Kinetics of the reaction between hydroxylamine and sodium bisulfite

Journal Article · Sat Aug 01 00:00:00 EDT 1981 · Journal of Physical Chemistry

DOI:https://doi.org/10.1021/j150617a030· OSTI ID:1134726

Gomiscek, S. ^[1]; Clem, R. ^[1]; Novakov, T. ^[1]; Chang, S. G. ^[1]

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1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)

Hydroxylamine and sulfur dioxide react in aqueous solution to form either sulfamic acid or ammonium bisulfate. Rate studies have been performed as a function of temperature. The rate law has been determined. For this research, the enthalpy and entropy of activation for the formation of both sulfamic acid and ammonium bisulfate have been evaluated.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
• Sponsoring Organization: USDOE; USDOE Morgantown Energy Technology Center (MET)
• DOE Contract Number: AC02-05CH11231; W-7405-ENG-48
• OSTI ID: 1134726
• Report Number(s): LBL-12008
• Journal Information: Journal of Physical Chemistry, Vol. 85, Issue 17; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY