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Title: Elevated temperature tribology of cobalt and tantalum-based alloys

Journal Article · · Wear
 [1];  [2];  [2];  [2];  [2]
  1. Univ. of North Texas, Denton, TX (United States)
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

This paper describes the friction and wear behavior of a Co–Cr alloy sliding on a Ta–W alloy. Measurements were performed in a pin-on-flat configuration with a hemispherically tipped Co-base alloy pin sliding on a Ta–W alloy flat from ambient to 430°C. Focused ion beam-scanning electron microscopy (FIB-SEM) and cross-sectional transmission electron microscopy (TEM) were used to identify the friction-induced changes to the chemistry and crystal structure in the subsurface regions of wear tracks. During sliding contact, transfer of material varied as a function of the test temperature, either from pin-to-flat, flat-to-pin, or both, resulting in either wear loss and/or volume gain. Friction coefficients (μ) and wear rates also varied as a function of test temperature. The lowest friction coefficient (μ=0.25) and wear rate (1×10–4 mm3/N•m) were observed at 430°C in argon atmosphere. This was attributed to the formation of a Co-base metal oxide layer (glaze), predominantly (Co, Cr)O with Rocksalt crystal structure, on the pin surface. Part of this oxide film transferred to the wear track on Ta–W, providing a self-mated oxide-on-oxide contact. Once the oxide glaze is formed, it is able to provide friction reduction for the entire temperature range of this study, ambient to 430°C. Furthermore, the results of this study indicate that glazing the surfaces of Haynes alloys with continuous layers of cobalt chrome oxide prior to wear could protect the cladded surfaces from damage.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1235348
Alternate ID(s):
OSTI ID: 1433746
Report Number(s):
SAND-2014-17398J; PII: S0043164815000046
Journal Information:
Wear, Vol. 330-331, Issue C; ISSN 0043-1648
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 27 works
Citation information provided by
Web of Science

References (15)

Sliding Characteristics of Metals at High Temperatures journal January 1960
High-temperature sliding wear of metals journal August 2002
Studies of the Unlubricated Wear of a Commercial Cobalt-Base Alloy at Temperatures up to about 400 C journal January 1976
Friction and wear properties of Stellite 31 at temperatures from 293 to 1073K journal January 1977
Investigation into the wear behaviour of Stellite 6 during rotation as an unlubricated bearing at 600°C journal November 2011
Elevated-temperature tribology of metallic materials journal July 2010
A generic model for dry sliding wear of metals at elevated temperatures journal May 2004
On the fcc → hcp transformation in a cobalt-base superalloy (Haynes alloy No. 25) journal March 1986
Automated Analysis of SEM X-Ray Spectral Images: A Powerful New Microanalysis Tool journal January 2003
The influence of phase transformations and oxidation on the galling resistance and low friction behaviour of a laser processed Co-based alloy journal October 2003
Wear mechanisms and in-service surface modifications of a Stellite 6B Co–Cr alloy journal June 2012
Surface modifications in tribological contacts journal February 2009
Deformation behavior of the cobalt-based superalloy Haynes 25: Experimental characterization and crystal plasticity modeling journal January 2014
Adhesive wear of nickel- and cobalt-base alloys journal April 1980
Solid lubricants: a review journal December 2012

Cited By (1)

Friction and Wear Characteristics of Single Crystal Ni-Based Superalloys at Elevated Temperatures journal February 2018