Phase transition in bulk single crystals and thin films of VO2 by nanoscale infrared spectroscopy and imaging

Liu, Mengkun; Sternbach, Aaron J.; Wagner, Martin; Slusar, Tetiana V.; Kong, Tai; Bud'ko, Sergey L.; Kittiwatanakul, Salinporn; Qazilbash, M. M.; McLeod, Alexander; Fei, Zhe; Abreu, Elsa; Zhang, Jingdi; Goldflam, Michael; Dai, Siyuan; Ni, Guang -Xin; Lu, Jiwei; Bechtel, Hans A.; Martin, Michael C.; Raschke, Markus B.; Averitt, Richard D.; Wolf, Stuart A.; Kim, Hyun -Tak; Canfield, Paul C.; Basov, D. N.

doi:10.1103/PhysRevB.91.245155

Title: Phase transition in bulk single crystals and thin films of $V O_{2}$ by nanoscale infrared spectroscopy and imaging

Journal Article · Mon Jun 29 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.91.245155· OSTI ID:1227379

Liu, Mengkun ^[1]; Sternbach, Aaron J. ^[2]; Wagner, Martin ^[2]; Slusar, Tetiana V. ^[3]; Kong, Tai ^[4]; Bud'ko, Sergey L. ^[4]; Kittiwatanakul, Salinporn ^[5]; Qazilbash, M. M. ^[6]; McLeod, Alexander ^[2]; Fei, Zhe ^[2]; Abreu, Elsa ^[7]; Zhang, Jingdi ^[8]; Goldflam, Michael ^[2]; Dai, Siyuan ^[2]; Ni, Guang -Xin ^[2]; Lu, Jiwei ^[5]; Bechtel, Hans A. ^[9]; Martin, Michael C. ^[9]; Raschke, Markus B. ^[10]; Averitt, Richard D. ^[2] more »

Univ. of California at San Diego, La Jolla, CA (United States); Stony Brook Univ., Stony Brook, NY (United States)
Univ. of California at San Diego, La Jolla, CA (United States)
Metal-Insulator Transition Creative Research Center, Daejeon (South Korea)
Iowa State Univ., Ames, IA (United States)
Univ. of Virginia, Charlottesville, VA (United States)
College of William and Mary, Williamsburg, VA (United States)
Boston Univ., Boston, MA (United States); ETH Zurich, Zurich (Switzerland)
Univ. of California at San Diego, La Jolla, CA (United States); Boston Univ., Boston, MA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of Colorado, Boulder, CO (United States)
Metal-Insulator Transition Creative Research Center, Daejeon (South Korea); Korean Univ. of Science and Technology, Daejeon (South Korea)

We have systematically studied a variety of vanadium dioxide (VO₂) crystalline forms, including bulk single crystals and oriented thin films, using infrared (IR) near-field spectroscopic imaging techniques. By measuring the IR spectroscopic responses of electrons and phonons in VO₂ with sub-grain-size spatial resolution (~20nm), we show that epitaxial strain in VO₂ thin films not only triggers spontaneous local phase separations, but leads to intermediate electronic and lattice states that are intrinsically different from those found in bulk. Generalized rules of strain- and symmetry-dependent mesoscopic phase inhomogeneity are also discussed. Furthermore, these results set the stage for a comprehensive understanding of complex energy landscapes that may not be readily determined by macroscopic approaches.

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Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: W911NF-13-1-0210; AC02-05CH11231; AC02-07CH11358; SC0012592; FG02-09ER46643; 1255156

OSTI ID:: 1227379

Alternate ID(s):: OSTI ID: 1198608

Report Number(s):: IS-J-8721; PRBMDO

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 91, Issue 24; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 63 works

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References (74)

Polycrystalline Macro-Domains Formed by Self-Organization of Ferroelectric Grains Lyahovitskaya, V.; Feldman, Y.; Zon, I. Advanced Materials, Vol. 17, Issue 16 https://doi.org/10.1002/adma.200402083	journal	August 2005
Emergent phenomena at oxide interfaces Hwang, H. Y.; Iwasa, Y.; Kawasaki, M. Nature Materials, Vol. 11, Issue 2 https://doi.org/10.1038/nmat3223	journal	January 2012
Oxides Which Show a Metal-to-Insulator Transition at the Neel Temperature Morin, F. J. Physical Review Letters, Vol. 3, Issue 1 https://doi.org/10.1103/PhysRevLett.3.34	journal	July 1959
Doubling the critical temperature of La1.9Sr0.1CuO4 using epitaxial strain Locquet, J. -P.; Perret, J.; Fompeyrine, J. Nature, Vol. 394, Issue 6692 https://doi.org/10.1038/28810	journal	July 1998
Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures Wang, J.; Neaton, J. B.; Zheng, H. Science, Vol. 299, Issue 5613, p. 1719-1722 https://doi.org/10.1126/science.1080615	journal	March 2003
Strain effects in low-dimensional transition metal oxides Cao, Jinbo; Wu, Junqiao Materials Science and Engineering: R: Reports, Vol. 71, Issue 2-4 https://doi.org/10.1016/j.mser.2010.08.001	journal	January 2011
Light-Induced Superconductivity in a Stripe-Ordered Cuprate Fausti, D.; Tobey, R. I.; Dean, N. Science, Vol. 331, Issue 6014 https://doi.org/10.1126/science.1197294	journal	January 2011
Terahertz-field-induced insulator-to-metal transition in vanadium dioxide metamaterial Liu, Mengkun; Hwang, Harold Y.; Tao, Hu Nature, Vol. 487, Issue 7407 https://doi.org/10.1038/nature11231	journal	July 2012
Electrodynamics of correlated electron materials Basov, D. N.; Averitt, Richard D.; van der Marel, Dirk Reviews of Modern Physics, Vol. 83, Issue 2 https://doi.org/10.1103/RevModPhys.83.471	journal	June 2011
Colossal magnetoresistant materials: the key role of phase separation Dagotto, Elbio; Hotta, Takashi; Moreo, Adriana Physics Reports, Vol. 344, Issue 1-3 https://doi.org/10.1016/S0370-1573(00)00121-6	journal	April 2001
Viewpoints on Microscopic and Mesoscopic Transformation Processes in Martensite Krumhansl, J. A. Le Journal de Physique IV, Vol. 05, Issue C2 https://doi.org/10.1051/jp4:1995201	journal	February 1995
Mesoscopic Percolating Resistance Network in a Strained Manganite Thin Film Lai, K.; Nakamura, M.; Kundhikanjana, W. Science, Vol. 329, Issue 5988 https://doi.org/10.1126/science.1189925	journal	July 2010
Mott Transition in VO2 Revealed by Infrared Spectroscopy and Nano-Imaging Qazilbash, M. M.; Brehm, M.; Chae, B. -G. Science, Vol. 318, Issue 5857 https://doi.org/10.1126/science.1150124	journal	December 2007
Intrinsic Inhomogeneities in Manganite Thin Films Investigated with Scanning Tunneling Spectroscopy Becker, T.; Streng, C.; Luo, Y. Physical Review Letters, Vol. 89, Issue 23 https://doi.org/10.1103/PhysRevLett.89.237203	journal	November 2002
A Strain-Driven Morphotropic Phase Boundary in BiFeO₃ Zeches, R. J.; Rossell, M. D.; Zhang, J. X. Science, Vol. 326, Issue 5955, p. 977-980 https://doi.org/10.1126/science.1177046	journal	November 2009
Mott Physics near the Insulator-To-Metal Transition in ${NdNiO}_{3}$ Stewart, M. K.; Liu, Jian; Kareev, M. Physical Review Letters, Vol. 107, Issue 17 https://doi.org/10.1103/PhysRevLett.107.176401	journal	October 2011
