doi.org/10.1149/1.1837510	journal	January 1997
Electrodeposition of aluminium from nonaqueous organic electrolytic systems and room temperature molten salts Zhao, Yuguang; VanderNoot, T. J. Electrochimica Acta, Vol. 42, Issue 1 https://doi.org/10.1016/0013-4686(96)00080-1	journal	January 1997
The Roles of V ₂ O ₅ and Stainless Steel in Rechargeable Al–Ion Batteries Reed, Luke D.; Menke, Erik Journal of The Electrochemical Society, Vol. 160, Issue 6 https://doi.org/10.1149/2.114306jes	journal	January 2013
Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4− and comparison with imidazolium based systems Abood, Hadi M. A.; Abbott, Andrew P.; Ballantyne, Andrew D. Chemical Communications, Vol. 47, Issue 12 https://doi.org/10.1039/c0cc04989a	journal	January 2011
Ionic Liquids: Solvents for the Electrodeposition of Metals and Semiconductors Endres, Frank ChemPhysChem, Vol. 3, Issue 2 https://doi.org/10.1002/1439-7641(20020215)3:2<144::AID-CPHC144>3.0.CO;2-#	journal	February 2002
Electrodeposition of Metals and Semiconductors in Air- and Water-Stable Ionic Liquids Zein El Abedin, Sherif; Endres, Frank ChemPhysChem, Vol. 7, Issue 1 https://doi.org/10.1002/cphc.200500288	journal	January 2006
Aluminium electrodeposition under ambient conditions Abbott, Andrew P.; Harris, Robert C.; Hsieh, Yi-Ting Phys. Chem. Chem. Phys., Vol. 16, Issue 28 https://doi.org/10.1039/C4CP01508H	journal	January 2014
Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides Coleman, Fergal; Srinivasan, Geetha; Swadźba-Kwaśny, Małgorzata Angewandte Chemie International Edition, Vol. 52, Issue 48 https://doi.org/10.1002/anie.201306267	journal	October 2013
New ionic liquids based on the complexation of dipropyl sulfide and AlCl ₃ for electrodeposition of aluminum Fang, Youxing; Jiang, Xueguang; Sun, Xiao-Guang Chemical Communications, Vol. 51, Issue 68 https://doi.org/10.1039/C5CC05233E	journal	January 2015
An AlCl3 based ionic liquid with a neutral substituted pyridine ligand for electrochemical deposition of aluminum Fang, Youxing; Yoshii, Kazuki; Jiang, Xueguang Electrochimica Acta, Vol. 160 https://doi.org/10.1016/j.electacta.2015.02.020	journal	April 2015
Sulfone-based electrolytes for aluminium rechargeable batteries Nakayama, Yuri; Senda, Yui; Kawasaki, Hideki Physical Chemistry Chemical Physics, Vol. 17, Issue 8 https://doi.org/10.1039/C4CP02183E	journal	January 2015
Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries Sun, Xiao-Guang; Fang, Youxing; Jiang, Xueguang Chemical Communications, Vol. 52, Issue 2, p. 292-295 https://doi.org/10.1039/C5CC06643C	journal	January 2016
The rechargeable aluminum-ion battery Jayaprakash, N.; Das, S. K.; Archer, L. A. Chemical Communications, Vol. 47, Issue 47 https://doi.org/10.1039/c1cc15779e	journal	January 2011
Fluorinated Natural Graphite Cathode for Rechargeable Ionic Liquid Based Aluminum–Ion Battery Rani, J. Vatsala; Kanakaiah, V.; Dadmal, Tulshiram Journal of The Electrochemical Society, Vol. 160, Issue 10 https://doi.org/10.1149/2.072310jes	journal	January 2013
Chloroaluminate-Doped Conducting Polymers as Positive Electrodes in Rechargeable Aluminum Batteries Hudak, Nicholas S. The Journal of Physical Chemistry C, Vol. 118, Issue 10 https://doi.org/10.1021/jp500593d	journal	March 2014
Binder-Free V ₂ O ₅ Cathode for Greener Rechargeable Aluminum Battery Wang, Huali; Bai, Ying; Chen, Shi ACS Applied Materials & Interfaces, Vol. 7, Issue 1 https://doi.org/10.1021/am508001h	journal	December 2014
Reversible Electrochemical Intercalation of Aluminum in Mo ₆ S ₈ Geng, Linxiao; Lv, Guocheng; Xing, Xuebing Chemistry of Materials, Vol. 27, Issue 14 https://doi.org/10.1021/acs.chemmater.5b01918	journal	July 2015
A new aluminium-ion battery with high voltage, high safety and low cost Sun, Haobo; Wang, Wei; Yu, Zhijing Chemical Communications, Vol. 51, Issue 59 https://doi.org/10.1039/C5CC00542F	journal	January 2015
Reversible Aluminum-Ion Intercalation in Prussian Blue Analogs and Demonstration of a High-Power Aluminum-Ion Asymmetric Capacitor Li, Zheng; Xiang, Kai; Xing, Wenting Advanced Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aenm.201401410	journal	November 2014
Cyclic chronopotentiometric studies of the LiAl anode in methyl acetate Fung, Y. S.; Lai, H. C. Journal of Applied Electrochemistry, Vol. 19, Issue 2 https://doi.org/10.1007/BF01062307	journal	March 1989
High performance batteries based on hybrid magnesium and lithium chemistry Cheng, Yingwen; Shao, Yuyan; Zhang, Ji-Guang Chem. Commun., Vol. 50, Issue 68 https://doi.org/10.1039/C4CC03620D	journal	January 2014
Ionic-liquid materials for the electrochemical challenges of the future Armand, Michel; Endres, Frank; MacFarlane, Douglas R. Nature Materials, Vol. 8, Issue 8, p. 621-629 https://doi.org/10.1038/nmat2448	journal	July 2009
Electrochemical investigations of ionic liquids with vinylene carbonate for applications in rechargeable lithium ion batteries Sun, Xiao-Guang; Dai, Sheng Electrochimica Acta, Vol. 55, Issue 15, p. 4618-4626 https://doi.org/10.1016/j.electacta.2010.03.019	journal	June 2010
Bicyclic imidazolium ionic liquids as potential electrolytes for rechargeable lithium ion batteries Sun, Xiao-Guang; Liao, Chen; Shao, Nan Journal of Power Sources, Vol. 237 https://doi.org/10.1016/j.jpowsour.2013.02.061	journal	September 2013
Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides Coleman, Fergal; Srinivasan, Geetha; Swadźba-Kwaśny, Małgorzata Angewandte Chemie, Vol. 125, Issue 48 https://doi.org/10.1002/ange.201306267	journal	October 2013

