Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus

Ling, Xi; Liang, Liangbo; Huang, Shengxi; Puretzky, Alexander A.; Geohegan, David B.; Sumpter, Bobby G.; Kong, Jing; Meunier, Vincent; Dresselhaus, Mildred S.

doi:10.1021/acs.nanolett.5b01117

Title: Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus

Journal Article · Fri May 08 00:00:00 EDT 2015 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.5b01117· OSTI ID:1185959

Ling, Xi ^[1]; Liang, Liangbo ^[2]; Huang, Shengxi ^[1]; Puretzky, Alexander A. ^[3]; Geohegan, David B. ^[3]; Sumpter, Bobby G. ^[4]; Kong, Jing ^[1]; Meunier, Vincent ^[2]; Dresselhaus, Mildred S. ^[1]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Rensselaer Polytechnic Inst., Troy, NY (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS) and Computer Science and Mathematics Div.

As a new two-dimensional layered material, black phosphorus (BP) is a very promising material for nanoelectronics and nano-optoelectronics. We use Raman spectroscopy and first-principles theory to characterize and understand low-frequency (LF) interlayer breathing modes (<100 cm-1) in few-layer BP for the first time. Using laser polarization dependence study and group theory analysis the breathing modes are assigned to Ag symmetry. Compared to the high-frequency (HF) Raman modes, the LF breathing modes are considerably more sensitive to interlayer coupling and thus their frequencies show stronger dependence on the number of layers. Hence, they constitute an effective means to probe both the crystalline orientation and thickness of few-layer BP. Furthermore, the temperature dependence shows that the breathing modes have a harmonic behavior, in contrast to HF Raman modes which exhibit anharmonicity.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Energy Frontier Research Centers (EFRC) (United States). Solid-State Solar-Thermal Energy Conversion Center (S3TEC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; SC0001299; FG02-09ER46577

OSTI ID:: 1185959

Journal Information:: Nano Letters, Vol. 15, Issue 6; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 163 works

Citation information provided by
Web of Science

References (69)

