Atomically Thin Heterostructures Based on Single-Layer Tungsten Diselenide and Graphene [Plus Supplemental Information]

Lin, Yu-Chuan; Chang, Chih-Yuan S.; Ghosh, Ram Krishna; Li, Jie; Zhu, Hui; Addou, Rafik; Diaconescu, Bogdan; Ohta, Taisuke; Peng, Xin; Lu, Ning; Kim, Moon J.; Robinson, Jeremy T.; Wallace, Robert M.; Mayer, Theresa S.; Datta, Suman; Li, Lain-Jong; Robinson, Joshua A.

doi:10.1021/nl503144a

Title: Atomically Thin Heterostructures Based on Single-Layer Tungsten Diselenide and Graphene [Plus Supplemental Information]

Journal Article · Mon Nov 10 00:00:00 EST 2014 · Nano Letters

DOI:https://doi.org/10.1021/nl503144a· OSTI ID:1183087

Lin, Yu-Chuan ^[1]; Chang, Chih-Yuan S. ^[2]; Ghosh, Ram Krishna ^[3]; Li, Jie ^[3]; Zhu, Hui ^[4]; Addou, Rafik ^[4]; Diaconescu, Bogdan ^[5]; Ohta, Taisuke ^[5]; Peng, Xin ^[4]; Lu, Ning; Kim, Moon J. ^[4]; Robinson, Jeremy T. ^[6]; Wallace, Robert M. ^[5]; Mayer, Theresa S. ^[3]; Datta, Suman ^[3]; Li, Lain-Jong ^[2]; Robinson, Joshua A. ^[1]

Pennsylvania State Univ., University Park, PA (United States). Dept. of Materials Science and Engineering and Center for 2-Dimensional and Layered Materials
Inst. of Atomic and Molecular Sciences, Tapei (Taiwan)
Pennsylvania State Univ., University Park, PA (United States). Dept. of Electrical Engineering
Univ. of Texas at Dallas, Richardson, TX (United States). Dept. of Materials Science and Engineering
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Naval Research Lab. (NRL), Washington, DC (United States)

Heterogeneous engineering of two-dimensional layered materials, including metallic graphene and semiconducting transition metal dichalcogenides, presents an exciting opportunity to produce highly tunable electronic and optoelectronic systems. We report the direct growth of highly crystalline, monolayer tungsten diselenide (WSe₂) on epitaxial graphene (EG). Raman spectroscopy and photoluminescence confirms high-quality WSe₂ monolayers; while transmission electron microscopy shows an atomically sharp interface and low energy electron diffraction confirms near perfect orientation between WSe₂ and EG. Vertical transport measurements across the WSe₂/EG heterostructure provides evidence that a tunnel barrier exists due to the van der Waals gap, and is supported by density functional theory that predicts a 1.6 eV barrier for transport from WSe₂ to graphene.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1183087

Report Number(s):: SAND-2014-16778J; 536647

Journal Information:: Nano Letters, Vol. 14, Issue 12; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 104 works

Citation information provided by
Web of Science

References (30)

