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Title: Combined raman and IR fiber-based sensor for gas detection

Patent ·
OSTI ID:1135723

A double-pass fiber-optic based spectroscopic gas sensor delivers Raman excitation light and infrared light to a hollow structure, such as a hollow fiber waveguide, that contains a gas sample of interest. A retro-reflector is placed at the end of this hollow structure to send the light back through the waveguide where the light is detected at the same end as the light source. This double pass retro reflector design increases the interaction path length of the light and the gas sample, and also reduces the form factor of the hollow structure.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-07NA27344
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA); University of South Carolina (Columbia, SC); Georgia Tech Research Corporation (Atlanta, GA)
Patent Number(s):
8,759,767
Application Number:
12/545,566
OSTI ID:
1135723
Resource Relation:
Patent File Date: 2009 Aug 21
Country of Publication:
United States
Language:
English

References (37)

Gas cell for raman scattering analysis by laser means patent June 1987
Method and apparatus for detecting gas patent November 1987
Optical-fiber raman spectroscopy used for remote in-situ environmental analysis patent February 1989
Gas species monitor system patent September 1990
Gas sample chamber patent October 1991
Velocity measurement by the vibrational tagging of diatomic molecules patent May 1992
Gas sample chamber patent November 1992
Multi-channel gas sample chamber patent June 1993
Spectroscopic cell design patent September 1994
Diode laser pumped Raman gas analysis system with reflective hollow tube gas cell patent May 1996
Method and apparatus for generating high power laser pulses in the two to six micron wavelength range patent December 1996
Method for monitoring particulates using beam-steered solid-state light source patent November 1998
Furnace for an engine exhaust measurement system patent September 2001
Infrared spectrometer for the measurement of isotopic ratios patent November 2002
Tubular-waveguide gas sample chamber for optical spectrometer, and related methods patent March 2003
Metallic gas cells and method for manufacturing the same patent October 2005
Optical multipass cell for repeated passing of light through the same point patent July 2012
Rotationally asymmetric chaotic optical multi-pass cavity patent October 2012
Method for detecting a gas species using a super tube waveguide patent-application June 2007
Optical multipass cell for repeated passing of light through the same point patent-application September 2008
Rotationally Asymmetric Chaotic Optical Multi-Pass Cavity patent-application March 2009
Gas Analyzer Systems patent-application August 2009
Optical Multipass Cell for Repeated Passing of Light Through the Same Point patent-application August 2010
Performance of Fiber-Optic Raman Probes for Analysis of Gas Mixtures in Enclosures journal January 2002
Hollow-waveguide gas sensing with room-temperature quantum cascade lasers journal January 2003
Review of hollow waveguide technology conference May 1995
Methane concentration and isotopic composition measurements with a mid-infrared quantum-cascade laser journal January 1999
High-power continuous-wave mid-infrared radiation generated by difference frequency mixing of diode-laser-seeded fiber amplifiers and its application to dual-beam spectroscopy journal January 1999
Portable fiber-coupled diode-laser-based sensor for multiple trace gas detection journal December 1999
Real-time measurements of trace gases using a compact difference-frequency-based sensor operating at 3.5 μm journal September 1998
Detection of formaldehyde using mid-infrared difference-frequency generation journal December 1997
Compact laser difference-frequency spectrometer for multicomponent trace gas detection journal May 1998
Precise measurement of methane in air using diode-pumped 3.4-μm difference-frequency generation in PPLN journal May 1997
Compact mid-infrared trace gas sensor based on difference-frequency generation of two diode lasers in periodically poled LiNbO 3 journal September 1998
Tunable, fiber coupled spectrometer based on difference-frequency generation in periodically poled lithium niobate conference January 2001
Laser Based Absorption Sensors for Trace Gas Monitoring in a Spacecraft Habitat conference July 1999
Room-temperature mid-infrared laser sensor for trace gas detection journal January 1997