Effects of Lewis acid catalysts on the hydrogenation and cracking of two-ring aromatic and hydroaromatic structures related to coal

Journal Article · Sun Aug 01 00:00:00 EDT 1982 · Fuel

DOI:https://doi.org/10.1016/0016-2361(82)90251-4· OSTI ID:1108764

Salim, Sadie S. ^[1]; Bell, Alexis T. ^[2]

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1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials and Molecular Research Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering; Chevron Research Corporation, Richmond, CA (United States)
2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials and Molecular Research Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering

Little is known about the hydrogenation of fused aromatic nuclei during the liquefaction of coal under the influence of Lewis acid catalysts. For this paper, this study was conducted to establish the effects of catalyst acidity on the activity and selectivity of Lewis acid catalysts, the sources of hydrogen involved in hydrogenation and cracking, and the relations between reactant structure and reactivity. Two-ring aromatic and hydroaromatic compounds were used to simulate some of the structural units present in coal. The catalysts examined were ZnCl₂ and AlCl₃. ZnCl₂ is less active than AlCl₃ for both hydrogenation and cracking but it does not promote the formation of tars via Scholl condensation: Methyl or hydroxyl substitution of the reactants greatly enhances their reactivity towards hydrogenation and cracking. The source of hydrogen consumed during hydrogenation depends on the choice of catalyst. In the presence of AlCl₃, Scholl condensation of aromatic nuclei serves as the principal source of hydrogen. Molecular hydrogen is used exclusively, though, when hydrogenation is catalysed by ZnCl₂. The formation of reaction products and the trends in reactant reactivity can be interpreted on the basis of carbonium ion mechanisms. Finally, the results of this study provide a basis for assessing the extent of hydrogenation occurring during the liquefaction of coal using ZnCl₂ or AlCl₃.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 1108764
• Report Number(s): LBL-11855
• Journal Information: Fuel, Vol. 61, Issue 8; ISSN 0016-2361
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
coal
hydrogenation
catalysts
catalysis