Method of enhanced lithiation of doped silicon carbide via high temperature annealing in an inert atmosphere

Hersam, Mark C.; Lipson, Albert L.; Bandyopadhyay, Sudeshna; Karmel, Hunter J; Bedzyk, Michael J

Title: Method of enhanced lithiation of doped silicon carbide via high temperature annealing in an inert atmosphere

Patent · Tue May 27 00:00:00 EDT 2014

OSTI ID:1133446

Hersam, Mark C.; Lipson, Albert L.; Bandyopadhyay, Sudeshna; Karmel, Hunter J; Bedzyk, Michael J

A method for enhancing the lithium-ion capacity of a doped silicon carbide is disclosed. The method utilizes heat treating the silicon carbide in an inert atmosphere. Also disclosed are anodes for lithium-ion batteries prepared by the method.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: Northwestern University (Evanston, IL)

Patent Number(s):: 8,734,674

Application Number:: 13/457,070

OSTI ID:: 1133446

Country of Publication:: United States

Language:: English

References (54)

Process for the thermal annealing of implantation-doped silicon carbide semiconductors Hölzlein, Karlheinz; Rupp, Roland; Wiedenhofer, Arno https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6406983 US Patent Document 6,406,983	patent	June 2002
Solution-Grown Silicon Nanowires for Lithium-Ion Battery Anodes Chan, Candace K.; Patel, Reken N.; O’Connell, Michael J. ACS Nano, Vol. 4, Issue 3 https://doi.org/10.1021/nn901409q	journal	March 2010
In-Plane Vacancy-Enabled High-Power Si-Graphene Composite Electrode for Lithium-Ion Batteries Zhao, Xin; Hayner, Cary M.; Kung, Mayfair C. Advanced Energy Materials, Vol. 1, Issue 6, p. 1079-1084 https://doi.org/10.1002/aenm.201100426	journal	October 2011
Strain Anisotropies and Self-Limiting Capacities in Single-Crystalline 3D Silicon Microstructures: Models for High Energy Density Lithium-Ion Battery Anodes Goldman, Jason L.; Long, Brandon R.; Gewirth, Andrew A. Advanced Functional Materials, Vol. 21, Issue 13, p. 2412-2422 https://doi.org/10.1002/adfm.201002487	journal	April 2011
The 6H-SiC structure model: Further refinement from SCXRD data from a terrestrial moissanite Capitani, G. C.; Di Pierro, S.; Tempesta, G. American Mineralogist, Vol. 92, Issue 2-3 https://doi.org/10.2138/am.2007.2346	journal	February 2007
Highly Reversible Lithium Storage in Spheroidal Carbon-Coated Silicon Nanocomposites as Anodes for Lithium-Ion Batteries Ng, See-How; Wang, Jiazhao; Wexler, David Angewandte Chemie International Edition, Vol. 45, Issue 41, p. 6896-6899 https://doi.org/10.1002/anie.200601676	journal	October 2006
Diffuse x-ray streaks from stacking faults in Si analyzed by atomistic simulations Nordlund, K.; Beck, U.; Metzger, T. H. Applied Physics Letters, Vol. 76, Issue 7 https://doi.org/10.1063/1.125604	journal	February 2000
Electron energy-loss spectrometry on lithiated graphite Hightower, A.; Ahn, C. C.; Fultz, B. Applied Physics Letters, Vol. 77, Issue 2 https://doi.org/10.1063/1.126936	journal	July 2000
Transitional structures of the interface between graphene and 6H–SiC (0001) Norimatsu, Wataru; Kusunoki, Michiko Chemical Physics Letters, Vol. 468, Issue 1-3, p. 52-56 https://doi.org/10.1016/j.cplett.2008.11.095	journal	January 2009
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Enhanced reversible lithium storage in a nanosize silicon/graphene composite Chou, Shu-Lei; Wang, Jia-Zhao; Choucair, Mohammad Electrochemistry Communications, Vol. 12, Issue 2, p. 303-306 https://doi.org/10.1016/j.elecom.2009.12.024	journal	February 2010
Composite anode material of silicon/graphite/carbon nanotubes for Li-ion batteries Zhang, Y.; Zhang, X. G.; Zhang, H. L. Electrochimica Acta, Vol. 51, Issue 23, p. 4994-5000 https://doi.org/10.1016/j.electacta.2006.01.043	journal	June 2006
Enhanced Performance in Epitaxial Graphene FETs With Optimized Channel Morphology Lin, Yu-Ming; Farmer, Damon B.; Jenkins, Keith A. IEEE Electron Device Letters, Vol. 32, Issue 10 https://doi.org/10.1109/LED.2011.2162934	journal	October 2011
Epitaxial Graphene Transistors on SiC Substrates Kedzierski, Jakub; Hsu, Pei-Lan; Healey, Paul IEEE Transactions on Electron Devices, Vol. 55, Issue 8 https://doi.org/10.1109/TED.2008.926593	journal	August 2008
Improvement of the Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn ₂ O ₄ Vidu, Ruxandra; Stroeve, Pieter Industrial & Engineering Chemistry Research, Vol. 43, Issue 13 https://doi.org/10.1021/ie034085z	journal	June 2004
Inner shell edge profiles in electron energy loss spectroscopy Ahn, Channing C.; Rez, Peter Ultramicroscopy, Vol. 17, Issue 2, p. 105-115 https://doi.org/10.1016/0304-3991(85)90003-8	journal	January 1985
The true crystal structure of Li₁₇M₄ (M=Ge, Sn, Pb)–revised from Li₂₂M₅ Goward, G. R.; Taylor, N. J.; Souza, D. C. S. Journal of Alloys and Compounds, Vol. 329, Issue 1-2, p. 82-91 https://doi.org/10.1016/S0925-8388(01)01567-5	journal	November 2001
Lattice site location of ion-implanted 8Li in Silicon Carbide Virdis, S.; Vetter, U.; Ronning, C. Journal of Applied Physics, Vol. 91, Issue 3 https://doi.org/10.1063/1.1425442	journal	February 2002
Evolution and structure of low-angle grain boundaries in 6H–SiC single crystals grown by sublimation method Gao, Yuqiang; Hu, Xiaobo; Chen, Xiufang Journal of Crystal Growth, Vol. 312, Issue 20, p. 2909-2913 https://doi.org/10.1016/j.jcrysgro.2010.06.031	journal	October 2010
Graphene-based electrode materials for rechargeable lithium batteries Liang, Minghui; Zhi, Linjie Journal of Materials Chemistry, Vol. 19, Issue 33 https://doi.org/10.1039/B901551E	journal	January 2009
Ultrathin Epitaxial Graphite: 2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics Berger, Claire; Song, Zhimin; Li, Tianbo The Journal of Physical Chemistry B, Vol. 108, Issue 52, p. 19912-19916 https://doi.org/10.1021/jp040650f	journal	December 2004
Core−Shell Li ₃ V ₂ (PO ₄ ) ₃ @C Composites as Cathode Materials for Lithium-Ion Batteries Ren, M. M.; Zhou, Z.; Gao, X. P. The Journal of Physical Chemistry C, Vol. 112, Issue 14 https://doi.org/10.1021/jp800040s	journal	March 2008
The First-Cycle Electrochemical Lithiation of Crystalline Ge: Dopant and Orientation Dependence and Comparison with Si Chan, Maria K. Y.; Long, Brandon R.; Gewirth, Andrew A. The Journal of Physical Chemistry Letters, Vol. 2, Issue 24 https://doi.org/10.1021/jz201432d	journal	November 2011
Si–SiC nanocomposite anodes synthesized using high-energy mechanical milling Kim, Il-seok; Blomgren, G. E.; Kumta, P. N. Journal of Power Sources, Vol. 130, Issue 1-2, p. 275-280 https://doi.org/10.1016/j.jpowsour.2003.12.014	journal	May 2004
Carbon nanotubes (CNTs) as a buffer layer in silicon/CNTs composite electrodes for lithium secondary batteries Kim, Taeahn; Mo, Y. H.; Nahm, K. S. Journal of Power Sources, Vol. 162, Issue 2, p. 1275-1281 https://doi.org/10.1016/j.jpowsour.2006.07.062	journal	November 2006