Anomalous Properties of the Vanadium Oxides Goodenough, John B. Annual Review of Materials Science, Vol. 1, Issue 1 https://doi.org/10.1146/annurev.ms.01.080171.000533	journal	August 1971
The two components of the crystallographic transition in VO2 Goodenough, John B. Journal of Solid State Chemistry, Vol. 3, Issue 4 https://doi.org/10.1016/0022-4596(71)90091-0	journal	November 1971
Very large anisotropy in the dc conductivity of epitaxial VO2 thin films grown on (011) rutile TiO2 substrates Lu, Jiwei; West, Kevin G.; Wolf, Stuart A. Applied Physics Letters, Vol. 93, Issue 26 https://doi.org/10.1063/1.3058769	journal	December 2008
Growth and characterization of vanadium dioxide thin films prepared by reactive-biased target ion beam deposition West, Kevin G.; Lu, Jiwei; Yu, Jiani Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 26, Issue 1 https://doi.org/10.1116/1.2819268	journal	January 2008
Metal–insulator transition of VO2 thin films grown on TiO2 (001) and (110) substrates Muraoka, Y.; Hiroi, Z. Applied Physics Letters, Vol. 80, Issue 4 https://doi.org/10.1063/1.1446215	journal	January 2002
Strain-Induced Self Organization of Metal−Insulator Domains in Single-Crystalline VO ₂ Nanobeams Wu, Junqiao; Gu, Qian; Guiton, Beth S. Nano Letters, Vol. 6, Issue 10 https://doi.org/10.1021/nl061831r	journal	October 2006
Interplay between Ferroelastic and Metal−Insulator Phase Transitions in Strained Quasi-Two-Dimensional VO ₂ Nanoplatelets Tselev, Alexander; Strelcov, Evgheni; Luk’yanchuk, Igor A. Nano Letters, Vol. 10, Issue 6 https://doi.org/10.1021/nl1008794	journal	June 2010
Anisotropic infrared response of vanadium dioxide microcrystals Huffman, T. J.; Xu, Peng; Qazilbash, M. M. Physical Review B, Vol. 87, Issue 11 https://doi.org/10.1103/PhysRevB.87.115121	journal	March 2013
In Situ Atom Scale Visualization of Domain Wall Dynamics in VO2 Insulator-Metal Phase Transition He, Xinfeng; Xu, Tao; Xu, Xiaofeng Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06544	journal	October 2014
Resistivity of the high-temperature metallic phase of ${VO}_{2}$ Allen, Philip B.; Wentzcovitch, Renata M.; Schulz, Werner W. Physical Review B, Vol. 48, Issue 7 https://doi.org/10.1103/PhysRevB.48.4359	journal	August 1993
Physical properties of V _{1− x} Ti _x O ₂ (0 < x < 0.187) single crystals Kong, Tai; Masters, Morgan W.; Bud’ko, Sergey L. APL Materials, Vol. 3, Issue 4 https://doi.org/10.1063/1.4908245	journal	April 2015
Analysis of the Surface Morphology and the Resistance of VO2 Thin Films on M-Plane Al2O3 Bong-Jun, Bong-Jun; Wook, Yong; Sungyoul, Sungyoul Journal of the Korean Physical Society, Vol. 50, Issue 3 https://doi.org/10.3938/jkps.50.653	journal	March 2007
Transport Anisotropy of Epitaxial VO$_{2}$ Films near the Metal–Semiconductor Transition Kittiwatanakul, Salinporn; Lu, Jiwei; Wolf, Stuart A. Applied Physics Express, Vol. 4, Issue 9 https://doi.org/10.1143/APEX.4.091104	journal	August 2011
Large epitaxial bi-axial strain induces a Mott-like phase transition in VO ₂ Kittiwatanakul, Salinporn; Wolf, Stuart A.; Lu, Jiwei Applied Physics Letters, Vol. 105, Issue 7 https://doi.org/10.1063/1.4893326	journal	August 2014
Anisotropy in the Electrical Resistivity of Vanadium Dioxide Single Crystals Everhart, C. R.; MacChesney, J. B. Journal of Applied Physics, Vol. 39, Issue 6 https://doi.org/10.1063/1.1656687	journal	May 1968
