Highly Selective Adsorption of Ethylene over Ethane in a MOF Featuring the Combination of Open Metal Site and -Complexation

Zhang, Yiming; Li, Baiyan; Wu, Zili; Ma, Shengqian

doi:10.1039/C4CC09774B

Title: Highly Selective Adsorption of Ethylene over Ethane in a MOF Featuring the Combination of Open Metal Site and -Complexation

Journal Article · Fri Jan 09 00:00:00 EST 2015 · ChemComm

DOI:https://doi.org/10.1039/C4CC09774B· OSTI ID:1207047

Zhang, Yiming ^[1]; Li, Baiyan ^[1]; Wu, Zili ^[2]; Ma, Shengqian ^[1]

Univ. of South Florida, Tampa, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The introduction of the combination of open metal site (OMS) and -complexation into MOF has led to very high ethylene/ethane adsorption selectivity at 318K, as illustrated in the context of MIL-101-Cr-SO₃Ag. The interactions with ethylene from both OMS and -complexation in MIL-101-Cr-SO₃Ag have been investigated by in situ IR spectroscopic studies and computational calculations, which suggest -complexation contributes dominantly to the high ethylene/ethane adsorption selectivity.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1207047

Journal Information:: ChemComm, Vol. 51, Issue 13; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 135 works

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