Lithium K(1s) synchrotron NEXAFS spectra of lithium-ion battery cathode, anode and electrolyte materials Braun, Artur; Wang, Hongxin; Shim, Joongpyo Journal of Power Sources, Vol. 170, Issue 1, p. 173-178 https://doi.org/10.1016/j.jpowsour.2007.04.022	journal	June 2007
Reversible high capacity nanocomposite anodes of Si/C/SWNTs for rechargeable Li-ion batteries Wang, Wei; Kumta, Prashant N. Journal of Power Sources, Vol. 172, Issue 2, p. 650-658 https://doi.org/10.1016/j.jpowsour.2007.05.025	journal	October 2007
Effect of FePO₄ coating on electrochemical and safety performance of LiCoO₂ as cathode material for Li-ion batteries Li, Gang; Yang, Zhanxu; Yang, Wensheng Journal of Power Sources, Vol. 183, Issue 2, p. 741-748 https://doi.org/10.1016/j.jpowsour.2008.05.047	journal	September 2008
Thermal and electrochemical behavior of yttria-stabilized zirconia coated LiCoO₂ during overcharge tests Fey, George Ting-Kuo; Hsiao, Chiao-Ling; Muralidharan, Pandurangan Journal of Power Sources, Vol. 189, Issue 1, p. 837-840 https://doi.org/10.1016/j.jpowsour.2008.07.016	journal	April 2009
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model Peled, E. Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128859	journal	January 1979
Change of Conductivity with Salt Content, Solvent Composition, and Temperature for Electrolytes of LiPF[sub 6] in Ethylene Carbonate-Ethyl Methyl Carbonate Ding, M. S.; Xu, K.; Zhang, S. S. Journal of The Electrochemical Society, Vol. 148, Issue 10 https://doi.org/10.1149/1.1403730	journal	January 2001
Electrochemical Evaluation and Structural Characterization of Commercial LiCoO[sub 2] Surfaces Modified with MgO for Lithium-Ion Batteries Wang, Zhaoxiang; Wu, Chuan; Liu, Lijun Journal of The Electrochemical Society, Vol. 149, Issue 4 https://doi.org/10.1149/1.1456919	journal	January 2002
Suppression of Cobalt Dissolution from the LiCoO[sub 2] Cathodes with Various Metal-Oxide Coatings Kim, Yong Jeong; Cho, Jaephil; Kim, Tae-Joon Journal of The Electrochemical Society, Vol. 150, Issue 12 https://doi.org/10.1149/1.1627347	journal	January 2003
Electrochemical Characterizations on Si and C-Coated Si Particle Electrodes for Lithium-Ion Batteries Liu, Wei-Ren; Wang, Jen-Hao; Wu, Hung-Chun Journal of The Electrochemical Society, Vol. 152, Issue 9 https://doi.org/10.1149/1.1954967	journal	January 2005
Enhanced Stability of LiCoO₂ Cathodes in Lithium-Ion Batteries Using Surface Modification by Atomic Layer Deposition Jung, Yoon Seok; Cavanagh, Andrew S.; Dillon, Anne C. Journal of The Electrochemical Society, Vol. 157, Issue 1, p. A75-A81 https://doi.org/10.1149/1.3258274	journal	January 2010
Preparation of transmission electron microscopy cross-section specimens using focused ion beam milling Langford, R. M.; Petford-Long, A. K. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 19, Issue 5 https://doi.org/10.1116/1.1378072	journal	September 2001
Studies on the Anode/Electrolyte Interfacein Lithium Ion Batteries Winter, Martin; Appel, Wolfgang K.; Evers, Bernd Monatshefte fuer Chemie/Chemical Monthly, Vol. 132, Issue 4 https://doi.org/10.1007/s007060170110	journal	April 2001
Superior Lithium Electroactive Mesoporous Si@Carbon Core−Shell Nanowires for Lithium Battery Anode Material Kim, Hyesun; Cho, Jaephil Nano Letters, Vol. 8, Issue 11, p. 3688-3691 https://doi.org/10.1021/nl801853x	journal	November 2008
Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries Cui, Li-Feng; Yang, Yuan; Hsu, Ching-Mei Nano Letters, Vol. 9, Issue 9, p. 3370-3374 https://doi.org/10.1021/nl901670t	journal	September 2009