Semiconducting black phosphorus Morita, A. Applied Physics A Solids and Surfaces, Vol. 39, Issue 4 https://doi.org/10.1007/BF00617267	journal	April 1986
Black phosphorus field-effect transistors Li, Likai; Yu, Yijun; Ye, Guo Jun Nature Nanotechnology, Vol. 9, Issue 5 https://doi.org/10.1038/nnano.2014.35	journal	March 2014
Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics Xia, Fengnian; Wang, Han; Jia, Yichen Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5458	journal	July 2014
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility Liu, Han; Neal, Adam T.; Zhu, Zhen ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn501226z	journal	March 2014
Electric field effect in ultrathin black phosphorus Koenig, Steven P.; Doganov, Rostislav A.; Schmidt, Hennrik Applied Physics Letters, Vol. 104, Issue 10 https://doi.org/10.1063/1.4868132	journal	March 2014
Strain-Induced Gap Modification in Black Phosphorus Rodin, A. S.; Carvalho, A.; Castro Neto, A. H. Physical Review Letters, Vol. 112, Issue 17 https://doi.org/10.1103/PhysRevLett.112.176801	journal	May 2014
Band structure and optical properties of black phosphorus Asahina, H.; Morita, A. Journal of Physics C: Solid State Physics, Vol. 17, Issue 11 https://doi.org/10.1088/0022-3719/17/11/006	journal	April 1984
Electronic Bandgap and Edge Reconstruction in Phosphorene Materials Liang, Liangbo; Wang, Jun; Lin, Wenzhi Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl502892t	journal	October 2014
Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus Tran, Vy; Soklaski, Ryan; Liang, Yufeng Physical Review B, Vol. 89, Issue 23 https://doi.org/10.1103/PhysRevB.89.235319	journal	June 2014
Black Phosphorus Radio-Frequency Transistors Wang, Han; Wang, Xiaomu; Xia, Fengnian Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl5029717	journal	October 2014
Fast and Broadband Photoresponse of Few-Layer Black Phosphorus Field-Effect Transistors Buscema, Michele; Groenendijk, Dirk J.; Blanter, Sofya I. Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl5008085	journal	May 2014
Plasmons and Screening in Monolayer and Multilayer Black Phosphorus Low, Tony; Roldán, Rafael; Wang, Han Physical Review Letters, Vol. 113, Issue 10 https://doi.org/10.1103/PhysRevLett.113.106802	journal	September 2014
Black Phosphorus Photodetector for Multispectral, High-Resolution Imaging Engel, Michael; Steiner, Mathias; Avouris, Phaedon Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl502928y	journal	October 2014
Photovoltaic effect in few-layer black phosphorus PN junctions defined by local electrostatic gating Buscema, Michele; Groenendijk, Dirk J.; Steele, Gary A. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5651	journal	August 2014
Semiconducting black phosphorus: synthesis, transport properties and electronic applications Liu, Han; Du, Yuchen; Deng, Yexin Chemical Society Reviews, Vol. 44, Issue 9 https://doi.org/10.1039/C4CS00257A	journal	January 2015
Phosphorus joins the family Churchill, Hugh O. H.; Jarillo-Herrero, Pablo Nature Nanotechnology, Vol. 9, Issue 5 https://doi.org/10.1038/nnano.2014.85	journal	May 2014
Two-dimensional material nanophotonics Xia, Fengnian; Wang, Han; Xiao, Di Nature Photonics, Vol. 8, Issue 12 https://doi.org/10.1038/nphoton.2014.271	journal	November 2014
The renaissance of black phosphorus Ling, Xi; Wang, Han; Huang, Shengxi Proceedings of the National Academy of Sciences, Vol. 112, Issue 15 https://doi.org/10.1073/pnas.1416581112	journal	March 2015