Van der Waals heterostructures Geim, A. K.; Grigorieva, I. V. Nature, Vol. 499, Issue 7459, p. 419-425 https://doi.org/10.1038/nature12385	journal	July 2013
Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures Britnell, L.; Gorbachev, R. V.; Jalil, R. Science, Vol. 335, Issue 6071 https://doi.org/10.1126/science.1218461	journal	February 2012
Atomically thin p–n junctions with van der Waals heterointerfaces Lee, Chul-Ho; Lee, Gwan-Hyoung; van der Zande, Arend M. Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.150	journal	August 2014
Cross-sectional imaging of individual layers and buried interfaces of graphene-based heterostructures and superlattices Haigh, S. J.; Gholinia, A.; Jalil, R. Nature Materials, Vol. 11, Issue 9 https://doi.org/10.1038/nmat3386	journal	July 2012
Direct Synthesis of van der Waals Solids Lin, Yu-Chuan; Lu, Ning; Perea-Lopez, Nestor ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn5003858	journal	March 2014
Direct Growth of Graphene/Hexagonal Boron Nitride Stacked Layers Liu, Zheng; Song, Li; Zhao, Shizhen Nano Letters, Vol. 11, Issue 5 https://doi.org/10.1021/nl200464j	journal	May 2011
van der Waals Epitaxy of MoS₂ Layers Using Graphene As Growth Templates Shi, Yumeng; Zhou, Wu; Lu, Ang-Yu Nano Letters, Vol. 12, Issue 6, p. 2784-2791 https://doi.org/10.1021/nl204562j	journal	May 2012
Graphene and boron nitride lateral heterostructures for atomically thin circuitry Levendorf, Mark P.; Kim, Cheol-Joo; Brown, Lola Nature, Vol. 488, Issue 7413, p. 627-632 https://doi.org/10.1038/nature11408	journal	August 2012
Evidence for Interlayer Coupling and Moiré Periodic Potentials in Twisted Bilayer Graphene Ohta, Taisuke; Robinson, Jeremy T.; Feibelman, Peter J. Physical Review Letters, Vol. 109, Issue 18 https://doi.org/10.1103/PhysRevLett.109.186807	journal	November 2012
Electronic Hybridization of Large-Area Stacked Graphene Films Robinson, Jeremy T.; Schmucker, Scott W.; Diaconescu, C. Bogdan ACS Nano, Vol. 7, Issue 1 https://doi.org/10.1021/nn304834p	journal	December 2012
Epitaxial graphene de Heer, Walt A.; Berger, Claire; Wu, Xiaosong Solid State Communications, Vol. 143, Issue 1-2 https://doi.org/10.1016/j.ssc.2007.04.023	journal	July 2007
Nucleation of Epitaxial Graphene on SiC(0001) Robinson, Joshua; Weng, Xiaojun; Trumbull, Kathleen ACS Nano, Vol. 4, Issue 1 https://doi.org/10.1021/nn901248j	journal	December 2009
Large-Area Synthesis of Highly Crystalline WSe ₂ Monolayers and Device Applications Huang, Jing-Kai; Pu, Jiang; Hsu, Chang-Lung ACS Nano, Vol. 8, Issue 1 https://doi.org/10.1021/nn405719x	journal	December 2013
Hole Contacts on Transition Metal Dichalcogenides: Interface Chemistry and Band Alignments McDonnell, Stephen; Azcatl, Angelica; Addou, Rafik ACS Nano, Vol. 8, Issue 6 https://doi.org/10.1021/nn501728w	journal	May 2014
Probing substrate-dependent long-range surface structure of single-layer and multilayer $Mo S_{2}$ by low-energy electron microscopy and microprobe diffraction Yeh, Po-Chun; Jin, Wencan; Zaki, Nader Physical Review B, Vol. 89, Issue 15 https://doi.org/10.1103/PhysRevB.89.155408	journal	April 2014
Direct observation of the transition from indirect to direct bandgap in atomically thin epitaxial MoSe2 Zhang, Yi; Chang, Tay-Rong; Zhou, Bo Nature Nanotechnology, Vol. 9, Issue 2 https://doi.org/10.1038/nnano.2013.277	journal	December 2013