Functionally Strain-Graded Nanoscoops for High Power Li-Ion Battery Anodes Krishnan, Rahul; Lu, Toh-Ming; Koratkar, Nikhil Nano Letters, Vol. 11, Issue 2 https://doi.org/10.1021/nl102981d	journal	February 2011
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Substrate-induced bandgap opening in epitaxial graphene Zhou, S. Y.; Gweon, G. -H.; Fedorov, A. V. Nature Materials, Vol. 6, Issue 10 https://doi.org/10.1038/nmat2003	journal	September 2007
Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide Emtsev, Konstantin V.; Bostwick, Aaron; Horn, Karsten Nature Materials, Vol. 8, Issue 3 https://doi.org/10.1038/nmat2382	journal	February 2009
K , L , and M shell generalized oscillator strengths and ionization cross sections for fast electron collisions Leapman, R. D.; Rez, P.; Mayers, D. F. The Journal of Chemical Physics, Vol. 72, Issue 2 https://doi.org/10.1063/1.439184	journal	January 1980
Thickness dependence of microstructures in La_0.9Sr_0.1MnO₃ thin films grown on exact-cut and miscut SrTiO₃ substrates Zhang, Hong-Di; An, Yu-Kai; Mai, Zhen-Hong Physica B: Condensed Matter, Vol. 403, Issue 12, p. 2008-2014 https://doi.org/10.1016/j.physb.2007.11.009	journal	June 2008
Compton Scattering of X Rays from Bound Electrons Eisenberger, P.; Platzman, P. M. Physical Review A, Vol. 2, Issue 2 https://doi.org/10.1103/PhysRevA.2.415	journal	August 1970
Local field effects at Li K edges in electron energy-loss spectra of Li, ${Li}_{2} O$ and LiF Mauchamp, V.; Moreau, P.; Ouvrard, G. Physical Review B, Vol. 77, Issue 4 https://doi.org/10.1103/PhysRevB.77.045117	journal	January 2008
Interface structure of epitaxial graphene grown on 4H-SiC(0001) Hass, J.; Millán-Otoya, J. E.; First, P. N. Physical Review B, Vol. 78, Issue 20 https://doi.org/10.1103/PhysRevB.78.205424	journal	November 2008
Epitaxial graphene on $6 H -SiC$ and Li intercalation Virojanadara, C.; Watcharinyanon, S.; Zakharov, A. A. Physical Review B, Vol. 82, Issue 20 https://doi.org/10.1103/PhysRevB.82.205402	journal	November 2010
Interaction, growth, and ordering of epitaxial graphene on SiC{0001} surfaces: A comparative photoelectron spectroscopy study Emtsev, K. V.; Speck, F.; Seyller, Th. Physical Review B, Vol. 77, Issue 15 https://doi.org/10.1103/PhysRevB.77.155303	journal	April 2008
Total-Reflection Inelastic X-Ray Scattering from a 10-nm Thick ${La}_{0.6} {Sr}_{0.4} {CoO}_{3}$ Thin Film Fister, T. T.; Fong, D. D.; Eastman, J. A. Physical Review Letters, Vol. 106, Issue 3 https://doi.org/10.1103/PhysRevLett.106.037401	journal	January 2011
Multielement spectrometer for efficient measurement of the momentum transfer dependence of inelastic x-ray scattering Fister, T. T.; Seidler, G. T.; Wharton, L. Review of Scientific Instruments, Vol. 77, Issue 6 https://doi.org/10.1063/1.2204581	journal	June 2006
Electronic Confinement and Coherence in Patterned Epitaxial Graphene Berger, C. Science, Vol. 312, Issue 5777 https://doi.org/10.1126/science.1125925	journal	May 2006
Structural analysis of PTCDA monolayers on epitaxial graphene with ultra-high vacuum scanning tunneling microscopy and high-resolution X-ray reflectivity Emery, Jonathan D.; Wang, Qing Hua; Zarrouati, Marie Surface Science, Vol. 605, Issue 17-18, p. 1685-1693 https://doi.org/10.1016/j.susc.2010.11.008	journal	September 2011

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