Hinge-like structure induced unusual properties of black phosphorus and new strategies to improve the thermoelectric performance Qin, Guangzhao; Yan, Qing-Bo; Qin, Zhenzhen Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06946	journal	November 2014
Enhanced Thermoelectric Efficiency via Orthogonal Electrical and Thermal Conductances in Phosphorene Fei, Ruixiang; Faghaninia, Alireza; Soklaski, Ryan Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl502865s	journal	September 2014
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712 https://doi.org/10.1038/nnano.2012.193	journal	November 2012
High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus Qiao, Jingsi; Kong, Xianghua; Hu, Zhi-Xin Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5475	journal	July 2014
Strain-Engineering the Anisotropic Electrical Conductance of Few-Layer Black Phosphorus Fei, Ruixiang; Yang, Li Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl500935z	journal	April 2014
Intrinsic and extrinsic performance limits of graphene devices on SiO₂ Chen, Jian-Hao; Jang, Chaun; Xiao, Shudong Nature Nanotechnology, Vol. 3, Issue 4, p. 206-209 https://doi.org/10.1038/nnano.2008.58	journal	March 2008
Acoustic phonon scattering limited carrier mobility in two-dimensional extrinsic graphene Hwang, E. H.; Das Sarma, S. Physical Review B, Vol. 77, Issue 11 https://doi.org/10.1103/PhysRevB.77.115449	journal	March 2008
Controlling Electron-Phonon Interactions in Graphene at Ultrahigh Carrier Densities Efetov, Dmitri K.; Kim, Philip Physical Review Letters, Vol. 105, Issue 25 https://doi.org/10.1103/PhysRevLett.105.256805	journal	December 2010
Phonon Anharmonicities in Graphite and Graphene Bonini, Nicola; Lazzeri, Michele; Marzari, Nicola Physical Review Letters, Vol. 99, Issue 17 https://doi.org/10.1103/PhysRevLett.99.176802	journal	October 2007
Observation of Layer-Breathing Mode Vibrations in Few-Layer Graphene through Combination Raman Scattering Lui, Chun Hung; Malard, Leandro M.; Kim, SukHyun Nano Letters, Vol. 12, Issue 11 https://doi.org/10.1021/nl302450s	journal	October 2012
Optical Phonon Modes and Localized Effective Charges of Transition-Metal Dichalcogenides Uchida, Shin-ichi; Tanaka, Shoji Journal of the Physical Society of Japan, Vol. 45, Issue 1 https://doi.org/10.1143/JPSJ.45.153	journal	July 1978
Acoustic phonons in the transition-metal dichalcogenide layer compound, TiSe2 Stirling, W. G.; Dorner, B.; Cheeke, J. D. N. Solid State Communications, Vol. 18, Issue 7 https://doi.org/10.1016/0038-1098(76)90240-4	journal	January 1976
From Bulk to Monolayer MoS2: Evolution of Raman Scattering Li, Hong; Zhang, Qing; Yap, Chin Chong Ray Advanced Functional Materials, Vol. 22, Issue 7 https://doi.org/10.1002/adfm.201102111	journal	January 2012
Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects Ferrari, Andrea C. Solid State Communications, Vol. 143, Issue 1-2, p. 47-57 https://doi.org/10.1016/j.ssc.2007.03.052	journal	July 2007
Electric Field Effect Tuning of Electron-Phonon Coupling in Graphene Yan, Jun; Zhang, Yuanbo; Kim, Philip Physical Review Letters, Vol. 98, Issue 16 https://doi.org/10.1103/PhysRevLett.98.166802	journal	April 2007
Symmetry-dependent phonon renormalization in monolayer MoS $_{2}$ transistor Chakraborty, Biswanath; Bera, Achintya; Muthu, D. V. S. Physical Review B, Vol. 85, Issue 16 https://doi.org/10.1103/PhysRevB.85.161403	journal	April 2012
