AgI-MOR Loading Effect on the Durability of the Sandia Low Temperature Sintering GCM Waste Form

Technical Report · Mon Sep 01 00:00:00 EDT 2014

DOI:https://doi.org/10.2172/1171567· OSTI ID:1171567

Nenoff, Tina Maria ^[1]; Brady, Patrick Vane. ^[1]; Mowry, Curtis D. ^[1]; Garino, Terry J. ^[1]

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1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Herein, we study the durability of the Sandia Bi-Si oxide Glass Composite Material (GCM) waste form when formulated with different weight percent levels of AgI-MOR. The post-iodine exposure AgI-MOR material was provided to SNL by ORNL. Durability results for the GCM fabricated with 22 and 25% AgI-MOR indicate releases of Ag and I at the same low rates as 15% AgI-MOR GCM, and by the same mechanism. Iodine and Ag release is controlled by the low solubility of an amorphous, hydrated silver iodide, not by the surface-controlled dissolution of I₂- loaded Ag-Mordenite. Based on this data, we postulate that much higher loading levels of AgIMOR are probable in this GCM waste form, and limits will govern by retention of mechanical integrity of the GCM versus the solubility of silver iodide.

• Research Organization: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
• Sponsoring Organization: USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)
• DOE Contract Number: AC04-94AL85000
• OSTI ID: 1171567
• Report Number(s): SAND2014-17380R; 537267
• Country of Publication: United States
• Language: English

Related Subjects

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES