Enhancement of oxidation resistance of graphite foams by polymer derived-silicon carbide coating for concentrated solar power applications

Kim, T.; Singh, D.; Singh, M.

doi:10.1016/j.egypro.2015.03.170

Title: Enhancement of oxidation resistance of graphite foams by polymer derived-silicon carbide coating for concentrated solar power applications

Journal Article · Fri May 01 00:00:00 EDT 2015 · Energy Procedia (Online)

DOI:https://doi.org/10.1016/j.egypro.2015.03.170· OSTI ID:1196241

Kim, T. ^[1]; Singh, D. ^[1]; Singh, M. ^[2]

Argonne National Lab. (ANL), Argonne, IL (United States)
Ohio Aerospace Inst., Cleveland, OH (United States)

Graphite foam with extremely high thermal conductivity has been investigated to enhance heat transfer of latent heat thermal energy storage (LHTES) systems. However, the use of graphite foam for elevated temperature applications (>600 °C) is limited due to poor oxidation resistance of graphite. In the present study, oxidation resistance of graphite foam coated with silicon carbide (SiC) was investigated. A pre-ceramic polymer derived coating (PDC) method was used to form a SiC coating on the graphite foams. Post coating deposition, the samples were analyzed by scanning electron microscopy and energy dispersive spectroscopy. The oxidation resistance of PDC-SiC coating was quantified by measuring the weight of the samples at several measuring points. The experiments were conducted under static argon atmosphere in a furnace. After the experiments, oxidation rates (%/hour) were calculated to predict the lifetime of the graphite foams. The experimental results showed that the PDC-SiC coating could prevent the oxidation of graphite foam under static argon atmosphere up to 900 °C.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1196241

Journal Information:: Energy Procedia (Online), Vol. 69, Issue C; Conference: Melbourne (Australia), 19-25 Apr 2015; ISSN 1876-6102

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 9 works

Citation information provided by
Web of Science

References (19)