Long-range atomic ordering and variable interlayer interactions in two overlapping graphene lattices with stacking misorientations Ohta, Taisuke; Beechem, Thomas E.; Robinson, Jeremy T. Physical Review B, Vol. 85, Issue 7 https://doi.org/10.1103/PhysRevB.85.075415	journal	February 2012
The transition metal dichalcogenides discussion and interpretation of the observed optical, electrical and structural properties Wilson, J. A.; Yoffe, A. D. Advances in Physics, Vol. 18, Issue 73 https://doi.org/10.1080/00018736900101307	journal	May 1969
Van der Waals epitaxy—a new epitaxial growth method for a highly lattice-mismatched system Koma, Atsushi Thin Solid Films, Vol. 216, Issue 1 https://doi.org/10.1016/0040-6090(92)90872-9	journal	August 1992
Epitaxial Monolayer MoS ₂ on Mica with Novel Photoluminescence Ji, Qingqing; Zhang, Yanfeng; Gao, Teng Nano Letters, Vol. 13, Issue 8 https://doi.org/10.1021/nl401938t	journal	July 2013
Homogeneous large-area graphene layer growth on $6 H$ -SiC(0001) Virojanadara, C.; Syväjarvi, M.; Yakimova, R. Physical Review B, Vol. 78, Issue 24 https://doi.org/10.1103/PhysRevB.78.245403	journal	December 2008
Quasi-Free-Standing Epitaxial Graphene on SiC Obtained by Hydrogen Intercalation Riedl, C.; Coletti, C.; Iwasaki, T. Physical Review Letters, Vol. 103, Issue 24 https://doi.org/10.1103/PhysRevLett.103.246804	journal	December 2009
Direct Imaging of Band Profile in Single Layer MoS ₂ on Graphite: Quasiparticle Energy Gap, Metallic Edge States, and Edge Band Bending Zhang, Chendong; Johnson, Amber; Hsu, Chang-Lung Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl501133c	journal	April 2014
Interface properties of CVD grown graphene transferred onto MoS ₂ (0001) Coy Diaz, Horacio; Addou, Rafik; Batzill, Matthias Nanoscale, Vol. 6, Issue 2 https://doi.org/10.1039/C3NR03692H	journal	January 2014
Ultrahigh-Gain Photodetectors Based on Atomically Thin Graphene-MoS2 Heterostructures Zhang, Wenjing; Chuu, Chih-Piao; Huang, Jing-Kai Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep03826	journal	January 2014
Large-Area Single-Layer MoSe ₂ and Its van der Waals Heterostructures Shim, Gi Woong; Yoo, Kwonjae; Seo, Seung-Bum ACS Nano, Vol. 8, Issue 7 https://doi.org/10.1021/nn405685j	journal	June 2014
Tunable Photoluminescence of Monolayer MoS ₂ via Chemical Doping Mouri, Shinichiro; Miyauchi, Yuhei; Matsuda, Kazunari Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl403036h	journal	November 2013
The effect of the substrate on the Raman and photoluminescence emission of single-layer MoS2 Buscema, Michele; Steele, Gary A.; van der Zant, Herre S. J. Nano Research, Vol. 7, Issue 4 https://doi.org/10.1007/s12274-014-0424-0	journal	April 2014
Structure of few-layer epitaxial graphene on 6H-SiC(0001) at atomic resolution Weng, Xiaojun; Robinson, Joshua A.; Trumbull, Kathleen Applied Physics Letters, Vol. 97, Issue 20 https://doi.org/10.1063/1.3517505	journal	November 2010
WSe₂ field effect transistors with enhanced ambipolar characteristics Das, Saptarshi; Appenzeller, Joerg Applied Physics Letters, Vol. 103, Issue 10, Article No. 103501 https://doi.org/10.1063/1.4820408	journal	September 2013