Anisotropy of the electrical conductivity of VO2 single crystals Bongers, P. F. Solid State Communications, Vol. 3, Issue 9 https://doi.org/10.1016/0038-1098(65)90032-3	journal	September 1965
THz spectroscopy of VO ₂ epitaxial films: controlling the anisotropic properties through strain engineering Abreu, Elsa; Liu, Mengkun; Lu, Jiwei New Journal of Physics, Vol. 14, Issue 8 https://doi.org/10.1088/1367-2630/14/8/083026	journal	August 2012
Anisotropic Electronic State via Spontaneous Phase Separation in Strained Vanadium Dioxide Films Liu, M. K.; Wagner, M.; Abreu, E. Physical Review Letters, Vol. 111, Issue 9 https://doi.org/10.1103/PhysRevLett.111.096602	journal	August 2013
Metal-insulator transition in epitaxial VO $_{2}$ thin films on TiO $_{2}$ (100) Zhong, Xing; LeClair, P.; Sarker, Sanjoy K. Physical Review B, Vol. 86, Issue 9 https://doi.org/10.1103/PhysRevB.86.094114	journal	September 2012
Mid-infrared near-field spectroscopy Amarie, Sergiu; Ganz, Thomas; Keilmann, Fritz Optics Express, Vol. 17, Issue 24 https://doi.org/10.1364/OE.17.021794	journal	January 2009
Nanoscale Conductivity Contrast by Scattering-Type Near-Field Optical Microscopy in the Visible, Infrared and THz Domains Keilmann, Fritz; Huber, Andreas J.; Hillenbrand, Rainer Journal of Infrared, Millimeter, and Terahertz Waves https://doi.org/10.1007/s10762-009-9525-3	journal	June 2009
Nano-optical imaging and spectroscopy of order, phases, and domains in complex solids Atkin, Joanna M.; Berweger, Samuel; Jones, Andrew C. Advances in Physics, Vol. 61, Issue 6 https://doi.org/10.1080/00018732.2012.737982	journal	December 2012
Near-field probing of vibrational absorption for chemical microscopy Knoll, B.; Keilmann, F. Nature, Vol. 399, Issue 6732 https://doi.org/10.1038/20154	journal	May 1999
Colloquium : Graphene spectroscopy Basov, D. N.; Fogler, M. M.; Lanzara, A. Reviews of Modern Physics, Vol. 86, Issue 3 https://doi.org/10.1103/RevModPhys.86.959	journal	July 2014
Nanoscale infrared spectroscopy as a non-destructive probe of extraterrestrial samples Dominguez, Gerardo; Mcleod, A. S.; Gainsforth, Zack Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6445	journal	December 2014
Infrared Nanoscopy of Dirac Plasmons at the Graphene–SiO ₂ Interface Fei, Zhe; Andreev, Gregory O.; Bao, Wenzhong Nano Letters, Vol. 11, Issue 11 https://doi.org/10.1021/nl202362d	journal	October 2011
Gate-tuning of graphene plasmons revealed by infrared nano-imaging Fei, Z.; Rodin, A. S.; Andreev, G. O. Nature, Vol. 487, Issue 7405 https://doi.org/10.1038/nature11253	journal	June 2012
Tunable Phonon Polaritons in Atomically Thin van der Waals Crystals of Boron Nitride Dai, S.; Fei, Z.; Ma, Q. Science, Vol. 343, Issue 6175 https://doi.org/10.1126/science.1246833	journal	March 2014
Performance of visible and mid-infrared scattering-type near-field optical microscopes Taubner, T.; Hillenbrand, R.; Keilmann, F. Journal of Microscopy, Vol. 210, Issue 3 https://doi.org/10.1046/j.1365-2818.2003.01164.x	journal	June 2003
Resonant Antenna Probes for Tip-Enhanced Infrared Near-Field Microscopy Huth, Florian; Chuvilin, Andrey; Schnell, Martin Nano Letters, Vol. 13, Issue 3 https://doi.org/10.1021/nl304289g	journal	February 2013
