Flash photolysis-shock tube studies.

Conference · Thu Mar 05 00:00:00 EST 1998

OSTI ID:11024

Michael, J V

Following earlier investigations on the dissociation rates of halogen containing molecules, we studied the thermal decompositions of CHCl{sub 3} and CF{sub 3}Br. In addition, we measured the branching ratio and rate constants for the thermal decomposition of H{sub 2}CO. We studied three bimolecular rate processes: H + H{sub 2}CC0, CF{sub 3} + H{sub 2}, and H + CF{sub 3}H. Decomposition studies in reflected shock waves on three reactions were completed using atomic resonance absorption spectroscopic (ARAS) detection and/or the laser schlieren density gradient (LS) method.

• Research Organization: Argonne National Lab., IL (US)
• Sponsoring Organization: US Department of Energy (US)
• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 11024
• Report Number(s): ANL/CHM/CP-95779; TRN: AH200127%%559
• Resource Relation: Conference: 20th Annual Combustion Research Conference, Dallas, TX (US), 03/29/1998--04/03/1998; Other Information: PBD: 5 Mar 1998
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BRANCHING RATIO
DISSOCIATION
PYROLYSIS
CHLORINATED ALIPHATIC HYDROCARBONS
HALOGENATED ALIPHATIC HYDROCARBONS
FORMALDEHYDE
CHEMICAL REACTION KINETICS
HYDROGENATION