Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO3− aerosol during the 2013 Southern Oxidant and Aerosol Study

Allen, H. M.; Draper, D. C.; Ayres, B. R.; Ault, A.; Bondy, A.; Takahama, S.; Modini, R. L.; Baumann, K.; Edgerton, E.; Knote, C.; Laskin, A.; Wang, B.; Fry, J. L.

doi:10.5194/acp-15-10669-2015

Title: Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO₃⁻ aerosol during the 2013 Southern Oxidant and Aerosol Study

Journal Article · Fri Sep 25 00:00:00 EDT 2015 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-15-10669-2015· OSTI ID:1229924

Allen, H. M. ^[1]; Draper, D. C. ^[2]; Ayres, B. R. ^[3]; Ault, A. ^[4]; Bondy, A. ^[4];

^[5]; Modini, R. L. ^[5]; Baumann, K. ^[6]; Edgerton, E. ^[6]; Knote, C. ^[7]; Laskin, A. ^[8]; Wang, B. ^[8]; Fry, J. L. ^[3]

Reed College, Portland, OR (United States); California Inst. of Technology (CalTech), Pasadena, CA (United States)
Reed College, Portland, OR (United States); Univ. of California, Irvine, CA (United States)
Reed College, Portland, OR (United States)
Univ. of Michigan, Ann Arbor, MI (United States)
Ecole Polytechnique Federale Lausanne, Lausanne (Switzlerland)
Atmospheric Research & Analysis, Inc., Cary, NC (United States)
Ludwig-Maximilians-Univ., Munich (Germany)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Inorganic aerosol composition was measured in the southeastern United States, a region that exhibits high aerosol mass loading during the summer, as part of the 2013 Southern Oxidant and Aerosol Study (SOAS) campaign. Measurements using a Monitor for AeRosols and GAses (MARGA) revealed two periods of high aerosol nitrate (NO₃⁻) concentrations during the campaign. These periods of high nitrate were correlated with increased concentrations of supermicron crustal and sea spray aerosol species, particularly Na⁺ and Ca²⁺, and with a shift towards aerosol with larger (1 to 2.5 μm) diameters. We suggest this nitrate aerosol forms by multiphase reactions of HNO₃ and particles, reactions that are facilitated by transport of crustal dust and sea spray aerosol from a source within the United States. The observed high aerosol acidity prevents the formation of NH₄NO₃, the inorganic nitrogen species often dominant in fine-mode aerosol at higher pH. In addition, calculation of the rate of the heterogeneous uptake of HNO₃ on mineral aerosol supports the conclusion that aerosol NO₃⁻ is produced primarily by this process, and is likely limited by the availability of mineral cation-containing aerosol surface area. Modeling of NO₃⁻ and HNO₃ by thermodynamic equilibrium models (ISORROPIA II and E-AIM) reveals the importance of including mineral cations in the southeastern United States to accurately balance ion species and predict gas–aerosol phase partitioning.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1229924

Report Number(s):: PNNL-SA-108640; 47887; 48347; KP1704020

Journal Information:: Atmospheric Chemistry and Physics (Online), Vol. 15, Issue 18; ISSN 1680-7324

Publisher:: European Geosciences UnionCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 50 works

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Chromatography related performance of the Monitor for AeRosols and GAses in ambient air (MARGA): laboratory and field-based evaluation Chen, Xi; Walker, John T.; Geron, Chris Atmospheric Measurement Techniques, Vol. 10, Issue 10 https://doi.org/10.5194/amt-10-3893-2017	journal	January 2017
A simplified parameterization of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) for global chemistry and climate models: a case study with GEOS-Chem v11-02-rc Jo, Duseong S.; Hodzic, Alma; Emmons, Louisa K. Geoscientific Model Development, Vol. 12, Issue 7 https://doi.org/10.5194/gmd-12-2983-2019	journal	January 2019
Computer-Controlled Raman Microspectroscopy (CC-Raman): A Method for the Rapid Characterization of Individual Atmospheric Aerosol Particles Craig, Rebecca L.; Bondy, Amy L.; Ault, Andrew P. Taylor & Francis https://doi.org/10.6084/m9.figshare.5056477.v1	text	January 2017
Computer-controlled Raman microspectroscopy (CC-Raman): A method for the rapid characterization of individual atmospheric aerosol particles Craig, Rebecca L.; Bondy, Amy L.; Ault, Andrew P. Aerosol Science and Technology, Vol. 51, Issue 9 https://doi.org/10.1080/02786826.2017.1337268	journal	May 2017

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Title: Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO3− aerosol during the 2013 Southern Oxidant and Aerosol Study

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Title: Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO₃⁻ aerosol during the 2013 Southern Oxidant and Aerosol Study