Anomalous Lattice Vibrations of Single- and Few-Layer MoS ₂ Lee, Changgu; Yan, Hugen; Brus, Louis E. ACS Nano, Vol. 4, Issue 5 https://doi.org/10.1021/nn1003937	journal	March 2010
Raman spectroscopy as a versatile tool for studying the properties of graphene Ferrari, Andrea C.; Basko, Denis M. Nature Nanotechnology, Vol. 8, Issue 4 https://doi.org/10.1038/nnano.2013.46	journal	April 2013
Raman spectroscopy of shear and layer breathing modes in multilayer MoS $_{2}$ Zhang, X.; Han, W. P.; Wu, J. B. Physical Review B, Vol. 87, Issue 11 https://doi.org/10.1103/PhysRevB.87.115413	journal	March 2013
Interlayer Breathing and Shear Modes in Few-Trilayer MoS ₂ and WSe ₂ Zhao, Yanyuan; Luo, Xin; Li, Hai Nano Letters, Vol. 13, Issue 3 https://doi.org/10.1021/nl304169w	journal	February 2013
Measurement of layer breathing mode vibrations in few-layer graphene Lui, Chun Hung; Heinz, Tony F. Physical Review B, Vol. 87, Issue 12 https://doi.org/10.1103/PhysRevB.87.121404	journal	March 2013
Raman and infrared reflection spectroscopy in black phosphorus Sugai, S.; Shirotani, I. Solid State Communications, Vol. 53, Issue 9 https://doi.org/10.1016/0038-1098(85)90213-3	journal	March 1985
Identifying the Crystalline Orientation of Black Phosphorus Using Angle-Resolved Polarized Raman Spectroscopy Wu, Juanxia; Mao, Nannan; Xie, Liming Angewandte Chemie, Vol. 127, Issue 8 https://doi.org/10.1002/ange.201410108	journal	January 2015
Isolation and characterization of few-layer black phosphorus Castellanos-Gomez, Andres; Vicarelli, Leonardo; Prada, Elsa 2D Materials, Vol. 1, Issue 2 https://doi.org/10.1088/2053-1583/1/2/025001	journal	June 2014
Extraordinary Photoluminescence and Strong Temperature/Angle-Dependent Raman Responses in Few-Layer Phosphorene Zhang, Shuang; Yang, Jiong; Xu, Renjing ACS Nano, Vol. 8, Issue 9 https://doi.org/10.1021/nn503893j	journal	August 2014
Inelastic neutron scattering study of acoustic phonons of black phosphorus Fujii, Y.; Akahama, Y.; Endo, S. Solid State Communications, Vol. 44, Issue 5 https://doi.org/10.1016/0038-1098(82)90558-0	journal	November 1982
Lattice-dynamical properties of black phosphorus under pressure studied by inelastic neutron scattering Yamada, Y.; Fujii, Y.; Akahama, Y. Physical Review B, Vol. 30, Issue 5 https://doi.org/10.1103/PhysRevB.30.2410	journal	September 1984
First-principles calculations of the ferroelastic transition between rutile-type and ${CaCl}_{2}$ -type ${SiO}_{2}$ at high pressures Togo, Atsushi; Oba, Fumiyasu; Tanaka, Isao Physical Review B, Vol. 78, Issue 13 https://doi.org/10.1103/PhysRevB.78.134106	journal	October 2008
Lattice Dynamics of Black Phosphorus. I. Valence Force Field Model Kaneta, Chioko; Katayama-Yoshida, Hiroshi; Morita, Akira Journal of the Physical Society of Japan, Vol. 55, Issue 4 https://doi.org/10.1143/JPSJ.55.1213	journal	April 1986
First-principles Raman spectra of MoS2, WS2 and their heterostructures Liang, Liangbo; Meunier, Vincent Nanoscale, Vol. 6, Issue 10 https://doi.org/10.1039/c3nr06906k	journal	January 2014
Pressure Dependence of the Lattice Vibration in the Orthorhombic and Rhombohedral Structures of Black Phosphorus Sugai, Shunji; Ueda, Toru; Murase, Kazuo Journal of the Physical Society of Japan, Vol. 50, Issue 10 https://doi.org/10.1143/JPSJ.50.3356	journal	October 1981
