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Title: Zeolitic imidazolate frameworks for kinetic separation of propane and propene

Patent ·
OSTI ID:1150001

Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.

Research Organization:
Rutgers, The State Univ. of New Jersey, New Brunswick, NJ (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-08ER46491
Assignee:
Rutgers, The State University of New Jersey (New Brunswick, NJ)
Patent Number(s):
8,796,462
Application Number:
13/109,614
OSTI ID:
1150001
Resource Relation:
Patent File Date: 2011 May 17
Country of Publication:
United States
Language:
English

References (19)

Enumeration of Not-Yet-Synthesized Zeolitic Zinc Imidazolate MOF Networks: A Topological and DFT Approach journal August 2008
Hydrogen Storage in a Prototypical Zeolitic Imidazolate Framework-8 journal May 2007
Zeolitic Boron Imidazolate Frameworks journal March 2009
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs journal May 2008
Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties journal March 2009
Design and Generation of Extended Zeolitic Metal–Organic Frameworks (ZMOFs): Synthesis and Crystal Structures of Zinc(II) Imidazolate Polymers with Zeolitic Topologies journal May 2007
Quasi-Free Methyl Rotation in Zeolitic Imidazolate Framework-8 journal December 2008
Eight coordination with bis(bidentate) bridging ligands: zeolitic topology versus square grid networks journal January 2008
New Zeolitic Imidazolate Frameworks: From Unprecedented Assembly of Cubic Clusters to Ordered Cooperative Organization of Complementary Ligands journal December 2008
Understanding the Adsorption and Diffusion of Carbon Dioxide in Zeolitic Imidazolate Frameworks: A Molecular Simulation Study journal February 2009
A New Zeolitic Topology with Sixteen-Membered Ring and Multidimensional Large Pore Channels journal September 2008
High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture journal February 2008
Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
  • Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627 https://doi.org/10.1021/ja805222x
journal September 2008
Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene journal August 2009
Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework journal April 2009
Adsorption of propane, propylene and isobutane on a metal–organic framework: Molecular simulation and experiment journal July 2009
Zeolite A imidazolate frameworks journal May 2007
Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies journal February 2006

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