A new series of oxycarbonate superconductors (Cu{sub 0.5}C{sub 0.5}){sub m}Ba{sub m+1}Ca{sub n-1}Cu{sub n}O{sub 2}({sub m+n})+1
Conference
·
OSTI ID:121641
- National Institute for Research in Inorganic Materials, Ibaraki (Japan)
We found a new series of oxycarbonate superconductors in the Ba-Ca-Cu-C-O system under high pressure of 5 GPa. Their ideal formula is (Cu{sub 0.5}C{sub 0.5}){sub m}Ba{sub m+1}Ca{sub n-1}Cu{sub n}O{sub 2}({sub m+n})+1 ((Cu,C)-m(m+1)(n-1)n). Thus far, n=3, 4 members of the m=1 series, (Cu,C)-1223 and (Cu,C)-1234, have been prepared in bulk while n=4, 5 members, (Cu,C)-2334 and (Cu,C)-2345, have been prepared for the m=2 series. (Cu,C)-1223 shows superconductivity below 67 K while T{sub c}`s of other compounds are above 110 K. In particular, (Cu,C)=1234 has the highest T{sub c} of 117 K.
- Research Organization:
- National Aeronautics and Space Administration (NASA), Washington, DC (United States); National Aeronautics and Space Administration, Houston, TX (United States). Lyndon B. Johnson Space Center
- OSTI ID:
- 121641
- Report Number(s):
- CONF-940627-Vol.2; ON: TI95017155; TRN: 99:003580
- Resource Relation:
- Conference: 4. international conference and exhibition of the World Congress on Superconductivity, Orlando, FL (United States), 27 Jun - 1 Jul 1994; Other Information: PBD: 1994; Related Information: Is Part Of Proceedings of the fourth international conference and exhibition: World Congress on superconductivity. Volume 2; Krishen, K.; Burnham, C. [eds.] [National Aeronautics and Space Administration, Houston, TX (United States). Lyndon B. Johnson Space Center]; PB: 400 p.
- Country of Publication:
- United States
- Language:
- English
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