Strong Thermal Transport Anisotropy and Strain Modulation in Single-Layer Phosphorene Ong, Zhun-Yong; Cai, Yongqing; Zhang, Gang The Journal of Physical Chemistry C, Vol. 118, Issue 43 https://doi.org/10.1021/jp5079357	journal	October 2014
Graphene Thickness Determination Using Reflection and Contrast Spectroscopy Ni, Z. H.; Wang, H. M.; Kasim, J. Nano Letters, Vol. 7, Issue 9 https://doi.org/10.1021/nl071254m	journal	September 2007
Unusual Angular Dependence of the Raman Response in Black Phosphorus Ribeiro, Henrique B.; Pimenta, Marcos A.; de Matos, Christiano J. S. ACS Nano, Vol. 9, Issue 4 https://doi.org/10.1021/acsnano.5b00698	journal	February 2015
Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization Lu, Wanglin; Nan, Haiyan; Hong, Jinhua Nano Research, Vol. 7, Issue 6 https://doi.org/10.1007/s12274-014-0446-7	journal	May 2014
Strong Enhancement of Raman Scattering from a Bulk-Inactive Vibrational Mode in Few-Layer MoTe ₂ Yamamoto, Mahito; Wang, Sheng Tsung; Ni, Meiyan ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn5007607	journal	March 2014
Exfoliation and Characterization of Bismuth Telluride Atomic Quintuples and Quasi-Two-Dimensional Crystals Teweldebrhan, Desalegne; Goyal, Vivek; Balandin, Alexander A. Nano Letters, Vol. 10, Issue 4 https://doi.org/10.1021/nl903590b	journal	April 2010
Anharmonic Decay of Optical Phonons Klemens, P. G. Physical Review, Vol. 148, Issue 2 https://doi.org/10.1103/PhysRev.148.845	journal	August 1966
Anharmonic phonon effects in Raman spectra of unsupported vertical graphene sheets Lin, Jingjing; Guo, Liwei; Huang, Qingsong Physical Review B, Vol. 83, Issue 12 https://doi.org/10.1103/PhysRevB.83.125430	journal	March 2011
Temperature Dependence of the Raman Spectra of Graphene and Graphene Multilayers Calizo, I.; Balandin, A. A.; Bao, W. Nano Letters, Vol. 7, Issue 9 https://doi.org/10.1021/nl071033g	journal	September 2007
Temperature-Dependent Raman Studies and Thermal Conductivity of Few-Layer MoS ₂ Sahoo, Satyaprakash; Gaur, Anand P. S.; Ahmadi, Majid The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp402509w	journal	April 2013
Temperature-dependent phonon shifts in monolayer MoS ₂ Lanzillo, Nicholas A.; Glen Birdwell, A.; Amani, Matin Applied Physics Letters, Vol. 103, Issue 9 https://doi.org/10.1063/1.4819337	journal	August 2013
Temperature dependence of radial breathing mode Raman frequency of single-walled carbon nanotubes Raravikar, Nachiket R.; Keblinski, Pawel; Rao, Apparao M. Physical Review B, Vol. 66, Issue 23 https://doi.org/10.1103/PhysRevB.66.235424	journal	December 2002
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Bilayer Phosphorene: Effect of Stacking Order on Bandgap and Its Potential Applications in Thin-Film Solar Cells Dai, Jun; Zeng, Xiao Cheng The Journal of Physical Chemistry Letters, Vol. 5, Issue 7 https://doi.org/10.1021/jz500409m	journal	March 2014
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Semiempirical GGA-type density functional constructed with a long-range dispersion correction Grimme, Stefan Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799 https://doi.org/10.1002/jcc.20495	journal	January 2006
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Electronic and thermoelectric properties of assembled graphene nanoribbons with elastic strain and structural dislocation Liang, Liangbo; Meunier, Vincent Applied Physics Letters, Vol. 102, Issue 14 https://doi.org/10.1063/1.4800777	journal	April 2013