Cited By (28)

One dimensional metallic edges in atomically thin WSe ₂ induced by air exposure Addou, Rafik; Smyth, Christopher M.; Noh, Ji-Young 2D Materials, Vol. 5, Issue 2 https://doi.org/10.1088/2053-1583/aab0cd	journal	March 2018
A roadmap for electronic grade 2D materials Briggs, Natalie; Subramanian, Shruti; Lin, Zhong 2D Materials, Vol. 6, Issue 2 https://doi.org/10.1088/2053-1583/aaf836	journal	January 2019
Exciton polaritons in two-dimensional dichalcogenide layers placed in a planar microcavity: Tunable interaction between two Bose-Einstein condensates Vasilevskiy, Mikhail I.; Santiago-Pérez, Darío G.; Trallero-Giner, Carlos Physical Review B, Vol. 92, Issue 24 https://doi.org/10.1103/physrevb.92.245435	journal	December 2015
Two-dimensional GaSe/MoSe ₂ misfit bilayer heterojunctions by van der Waals epitaxy Li, Xufan; Lin, Ming-Wei; Lin, Junhao Science Advances, Vol. 2, Issue 4 https://doi.org/10.1126/sciadv.1501882	journal	April 2016
Interface-Induced WSe2 In-plane Homojunction for High-Performance Photodetection Chi, Jiawei; Guo, Nan; Sun, Yue Nanoscale Research Letters, Vol. 15, Issue 1 https://doi.org/10.1186/s11671-020-03342-9	journal	May 2020
WSe ₂ homojunctions and quantum dots created by patterned hydrogenation of epitaxial graphene substrates Pan, Yi; Fölsch, Stefan; Lin, Yu-Chuan 2D Materials, Vol. 6, Issue 2 https://doi.org/10.1088/2053-1583/aaf58c	journal	January 2019
Novel Optoelectronic Devices: Transition-Metal-Dichalcogenide-Based 2D Heterostructures Zeng, Qingsheng; Liu, Zheng Advanced Electronic Materials, Vol. 4, Issue 2 https://doi.org/10.1002/aelm.201700335	journal	January 2018
2D-Crystal-Based Functional Inks Bonaccorso, Francesco; Bartolotta, Antonino; Coleman, Jonathan N. Advanced Materials, Vol. 28, Issue 29 https://doi.org/10.1002/adma.201506410	journal	June 2016
2D materials and van der Waals heterostructures Novoselov, K. S.; Mishchenko, A.; Carvalho, A. Science, Vol. 353, Issue 6298 https://doi.org/10.1126/science.aac9439	journal	July 2016
Influence of a substrate on ultrafast interfacial charge transfer and dynamical interlayer excitons in monolayer WSe ₂ /graphene heterostructures Xing, Xiao; Zhao, Litao; Zhang, Wenjie Nanoscale, Vol. 12, Issue 4 https://doi.org/10.1039/c9nr09309e	journal	January 2020
Atomistic modeling of the metallic-to-semiconducting phase boundaries in monolayer MoS ₂ Saha, Dipankar; Mahapatra, Santanu Applied Physics Letters, Vol. 108, Issue 25 https://doi.org/10.1063/1.4954257	journal	June 2016
Substantial improvements of long-term stability in encapsulation-free WS ₂ using highly interacting graphene substrate Kim, Se-Yang; Kwak, Jinsung; Kim, Jung Hwa 2D Materials, Vol. 4, Issue 1 https://doi.org/10.1088/2053-1583/4/1/011007	journal	November 2016
The vertical growth of MoS ₂ layers at the initial stage of CVD from first-principles Xue, Xiong-Xiong; Feng, Yexin; Chen, Keqiu The Journal of Chemical Physics, Vol. 148, Issue 13 https://doi.org/10.1063/1.5010996	journal	April 2018
Parallel Stitching of 2D Materials Ling, Xi; Lin, Yuxuan; Ma, Qiong Advanced Materials, Vol. 28, Issue 12 https://doi.org/10.1002/adma.201505070	journal	January 2016
Progress, Challenges, and Opportunities for 2D Material Based Photodetectors Long, Mingsheng; Wang, Peng; Fang, Hehai Advanced Functional Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adfm.201803807	journal	September 2018
2D materials advances: from large scale synthesis and controlled heterostructures to improved characterization techniques, defects and applications Lin, Zhong; McCreary, Amber; Briggs, Natalie 2D Materials, Vol. 3, Issue 4 https://doi.org/10.1088/2053-1583/3/4/042001	journal	December 2016
