NMR and NQR study of the thermodynamically stable quasicrystals
- Iowa State Univ., Ames, IA (United States)
27Al and 61,65Cu NMR measurements are reported for powder samples of stable AlCuFe and AlCuRu icosahedral quasicrystals and their crystalline approximants, and for a AlPdMn single grain quasicrystal. Furthermore, 27Al NQR spectra at 4.2 K have been observed in the AlCuFe and AlCuRu samples. From the quadrupole perturbed NMR spectra at different magnetic fields, and from the zero field NQR spectra, a wide distribution of local electric field gradient (EFG) tensor components and principal axis system orientations was found at the Al site. A model EFG calculation based on a 1/1 AlCuFe approximant was successful in explaining the observed NQR spectra. It is concluded that the average local gradient is largely determined by the p-electron wave function at the Al site, while the width of the distribution is due to the lattice contribution to the EFG. Comparison of 63Cu NMR with 27Al NMR shows that the EFG distribution at the two sites is similar, but that the electronic contribution to the EFG is considerably smaller at the Cu site, in agreement with a more s-type wave function of the conduction electrons.
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 108133
- Report Number(s):
- IS-T-1731; ON: DE96000223; TRN: 95:007089
- Resource Relation:
- Other Information: TH: Thesis (Ph.D.); PBD: 10 Feb 1995
- Country of Publication:
- United States
- Language:
- English
Similar Records
Distribution of nonequivalent aluminum sites revealed in Al-Cu-Ru and Al-Cu-Fe quasicrystals by [sup 27]Al NQR
Investigation of structural information for boron-rich solids and aluminates via NMR and NQR studies