Cited By (37)

Phosphorene: Current status, challenges and opportunities Goswami, Anandarup; Gawande, Manoj B. Frontiers of Chemical Science and Engineering, Vol. 13, Issue 2 https://doi.org/10.1007/s11705-018-1783-y	journal	June 2019
Two-dimensional layered materials: from mechanical and coupling properties towards applications in electronics Zhan, Hao; Guo, Dan; Xie, GuoXin Nanoscale, Vol. 11, Issue 28 https://doi.org/10.1039/c9nr03611c	journal	January 2019
Black Phosphorus Nanosheets: Synthesis, Characterization and Applications Eswaraiah, Varrla; Zeng, Qingsheng; Long, Yi Small, Vol. 12, Issue 26 https://doi.org/10.1002/smll.201600032	journal	May 2016
Revealing molecular-level surface redox sites of controllably oxidized black phosphorus nanosheets Nakhanivej, Puritut; Yu, Xu; Park, Sul Ki Nature Materials, Vol. 18, Issue 2 https://doi.org/10.1038/s41563-018-0230-2	journal	December 2018
Thickness-dependent Raman spectra, transport properties and infrared photoresponse of few-layer black phosphorus Liu, Sijie; Huo, Nengjie; Gan, Sheng Journal of Materials Chemistry C, Vol. 3, Issue 42 https://doi.org/10.1039/c5tc01809a	journal	January 2015
Electronic and optical properties of strained graphene and other strained 2D materials: a review Naumis, Gerardo G.; Barraza-Lopez, Salvador; Oliva-Leyva, Maurice Reports on Progress in Physics, Vol. 80, Issue 9 https://doi.org/10.1088/1361-6633/aa74ef	journal	August 2017
Spotting the differences in two-dimensional materials – the Raman scattering perspective Zhang, Shishu; Zhang, Na; Zhao, Yan Chemical Society Reviews, Vol. 47, Issue 9 https://doi.org/10.1039/c7cs00874k	journal	January 2018
Anisotropic Thermal Conductivity of Exfoliated Black Phosphorus Jang, Hyejin; Wood, Joshua D.; Ryder, Christopher R. Advanced Materials, Vol. 27, Issue 48 https://doi.org/10.1002/adma.201503466	journal	October 2015
Stacking-dependent interlayer phonons in 3R and 2H MoS ₂ van Baren, Jeremiah; Ye, Gaihua; Yan, Jia-An 2D Materials, Vol. 6, Issue 2 https://doi.org/10.1088/2053-1583/ab0196	journal	February 2019
Laser Synthesis, Processing, and Spectroscopy of Atomically-Thin Two Dimensional Materials Geohegan, David B.; Puretzky, Alex A.; Boulesbaa, Aziz Advances in the Application of Lasers in Materials Science https://doi.org/10.1007/978-3-319-96845-2_1	book	January 2018
The impact of hexagonal boron nitride encapsulation on the structural and vibrational properties of few layer black phosphorus Birowska, Magdalena; Urban, Joanna; Baranowski, Michał Nanotechnology, Vol. 30, Issue 19 https://doi.org/10.1088/1361-6528/ab0332	journal	February 2019
Interfacial Engineering of Van der Waals Coupled 2D Layered Materials Hong, Hao; Liu, Can; Cao, Ting Advanced Materials Interfaces, Vol. 4, Issue 9 https://doi.org/10.1002/admi.201601054	journal	February 2017
Anomalous interlayer vibrations in strongly coupled layered PdSe ₂ Puretzky, Alexander A.; Oyedele, Akinola D.; Xiao, Kai 2D Materials, Vol. 5, Issue 3 https://doi.org/10.1088/2053-1583/aabe4d	journal	May 2018
Controlled nanofabrication of metal-free SERS substrate on few layered black phosphorus by low power focused laser irradiation Kundu, Anirban; Rani, Renu; Hazra, Kiran Shankar Nanoscale, Vol. 11, Issue 35 https://doi.org/10.1039/c9nr02615k	journal	January 2019
Characterization methods dedicated to nanometer-thick hBN layers Schué, Léonard; Stenger, Ingrid; Fossard, Frédéric 2D Materials, Vol. 4, Issue 1 https://doi.org/10.1088/2053-1583/4/1/015028	journal	November 2016
Strong optical limiting behavior discovered in black phosphorus Zhang, Fang; Wu, Zhixin; Wang, Zhengping RSC Advances, Vol. 6, Issue 24 https://doi.org/10.1039/c6ra01607c	journal	January 2016
Black Phosphorus: Optical Characterization, Properties and Applications Huang, Shengxi; Ling, Xi Small, Vol. 13, Issue 38 https://doi.org/10.1002/smll.201700823	journal	July 2017
Remarkable anisotropic phonon response in uniaxially strained few-layer black phosphorus Wang, Yanlong; Cong, Chunxiao; Fei, Ruixiang Nano Research, Vol. 8, Issue 12 https://doi.org/10.1007/s12274-015-0895-7	journal	November 2015
Phosphorene: from theory to applications Carvalho, Alexandra; Wang, Min; Zhu, Xi Nature Reviews Materials, Vol. 1, Issue 11 https://doi.org/10.1038/natrevmats.2016.61	journal	August 2016
Anisotropic optical and electronic properties of two-dimensional layered germanium sulfide Tan, Dezhi; Lim, Hong En; Wang, Feijiu Nano Research, Vol. 10, Issue 2 https://doi.org/10.1007/s12274-016-1312-6	journal	December 2016
