O3-type layered transition metal oxide Na(NiCoFeTi)1/4O2 as a high rate and long cycle life cathode material for sodium ion batteries

Yue, Ji -Li; Yang, Xiao -Qing; Zhou, Yong -Ning; Yu, Xiqian; Bak, Seong -Min; Fu, Zheng -Wen

doi:10.1039/C5TA05769H

Title: O3-type layered transition metal oxide Na(NiCoFeTi)_1/4O₂ as a high rate and long cycle life cathode material for sodium ion batteries

Journal Article · Fri Oct 09 00:00:00 EDT 2015 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C5TA05769H· OSTI ID:1228845

Yue, Ji -Li ^[1]; Yang, Xiao -Qing ^[2]; Zhou, Yong -Ning ^[3]; Yu, Xiqian ^[2]; Bak, Seong -Min ^[2]; Fu, Zheng -Wen ^[1]

Fudan Univ., Shanghai (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Fudan Univ., Shanghai (China); Brookhaven National Lab. (BNL), Upton, NY (United States)

High rate capability and long cycle life are challenging goals for the development of room temperature sodium-ion batteries. Here we report a new single phase quaternary O3-type layer-structured transition metal oxide Na(NiCoFeTi)_1/4O₂ synthesized by a simple solid-state reaction as a new cathode material for sodium-ion batteries. It can deliver a reversible capacity of 90.6 mA h g^–1 at a rate as high as 20C. At 5C, 75.0% of the initial specific capacity can be retained after 400 cycles with a capacity-decay rate of 0.07% per cycle, demonstrating a superior long-term cyclability at high current density. X-ray diffraction and absorption characterization revealed reversible phase transformations and electronic structural changes during the Na⁺ deintercalation/intercalation process. Ni, Co and Fe ions contribute to charge compensation during charge and discharge. Although Ti ions do not contribute to the charge transfer, they play a very important role in stabilizing the structure during charge and discharge by suppressing the Fe migration. Additionally, Ti substitution can also smooth the charge–discharge plateaus effectively, which provides a potential advantage for the commercialization of this material for room temperature sodium-ion batteries.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1228845

Report Number(s):: BNL-108557-2015-JA; JMCAET; R&D Project: MA453MAEA; VT0301010

Journal Information:: Journal of Materials Chemistry. A, Vol. 3, Issue 46; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 82 works

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Title: O3-type layered transition metal oxide Na(NiCoFeTi)1/4O2 as a high rate and long cycle life cathode material for sodium ion batteries

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Title: O3-type layered transition metal oxide Na(NiCoFeTi)_1/4O₂ as a high rate and long cycle life cathode material for sodium ion batteries