Band Structure Engineering in 2D Materials for Optoelectronic Applications Bao, Xiaozhi; Ou, Qingdong; Xu, Zai-Quan Advanced Materials Technologies, Vol. 3, Issue 11 https://doi.org/10.1002/admt.201800072	journal	September 2018
Scalable BEOL compatible 2D tungsten diselenide Kozhakhmetov, Azimkhan; Nasr, Joseph R.; Zhang, Fu 2D Materials, Vol. 7, Issue 1 https://doi.org/10.1088/2053-1583/ab5ad1	journal	December 2019
Multimodal spectromicroscopy of monolayer WS ₂ enabled by ultra-clean van der Waals epitaxy Kastl, C.; Chen, C. T.; Koch, R. J. 2D Materials, Vol. 5, Issue 4 https://doi.org/10.1088/2053-1583/aad21c	journal	July 2018
Physical properties of low-dimensional ${s p}^{2}$ -based carbon nanostructures Meunier, V.; Souza Filho, A. G.; Barros, E. B. Reviews of Modern Physics, Vol. 88, Issue 2 https://doi.org/10.1103/revmodphys.88.025005	journal	May 2016
Strain-Mediated Stability of Structures and Electronic Properties of ReS ₂ , Janus ReSSe, and ReSe ₂ Monolayers Zong, Jia-Qi; Zhang, Shu-Feng; Ji, Wei-Xiao Journal of Nanomaterials, Vol. 2019 https://doi.org/10.1155/2019/9239487	journal	October 2019
Tuning the Electronic and Photonic Properties of Monolayer MoS ₂ via In Situ Rhenium Substitutional Doping Zhang, Kehao; Bersch, Brian M.; Joshi, Jaydeep Advanced Functional Materials, Vol. 28, Issue 16 https://doi.org/10.1002/adfm.201706950	journal	February 2018
A General Method for the Chemical Synthesis of Large-Scale, Seamless Transition Metal Dichalcogenide Electronics Li, Li; Guo, Yichuan; Sun, Yuping Advanced Materials, Vol. 30, Issue 12 https://doi.org/10.1002/adma.201706215	journal	January 2018
Misfit strain-induced energy dissipation for graphene/MoS ₂ heterostructure nanomechanical resonators He, Ji-Dong; Jiang, Jin-Wu Nanotechnology, Vol. 30, Issue 26 https://doi.org/10.1088/1361-6528/ab0f86	journal	April 2019
Theory of optically induced Förster coupling in van der Waals coupled heterostructures Selig, Malte; Malic, Ermin; Ahn, Kwang Jun Physical Review B, Vol. 99, Issue 3 https://doi.org/10.1103/physrevb.99.035420	journal	January 2019
2D materials and van der Waals heterostructures Novoselov, K. S.; Mishchenko, A.; Carvalho, A. arXiv https://doi.org/10.48550/arxiv.1608.03059	text	January 2016
Atomically Sharp Interface in an h-BN-epitaxial graphene van der Waals Heterostructure Sediri, Haikel; Pierucci, Debora; Hajlaoui, Mahdi Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep16465	journal	November 2015
Na-ion Storage Performances of FeSex and Fe2O3 Hollow Nanoparticles-Decorated Reduced Graphene Oxide Balls prepared by Nanoscale Kirkendall Diffusion Process Park, Gi Dae; Cho, Jung Sang; Lee, Jung-Kul Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep22432	journal	February 2016

Similar Records

Hybrid Heterostructures to Generate Long-Lived and Mobile Photocarriers in Graphene

Journal Article · Thu Feb 16 00:00:00 EST 2023 · ACS Nano · OSTI ID:1183087

Valencia-Acuna, Pavel; Rudayni, Fatimah; Rijal, Kushal; +2 more

Selective Transfer of Rotationally Commensurate MoS₂ from an Epitaxially Grown van der Waals Heterostructure

Journal Article · Fri Nov 16 00:00:00 EST 2018 · Chemistry of Materials · OSTI ID:1183087

Kang, Junmo; Balla, Itamar; Liu, Xiaolong; +4 more

Observation of long-lived interlayer excitons in monolayer MoSe₂–WSe₂ heterostructures

Journal Article · Tue Feb 24 00:00:00 EST 2015 · Nature Communications · OSTI ID:1183087

Rivera, Pasqual; Schaibley, John R.; Jones, Aaron M.; +11 more

Related Subjects

36 MATERIALS SCIENCE

Title: Atomically Thin Heterostructures Based on Single-Layer Tungsten Diselenide and Graphene [Plus Supplemental Information]

Citation Formats

References (30)

Cited By (28)

Similar Records

Related Subjects