Ultrabroadband infrared nanospectroscopic imaging Bechtel, H. A.; Muller, E. A.; Olmon, R. L. Proceedings of the National Academy of Sciences, Vol. 111, Issue 20 https://doi.org/10.1073/pnas.1400502111	journal	May 2014
Insulator–metal transition of VO ₂ ultrathin films on silicon: evidence for an electronic origin by infrared spectroscopy Peng, W. W.; Niu, G.; Tétot, R. Journal of Physics: Condensed Matter, Vol. 25, Issue 44 https://doi.org/10.1088/0953-8984/25/44/445402	journal	October 2013
Mesoscopic Metal−Insulator Transition at Ferroelastic Domain Walls in VO ₂ Tselev, Alexander; Meunier, Vincent; Strelcov, Evgheni ACS Nano, Vol. 4, Issue 8 https://doi.org/10.1021/nn1004364	journal	July 2010
Control of the metal–insulator transition in vanadium dioxide by modifying orbital occupancy Aetukuri, Nagaphani B.; Gray, Alexander X.; Drouard, Marc Nature Physics, Vol. 9, Issue 10 https://doi.org/10.1038/nphys2733	journal	September 2013
Symmetry breaking and geometric confinement in VO ₂ : Results from a three-dimensional infrared nano-imaging Liu, Mengkun; Wagner, Martin; Zhang, Jingdi Applied Physics Letters, Vol. 104, Issue 12 https://doi.org/10.1063/1.4869558	journal	March 2014
Direct Observation of Decoupled Structural and Electronic Transitions and an Ambient Pressure Monocliniclike Metallic Phase of ${VO}_{2}$ Laverock, J.; Kittiwatanakul, S.; Zakharov, A. A. Physical Review Letters, Vol. 113, Issue 21 https://doi.org/10.1103/PhysRevLett.113.216402	journal	November 2014
Electron Localization Induced by Uniaxial Stress in Pure V $O_{2}$ Pouget, J. P.; Launois, H.; D'Haenens, J. P. Physical Review Letters, Vol. 35, Issue 13 https://doi.org/10.1103/PhysRevLett.35.873	journal	September 1975
Effects of strain on the electronic structure of ${VO}_{2}$ Lazarovits, Bence; Kim, Kyoo; Haule, Kristjan Physical Review B, Vol. 81, Issue 11 https://doi.org/10.1103/PhysRevB.81.115117	journal	March 2010
Dimerization of a linear Heisenberg chain in the insulating phases of $V_{1 - x} {Cr}_{x} O_{2}$ Pouget, J. P.; Launois, H.; Rice, T. M. Physical Review B, Vol. 10, Issue 5 https://doi.org/10.1103/PhysRevB.10.1801	journal	September 1974
${VO}_{2}$ : Peierls or Mott-Hubbard? A view from band theory Wentzcovitch, Renata M.; Schulz, Werner W.; Allen, Philip B. Physical Review Letters, Vol. 72, Issue 21 https://doi.org/10.1103/PhysRevLett.72.3389	journal	May 1994
Metallization of vanadium dioxide driven by large phonon entropy Budai, John D.; Hong, Jiawang; Manley, Michael E. Nature, Vol. 515, Issue 7528 https://doi.org/10.1038/nature13865	journal	November 2014
Growth of single crystals from metallic fluxes Canfield, P. C.; Fisk, Z. Philosophical Magazine B, Vol. 65, Issue 6 https://doi.org/10.1080/13642819208215073	journal	June 1992
Photoemission evidence for crossover from Peierls-like to Mott-like transition in highly strained VO $_{2}$ Laverock, J.; Preston, A. R. H.; Newby, D. Physical Review B, Vol. 86, Issue 19 https://doi.org/10.1103/PhysRevB.86.195124	journal	November 2012
Structural Aspects of the Metal-Insulator Transitions in Cr-Doped V $O_{2}$ Marezio, M.; McWhan, D. B.; Remeika, J. P. Physical Review B, Vol. 5, Issue 7 https://doi.org/10.1103/PhysRevB.5.2541	journal	April 1972