Cited By (11)

Emerging Nonaqueous Aluminum-Ion Batteries: Challenges, Status, and Perspectives Zhang, Yu; Liu, Shiqi; Ji, Yongjun Advanced Materials, Vol. 30, Issue 38 https://doi.org/10.1002/adma.201706310	journal	June 2018
Paving the Path toward Reliable Cathode Materials for Aluminum-Ion Batteries Wu, Feng; Yang, Haoyi; Bai, Ying Advanced Materials, Vol. 31, Issue 16 https://doi.org/10.1002/adma.201806510	journal	February 2019
Trends in Aluminium-Based Intercalation Batteries Ambroz, Filip; Macdonald, Thomas J.; Nann, Thomas Advanced Energy Materials, Vol. 7, Issue 15 https://doi.org/10.1002/aenm.201602093	journal	March 2017
Die wiederaufladbare Aluminiumbatterie: Möglichkeiten und Herausforderungen Yang, Huicong; Li, Hucheng; Li, Juan Angewandte Chemie, Vol. 131, Issue 35 https://doi.org/10.1002/ange.201814031	journal	June 2019
The Rechargeable Aluminum Battery: Opportunities and Challenges Yang, Huicong; Li, Hucheng; Li, Juan Angewandte Chemie International Edition, Vol. 58, Issue 35 https://doi.org/10.1002/anie.201814031	journal	August 2019
Stable Performance of Aluminum-Metal Battery by Incorporating Lithium-Ion Chemistry Yoo, Dong-Joo; Kim, Joo-Seong; Shin, Jaeho ChemElectroChem, Vol. 4, Issue 9 https://doi.org/10.1002/celc.201700271	journal	May 2017
Synthesis and Characterization of Bromoaluminate Ionic Liquids Hog, Michael; Schneider, Marius; Krossing, Ingo Chemistry - A European Journal, Vol. 23, Issue 41 https://doi.org/10.1002/chem.201700105	journal	June 2017
Critical Role of pH Evolution of Electrolyte in the Reaction Mechanism for Rechargeable Zinc Batteries Lee, Boeun; Seo, Hyo Ree; Lee, Hae Ri ChemSusChem, Vol. 9, Issue 20 https://doi.org/10.1002/cssc.201600702	journal	September 2016
Ion Dynamics in Ionic-Liquid-Based Li-Ion Electrolytes Investigated by Neutron Scattering and Dielectric Spectroscopy Jafta, Charl J.; Bridges, Craig; Haupt, Leon ChemSusChem, Vol. 11, Issue 19 https://doi.org/10.1002/cssc.201801321	journal	September 2018
Design and modification of cathode materials for high energy density aluminum-ion batteries: a review Li, Changgang; Zhang, Xudong; He, Wen Journal of Materials Science: Materials in Electronics, Vol. 29, Issue 16 https://doi.org/10.1007/s10854-018-9478-1	journal	June 2018
The O ₂ -assisted Al/CO ₂ electrochemical cell: A system for CO ₂ capture/conversion and electric power generation Al Sadat, Wajdi I.; Archer, Lynden A. Science Advances, Vol. 2, Issue 7 https://doi.org/10.1126/sciadv.1600968	journal	July 2016

Similar Records

A sodium–aluminum hybrid battery

Journal Article · Tue Mar 07 00:00:00 EST 2017 · Journal of Materials Chemistry. A · OSTI ID:1237159

Sun, Xiao-Guang; Zhang, Zhizhen; Guan, Hong Yu; +5 more

Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries

Journal Article · Thu Oct 22 00:00:00 EDT 2015 · ChemComm · OSTI ID:1237159

Sun, Xiao -Guang; Fang, Youxing; Jiang, Xueguang; +3 more

Rechargeable aluminum batteries: effects of cations in ionic liquid electrolytes

Journal Article · Thu Apr 11 00:00:00 EDT 2019 · RSC Advances · OSTI ID:1237159

Zhu, Guanzhou; Angell, Michael; Pan, Chun-Jern; +8 more

Related Subjects

25 ENERGY STORAGE

Title: A high performance hybrid battery based on aluminum anode and LiFePO4 cathode

Citation Formats

References (37)

Cited By (11)

Similar Records

Related Subjects

Title: A high performance hybrid battery based on aluminum anode and LiFePO₄ cathode