Expanding iClick to group 9 metals

Beto, Christopher C.; Yang, Xi; Powers, Andrew R.; Ghiviriga, Ion; Abboud, Khalil A.; Veige, Adam S.

doi:10.1016/j.poly.2015.08.032

Title: Expanding iClick to group 9 metals

Journal Article · Tue Sep 01 00:00:00 EDT 2015 · Polyhedron

DOI:https://doi.org/10.1016/j.poly.2015.08.032· OSTI ID:1225602

Beto, Christopher C. ^[1]; Yang, Xi ^[1]; Powers, Andrew R. ^[1]; Ghiviriga, Ion ^[1]; Abboud, Khalil A. ^[1]; Veige, Adam S. ^[1]

Univ. of Florida, Gainesville, FL (United States)

In this study, the iClick (inorganic click) reactions between gold-acetylides and group 9 transition metal-azide complexes are presented. Complexes [Rh(CO)(PPh₃)₂][PPh₃Au](μ-N₃C₂C₆H₄NO₂) (3), {[Rh(CO)(PPh₃)][PPh₃Au](μ-N₃C₂C₆H₄NO₂)}₂ (4), and [(CO)(PPh₃)₂IrAuPPh₃](μ-N₃C₂C₆H₄NO₂) (6) have been synthesized via M-azide/M-acetylide cycloaddition reactions between PPh₃Au(Ctriple bond; length of mdashCC₆H₄NO₂) (2) and either Rh(CO)(PPh₃)₂N₃ (1), or Ir(CO)(PPh₃)₂N₃ (5). Complexes 3, 4, and 6 have been characterized by a combination of NMR spectroscopies, crystallography and combustion analysis.

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Research Organization:: Univ. of Florida, Gainesville, FL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0010510

OSTI ID:: 1225602

Alternate ID(s):: OSTI ID: 1373338

Journal Information:: Polyhedron, Journal Name: Polyhedron; ISSN 0277-5387

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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