Method for halogenating or radiohalogenating a chemical compound

Kabalka, George W.

Title: Method for halogenating or radiohalogenating a chemical compound

Patent · Tue May 09 00:00:00 EDT 2006

OSTI ID:1175735

Kabalka, George W.

A method for obtaining a halogenated organic compound, whereby an organotrifluoroborate compound is reacted with a halide ion in the presence of an oxidizing agent to produce the corresponding halogenated organic compound. The method may be used for producing radiohalogenated organic compounds.

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Research Organization:: University Of Tennessee Research Foundation, Knoxville, TN (United States)

Sponsoring Organization:: USDOE

Assignee:: University Of Tennessee Research Foundation

Patent Number(s):: 7,041,859

Application Number:: 11/174,797

OSTI ID:: 1175735

Country of Publication:: United States

Language:: English

References (9)

Cross-coupling reactions of arenediazonium tetrafluoroborates with potassium aryl- or alkenyltrifluoroborates catalyzed by palladium Darses, Sylvain; Genêt, Jean-Pierre; Brayer, Jean-Louis Tetrahedron Letters, Vol. 38, Issue 25 https://doi.org/10.1016/S0040-4039(97)00939-8	journal	June 1997
Iodination of organotrifluoroborates: synthesis of vinyl and alkynyl iodides Kabalka, George W.; Reddy Mereddy, Arjun Tetrahedron Letters, Vol. 45, Issue 7 https://doi.org/10.1016/j.tetlet.2003.12.050	journal	February 2004
Potassium Organotrifluoroborates: New Partners in Palladium-Catalysed Cross-Coupling Reactions Darses, Sylvain; Michaud, Guillaume; Genêt, Jean-Pierre European Journal of Organic Chemistry, Vol. 1999, Issue 8, p. 1875-1883 https://doi.org/10.1002/(SICI)1099-0690(199908)1999:8<1875::AID-EJOC1875>3.0.CO;2-W	journal	August 1999
A facile synthesis of aryl iodides via potassium aryltrifluoroborates Kabalka, George W.; Mereddy, Arjun R. Tetrahedron Letters, Vol. 45, Issue 2 https://doi.org/10.1016/j.tetlet.2003.10.149	journal	January 2004
Conversion of Arylboronic Acids into Potassium Aryltrifluoroborates: Convenient Precursors of Arylboron Difluoride Lewis Acids Vedejs, E.; Chapman, R. W.; Fields, S. C. The Journal of Organic Chemistry, Vol. 60, Issue 10 https://doi.org/10.1021/jo00115a016	journal	May 1995
Synthesis of Organic Bromides via Organotrifluoroborates Kabalka, George W.; Mereddy, Arjun Reddy Organometallics, Vol. 23, Issue 19 https://doi.org/10.1021/om049685s	journal	September 2004
Palladium-Catalyzed Cross-Coupling of Acetates of Baylis−Hillman Adducts and Potassium Organotrifluoroborates Kabalka, George W.; Venkataiah, Bollu; Dong, Gang Organic Letters, Vol. 5, Issue 21 https://doi.org/10.1021/ol0351798	journal	October 2003
Development of the Suzuki−Miyaura Cross-Coupling Reaction: Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations Molander, Gary A.; Katona, Bryson W.; Machrouhi, Fouzia The Journal of Organic Chemistry, Vol. 67, Issue 24 https://doi.org/10.1021/jo0262356	journal	November 2002
Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates ^† Molander, Gary A.; Rivero, Marta Rodríguez Organic Letters, Vol. 4, Issue 1 https://doi.org/10.1021/ol0169729	journal	January 2002

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