Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy

Lukatskaya, Maria R.; Bak, Seong -Min; Yu, Xiqian; Yang, Xiao -Qing; Barsoum, Michel W.; Gogotsi, Yury

doi:10.1002/aenm.201500589

Title: Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy

Journal Article · Thu May 28 00:00:00 EDT 2015 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201500589· OSTI ID:1188237

Lukatskaya, Maria R. ^[1]; Bak, Seong -Min ^[2]; Yu, Xiqian ^[2]; Yang, Xiao -Qing ^[2]; Barsoum, Michel W. ^[1]; Gogotsi, Yury ^[1]

Drexel Univ., Philadelphia, PA (United States). Dept. of Materials Science and Engineering and A.J. Drexel Nanomaterials Inst.
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.

The field of supercapacitors (electrochemical capacitors) is constantly evolving. The global motivation is to create devices that possess a significant energy density without compromising the power density. To achieve this goal, new materials must be discovered and complex electrode architectures developed.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: SC00112704

OSTI ID:: 1188237

Report Number(s):: BNL-108018-2015-JA; R&D Project: MA453MAEA; VT1201000

Journal Information:: Advanced Energy Materials, Vol. 10, Issue 5; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 374 works

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Synthesis of Two-Dimensional Materials for Capacitive Energy Storage Mendoza-Sánchez, Beatriz; Gogotsi, Yury Advanced Materials, Vol. 28, Issue 29 https://doi.org/10.1002/adma.201506133	journal	June 2016
High photoluminescence quantum yield of 18.7% by using nitrogen-doped Ti ₃ C ₂ MXene quantum dots Xu, Quan; Ding, Lan; Wen, Yangyang Journal of Materials Chemistry C, Vol. 6, Issue 24 https://doi.org/10.1039/c8tc02156b	journal	January 2018
Flexible Ti ₃ C ₂ T _x /PEDOT:PSS films with outstanding volumetric capacitance for asymmetric supercapacitors Li, Lu; Zhang, Na; Zhang, Mingyi Dalton Transactions, Vol. 48, Issue 5 https://doi.org/10.1039/c8dt04374d	journal	January 2019
Clay-Inspired MXene-Based Electrochemical Devices and Photo-Electrocatalyst: State-of-the-Art Progresses and Challenges Wang, Hou; Wu, Yan; Yuan, Xingzhong Advanced Materials, Vol. 30, Issue 12 https://doi.org/10.1002/adma.201704561	journal	January 2018
Recent Development of Printed Micro‐Supercapacitors: Printable Materials, Printing Technologies, and Perspectives Li, Hongpeng; Liang, Jiajie Advanced Materials, Vol. 32, Issue 3 https://doi.org/10.1002/adma.201805864	journal	April 2019
Advanced Energy Storage Devices: Basic Principles, Analytical Methods, and Rational Materials Design Liu, Jilei; Wang, Jin; Xu, Chaohe Advanced Science, Vol. 5, Issue 1 https://doi.org/10.1002/advs.201700322	journal	November 2017
MXene-on-Paper Coplanar Microsupercapacitors Kurra, Narendra; Ahmed, Bilal; Gogotsi, Yury Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601372	journal	September 2016
Electrochromic Effect in Titanium Carbide MXene Thin Films Produced by Dip‐Coating Salles, Pol; Pinto, David; Hantanasirisakul, Kanit Advanced Functional Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adfm.201809223	journal	February 2019
Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes Xia, Yu; Mathis, Tyler S.; Zhao, Meng-Qiang Nature, Vol. 557, Issue 7705 https://doi.org/10.1038/s41586-018-0109-z	journal	May 2018
Interlayer Hydrogen‐Bonded Metal Porphyrin Frameworks/MXene Hybrid Film with High Capacitance for Flexible All‐Solid‐State Supercapacitors Zhao, Weiwei; Peng, Jiali; Wang, Weikang Small, Vol. 15, Issue 18 https://doi.org/10.1002/smll.201901351	journal	March 2019
A nanoporous MXene film enables flexible supercapacitors with high energy storage Fan, Zhimin; Wang, Youshan; Xie, Zhimin Nanoscale, Vol. 10, Issue 20 https://doi.org/10.1039/c8nr01550c	journal	January 2018
Fluorine-Free Synthesis of High-Purity Ti ₃ C ₂ T _x (T=OH, O) via Alkali Treatment Li, Tengfei; Yao, Lulu; Liu, Qinglei Angewandte Chemie International Edition, Vol. 57, Issue 21 https://doi.org/10.1002/anie.201800887	journal	April 2018
Synthesis of Nitrogen-Doped Two-Dimensional Ti ₃ C ₂ with Enhanced Electrochemical Performance Tang, Yi; Zhu, Jianfeng; Wu, Wenling Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.0041706jes	journal	January 2017
Knittable and Washable Multifunctional MXene‐Coated Cellulose Yarns Uzun, Simge; Seyedin, Shayan; Stoltzfus, Amy L. Advanced Functional Materials, Vol. 29, Issue 45 https://doi.org/10.1002/adfm.201905015	journal	September 2019
Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance Yan, Jun; Ren, Chang E.; Maleski, Kathleen Advanced Functional Materials, Vol. 27, Issue 30 https://doi.org/10.1002/adfm.201701264	journal	June 2017
2D Materials Beyond Graphene for High-Performance Energy Storage Applications Zhang, Xiaoyan; Hou, Lili; Ciesielski, Artur Advanced Energy Materials, Vol. 6, Issue 23 https://doi.org/10.1002/aenm.201600671	journal	July 2016
MXene-Conducting Polymer Asymmetric Pseudocapacitors Boota, Muhammad; Gogotsi, Yury Advanced Energy Materials, Vol. 9, Issue 7 https://doi.org/10.1002/aenm.201802917	journal	December 2018
Scalable nanomanufacturing of inkjet-printed wearable energy storage devices Huang, Tao-Tse; Wu, Wenzhuo Journal of Materials Chemistry A, Vol. 7, Issue 41 https://doi.org/10.1039/c9ta05239a	journal	January 2019

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Title: Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy

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