Highly In‐Plane Anisotropic 2D GeAs ₂ for Polarization‐Sensitive Photodetection Li, Liang; Gong, Penglai; Sheng, Daopeng Advanced Materials, Vol. 30, Issue 50 https://doi.org/10.1002/adma.201804541	journal	August 2018
Lattice Vibration and Raman Scattering in Anisotropic Black Phosphorus Crystals Mao, Nannan; Zhang, Shuqing; Wu, Juanxia Small Methods, Vol. 2, Issue 6 https://doi.org/10.1002/smtd.201700409	journal	April 2018
Thickness-dependent resistive switching in black phosphorus CBRAM Rehman, Shania; Khan, Muhammad Farooq; Aftab, Sikandar Journal of Materials Chemistry C, Vol. 7, Issue 3 https://doi.org/10.1039/c8tc04538k	journal	January 2019
Layer-Number Dependent Optical Properties of 2D Materials and Their Application for Thickness Determination Li, Xiao-Li; Han, Wen-Peng; Wu, Jiang-Bin Advanced Functional Materials, Vol. 27, Issue 19 https://doi.org/10.1002/adfm.201604468	journal	January 2017
Temperature-dependent layer breathing modes in two-dimensional materials Maity, Indrajit; Maiti, Prabal K.; Jain, Manish Physical Review B, Vol. 97, Issue 16 https://doi.org/10.1103/physrevb.97.161406	journal	April 2018
Tunable Schottky barriers in ultrathin black phosphorus field effect transistors via polymer capping Li, Yanyong; Lin, Shenghuang; Liu, Yanghui 2D Materials, Vol. 6, Issue 2 https://doi.org/10.1088/2053-1583/aafd3c	journal	January 2019
Raman Sensitive Degradation and Etching Dynamics of Exfoliated Black Phosphorus Alsaffar, Fadhel; Alodan, Sarah; Alrasheed, Abdul Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep44540	journal	March 2017
2D Black Phosphorus: from Preparation to Applications for Electrochemical Energy Storage Wu, Shuxing; Hui, Kwan San; Hui, Kwun Nam Advanced Science, Vol. 5, Issue 5 https://doi.org/10.1002/advs.201700491	journal	February 2018
Ultralow-Frequency Collective Compression Mode and Strong Interlayer Coupling in Multilayer Black Phosphorus Dong, Shan; Zhang, Anmin; Liu, Kai Physical Review Letters, Vol. 116, Issue 8 https://doi.org/10.1103/physrevlett.116.087401	journal	February 2016
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices Pang, Jinbo; Bachmatiuk, Alicja; Yin, Yin Advanced Energy Materials, Vol. 8, Issue 8 https://doi.org/10.1002/aenm.201702093	journal	December 2017
Probing the Domain Architecture in 2D α-Mo ₂ C via Polarized Raman Spectroscopy Li, Tianshu; Luo, Weijun; Kitadai, Hikari Advanced Materials, Vol. 31, Issue 8 https://doi.org/10.1002/adma.201807160	journal	January 2019
Robust Amphiphobic Few‐Layer Black Phosphorus Nanosheet with Improved Stability Liu, Xiao; Bai, Yunfei; Xu, Jun Advanced Science, Vol. 6, Issue 23 https://doi.org/10.1002/advs.201901991	journal	September 2019
Curvature analysis of single layer graphene on the basis of extreme low-frequency Raman spectroscopy Shen, Y.; Dai, E.; Liu, X. Applied Physics Letters, Vol. 114, Issue 16 https://doi.org/10.1063/1.5090908	journal	April 2019
Vibrational properties and Raman spectra of pristine and fluorinated blue phosphorene Deng, Zexiang; Li, Zhibing; Wang, Weiliang Physical Chemistry Chemical Physics, Vol. 21, Issue 3 https://doi.org/10.1039/c8cp05699d	journal	January 2019
Highly anisotropic thermoelectric properties of black phosphorus crystals Zeng, Qingsheng; Sun, Bo; Du, Kezhao 2D Materials, Vol. 6, Issue 4 https://doi.org/10.1088/2053-1583/ab2816	journal	July 2019
Ab initio study of electron-phonon interaction in phosphorene Liao, Bolin; Zhou, Jiawei; Qiu, Bo arXiv https://doi.org/10.48550/arxiv.1410.4242	text	January 2014
The impact of hexagonal boron nitride encapsulation on the structural and vibrational properties of few layer black phosphorus Birowska, Magdalena; Urban, Joanna; Baranowski, Michał arXiv https://doi.org/10.48550/arxiv.2002.10180	text	January 2020

Similar Records

Resonance-Enhanced Excitation of Interlayer Vibrations in Atomically Thin Black Phosphorus

Journal Article · Fri May 28 00:00:00 EDT 2021 · Nano Letters · OSTI ID:1185959

Mao, Nannan; Lin, Yuxuan; Bie, Ya-Qing; +6 more

Ultralow-frequency collective compression mode and strong interlayer coupling in multilayer black phosphorus

Journal Article · Fri Feb 26 00:00:00 EST 2016 · Physical Review Letters · OSTI ID:1185959

Dong, Shan; Zhang, Anmin; Liu, Kai; +9 more

Low-Frequency Interlayer Raman Modes to Probe Interface of Twisted Bilayer MoS ₂

Journal Article · Sun Feb 21 00:00:00 EST 2016 · Nano Letters · OSTI ID:1185959

Huang, Shengxi; Liang, Liangbo; Ling, Xi; +6 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY

Title: Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus

Citation Formats

References (69)

Cited By (37)

Similar Records

Related Subjects