Role of microstructures on the M1-M2 phase transition in epitaxial VO2 thin films Ji, Yanda; Zhang, Yin; Gao, Min Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04854	journal	May 2014
Moving boundaries and travelling domains during switching of VO ₂ single crystals Fisher, B. Journal of Physics C: Solid State Physics, Vol. 8, Issue 13 https://doi.org/10.1088/0022-3719/8/13/016	journal	July 1975
Metal-semiconductor domain configurations during switching of VO ₂ single crystals Fisher, B. Journal of Physics C: Solid State Physics, Vol. 9, Issue 7 https://doi.org/10.1088/0022-3719/9/7/011	journal	April 1976
Infrared spectroscopy and nano-imaging of the insulator-to-metal transition in vanadium dioxide Qazilbash, M. M.; Brehm, M.; Andreev, G. O. Physical Review B, Vol. 79, Issue 7 https://doi.org/10.1103/PhysRevB.79.075107	journal	February 2009
Strain and temperature dependence of the insulating phases of VO $_{2}$ near the metal-insulator transition Atkin, Joanna M.; Berweger, Samuel; Chavez, Emily K. Physical Review B, Vol. 85, Issue 2 https://doi.org/10.1103/PhysRevB.85.020101	journal	January 2012
Doping-Based Stabilization of the M2 Phase in Free-Standing VO ₂ Nanostructures at Room Temperature Strelcov, Evgheni; Tselev, Alexander; Ivanov, Ilia Nano Letters, Vol. 12, Issue 12 https://doi.org/10.1021/nl303065h	journal	February 2012
Measurement of a solid-state triple point at the metal–insulator transition in VO2 Park, Jae Hyung; Coy, Jim M.; Kasirga, T. Serkan Nature, Vol. 500, Issue 7463 https://doi.org/10.1038/nature12425	journal	August 2013
Optical and transport properties of high quality crystals of V2O4 near the metallic transition temperature Ladd, Larry A.; Paul, William Solid State Communications, Vol. 7, Issue 4 https://doi.org/10.1016/0038-1098(69)90888-6	journal	February 1969
Pressure Dependence of the Resistance of VO ₂ Neuman, C. H.; Lawson, A. W.; Brown, R. F. The Journal of Chemical Physics, Vol. 41, Issue 6 https://doi.org/10.1063/1.1726128	journal	September 1964
Memory Metamaterials Driscoll, T.; Kim, H. -T.; Chae, B. -G. Science, Vol. 325, Issue 5947 https://doi.org/10.1126/science.1176580	journal	August 2009
Oxide Electronics Utilizing Ultrafast Metal-Insulator Transitions Yang, Zheng; Ko, Changhyun; Ramanathan, Shriram Annual Review of Materials Research, Vol. 41, Issue 1 https://doi.org/10.1146/annurev-matsci-062910-100347	journal	August 2011
Decoupling of Structural and Electronic Phase Transitions in ${VO}_{2}$ Tao, Zhensheng; Han, Tzong-Ru T.; Mahanti, Subhendra D. Physical Review Letters, Vol. 109, Issue 16 https://doi.org/10.1103/PhysRevLett.109.166406	journal	October 2012
A photoinduced metal-like phase of monoclinic VO ₂ revealed by ultrafast electron diffraction Morrison, Vance R.; Chatelain, Robert. P.; Tiwari, Kunal L. Science, Vol. 346, Issue 6208 https://doi.org/10.1126/science.1253779	journal	October 2014
Instantaneous Band Gap Collapse in Photoexcited Monoclinic ${VO}_{2}$ due to Photocarrier Doping Wegkamp, Daniel; Herzog, Marc; Xian, Lede Physical Review Letters, Vol. 113, Issue 21 https://doi.org/10.1103/PhysRevLett.113.216401	journal	November 2014

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Title: Phase transition in bulk single crystals and thin films of $V O_{2}$ by nanoscale infrared spectroscopy and imaging