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Title: Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage

Patent ·
OSTI ID:1175467
; ; ; ;

An isoreticular metal-organic framework (IRMOF) and method for systematically forming the same. The method comprises the steps of dissolving at least one source of metal cations and at least one organic linking compound in a solvent to form a solution; and crystallizing the solution under predetermined conditions to form a predetermined IRMOF. At least one of functionality, dimension, pore size and free volume of the IRMOF is substantially determined by the organic linking compound.

Research Organization:
Univ. of Michigan, Ann Arbor, MI (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-99ER15000; FG03-98ER14903
Assignee:
The Regents of the University of Michigan (Ann Arbor, MI)
Patent Number(s):
6,930,193
Application Number:
10/137,043
OSTI ID:
1175467
Country of Publication:
United States
Language:
English

References (18)

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Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1 journal May 2000
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Lithium Insertion into Titanium Phosphates, Silicates, and Sulfates journal December 2002
Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal November 1999
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van der Waals Volumes and Radii journal March 1964
Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments journal July 1989
Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate) journal March 1998
Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties journal February 2000
Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures journal August 2001
Organic-functionalized molecular sieves as shape-selective catalysts journal May 1998
Design of an adsorbent with an ideal pore structure for methane adsorption using metal complexes journal January 2001
Turning Down the Heat: Design and Mechanism in Solid-State Synthesis journal March 1993
Variable Pore Size, Variable Chemical Functionality, and an Example of Reactivity within Porous Phenylacetylene Silver Salts journal September 1999

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