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Title: Linking Metal Ions via Inorganic Click (iClick) Reactions

Technical Report ·
DOI:https://doi.org/10.2172/1226015· OSTI ID:1226015
 [1]
  1. Univ. of Florida, Gainesville, FL (United States)

This final report discusses the major objectives of the project, a discussion of the objectives achieved, a discussion of the objectives that failed, and finally, a discussion of future directions given the new knowledge obtained. This one-year seed project (with one year no-cost extension) contained three objectives: A) Expand the scope of iClick synthesis beyond AuI/AuI reactions. B) Elucidate a CuI-catalyzed iClick reaction. C) Synthesize and characterize tri- and tetra-metallic complexes as models for metallopolymers. Objectives A and C were achieved, whereas only parts of objective B were achieved.

Research Organization:
Univ. of Florida, Gainesville, FL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0010510
OSTI ID:
1226015
Report Number(s):
DOE-UF-0510
Country of Publication:
United States
Language:
English

References (2)

Expanding iClick to group 9 metals journal March 2016
1,3-Dipolar cycloaddition between a metal–azide (Ph3PAuN3) and a metal–acetylide (Ph3PAuCCPh): an inorganic version of a click reaction journal January 2011

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