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Title: Oxy-Combustion Environmental Characterization: Fire- and Steam-Side Corrosion in Advanced Combustion

Conference ·
OSTI ID:1094990

Steamside Oxidation: A first high pressure test was completed, 293 hr at 267 bar and 670°C; A parallel 1 bar test was done for comparison; Mass gains were higher for all alloys at 267 bar than at 1 bar. A comparison was made with longer-term literature data: Ferritic steels--no consistent pressure effect; Austenitic steels--fine grain alloys less able to maintain protective chromia scale as pressure increases; Ni-base alloys--more mass gains above 105 bar than below. Not based on many data points. Fireside Corrosion: 1. Conditions for most severe corrosion: Temperature: 700{degrees}C Deposit: Standard Corrosion Mix Duration: 160 hours Gas Atmosphere: O{sub 2} + 1000ppm SO{sub 2} Pt-catalyst placed in the hot zone next to the specimens 2. Possible SO{sub 2} threshold in gas atmosphere for corrosion; 3. Corrosion greater in steel alloys than Ni-based alloys; 4. Corrosion mechanism proposed for steel alloys and Ni-based alloys.

Research Organization:
National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
OSTI ID:
1094990
Report Number(s):
NETL-PUB-708
Resource Relation:
Conference: 27th Annual Meeting on Fossil Energy Materials, Pittsburgh, PA, June 18-20, 2013.
Country of Publication:
United States
Language:
English

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