From silicon to carbon Fitzer, E. Carbon, Vol. 16, Issue 1 https://doi.org/10.1016/0008-6223(78)90108-2	journal	January 1978
Freezing on a finned tube for either conduction-controlled or natural-convection-controlled heat transfer Sparrow, E. M.; Larson, E. D.; Ramsey, J. W. International Journal of Heat and Mass Transfer, Vol. 24, Issue 2 https://doi.org/10.1016/0017-9310(81)90035-1	journal	February 1981
Numerical Solution for Freezing Adjacent to a Finned Surface Smith, Richard N.; Koch, James D. Proceeding of International Heat Transfer Conference 7 https://doi.org/10.1615/IHTC7.710	conference	January 1982
Study of the heat transfer behavior of a latent heat thermal energy storage unit with a finned tube Lacroix, Marcel International Journal of Heat and Mass Transfer, Vol. 36, Issue 8 https://doi.org/10.1016/S0017-9310(05)80139-5	journal	January 1993
Experimental analysis and numerical modelling of inward solidification on a finned vertical tube for a latent heat storage unit Velraj, R.; Seeniraj, R. V.; Hafner, B. Solar Energy, Vol. 60, Issue 5 https://doi.org/10.1016/S0038-092X(96)00167-3	journal	June 1997
An experimental study of enhanced heat transfer in rectangular PCM thermal storage Stritih, Uroš International Journal of Heat and Mass Transfer, Vol. 47, Issue 12-13 https://doi.org/10.1016/j.ijheatmasstransfer.2004.02.001	journal	June 2004
A comparison of heat transfer enhancement in a medium temperature thermal energy storage heat exchanger using fins Agyenim, Francis; Eames, Philip; Smyth, Mervyn Solar Energy, Vol. 83, Issue 9 https://doi.org/10.1016/j.solener.2009.04.007	journal	September 2009
Solidification of low conductivity material containing dispersed high conductivity particles Siegel, Robert International Journal of Heat and Mass Transfer, Vol. 20, Issue 10 https://doi.org/10.1016/0017-9310(77)90195-8	journal	October 1977
Heat Transfer Enhancement Study of a LHTS Unit Containing Dispersed High Conductivity Particles Seeniraj, R. V.; Velraj, R.; Lakshmi Narasimhan, N. Journal of Solar Energy Engineering, Vol. 124, Issue 3 https://doi.org/10.1115/1.1488669	journal	August 2002
High-thermal-conductivity, mesophase-pitch-derived carbon foams: effect of precursor on structure and properties Klett, James; Hardy, Rommie; Romine, Ernie Carbon, Vol. 38, Issue 7, p. 953-973 https://doi.org/10.1016/S0008-6223(99)00190-6	journal	January 2000
Phase change material with graphite foam for applications in high-temperature latent heat storage systems of concentrated solar power plants Zhao, Weihuan; France, David M.; Yu, Wenhua Renewable Energy, Vol. 69 https://doi.org/10.1016/j.renene.2014.03.031	journal	September 2014
Improvement of the oxidation resistance of a graphite material by compositionally gradient SiC/C layer Fujii, Kimio; Nakano, Junichi; Shindo, Masami Journal of Nuclear Materials, Vol. 203, Issue 1 https://doi.org/10.1016/0022-3115(93)90424-W	journal	July 1993
Improvement in oxidation resistance of the nuclear graphite by reaction-coated SiC coating Chunhe, Tang; Jie, Guan Journal of Nuclear Materials, Vol. 224, Issue 1 https://doi.org/10.1016/0022-3115(95)00031-3	journal	July 1995
Silicon-carbide/boron-containing coatings for the oxidation protection of graphite Fergus, Jeffrey W.; Worrell, Wayne L. Carbon, Vol. 33, Issue 4 https://doi.org/10.1016/0008-6223(94)00178-3	journal	January 1995
Oxidation resistant SiC coating for graphite materials Zhu, Qingshan; Qiu, Xueliang; Ma, Changwen Carbon, Vol. 37, Issue 9 https://doi.org/10.1016/S0008-6223(99)00010-X	journal	January 1999
Oxidation protective behavior of SiC/Si–MoSi2 coating for different graphite matrix Zhao, Juan; Liu, Lang; Guo, Quangui Materials Letters, Vol. 60, Issue 16 https://doi.org/10.1016/j.matlet.2005.12.072	journal	July 2006
Anti-oxidation behavior of chemical vapor reaction SiC coatings on different carbon materials at high temperatures Yang, Xin; Huang, Qi-zhong; Zou, Yan-hong Transactions of Nonferrous Metals Society of China, Vol. 19, Issue 5 https://doi.org/10.1016/S1003-6326(08)60404-5	journal	October 2009
Enhancement of Oxidation Resistance of Graphite Foams by SiC Coating for Concentrated Solar Power Applications Kim, Taeil; Singh, Dileep; Singh, Mrityunjay Mechanical Properties and Performance of Engineering Ceramics and Composites IX https://doi.org/10.1002/9781119031192.ch16	book	October 2014
Effects of Porosity and Temperature on Oxidation Behavior in Air of Selected Nuclear Graphites Chen, Dongyue; Li, Zhengcao; Miao, Wei MATERIALS TRANSACTIONS, Vol. 53, Issue 6 https://doi.org/10.2320/matertrans.MBW201107	journal	January 2012

Similar Records

Critical thickness of polymer‐derived ceramic coatings with particulate fillers

Journal Article · Mon Nov 21 00:00:00 EST 2022 · International Journal of Applied Ceramic Technology · OSTI ID:1196241

Zhang, Zhao; Bordia, Rajendra K.; Peng, Fei

Titanium nitride/carbon coatings on graphite fibers

Journal Article · Sat Mar 01 00:00:00 EST 1997 · Journal of the American Ceramic Society · OSTI ID:1196241

Liu, Y; Treadwell, D R; Kannisto, M R; +2 more

Laboratory-Scale Coal-Derived Graphene Process (Final Report)

Technical Report · Mon Jun 05 00:00:00 EDT 2023 · OSTI ID:1196241

Azenkeng, Alexander; Stanislowski, Nicholas E.; Tibbetts, James E.; +1 more

Related Subjects

36 MATERIALS SCIENCE
graphite foam
latent heat
thermal energy storage
polymer derived coating
silicon carbide
oxidation

Title: Enhancement of oxidation resistance of graphite foams by polymer derived-silicon carbide coating for concentrated solar power applications

Citation Formats

References (19)

Similar Records

Related Subjects