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Title: Advances in passive-remote and extractive Fourier transform infrared spectroscopic systems

Technical Report ·
DOI:https://doi.org/10.2172/10189290· OSTI ID:10189290

The Clean Air Act of 1990 requires the monitoring of air toxics including those from incinerator emissions. Continuous emission monitors (CEM) would demonstrate the safety of incinerators and address public concern about emissions of hazardous organic compounds. Fourier transform infrared (FTIR) spectroscopy can provide the technology for continuous emission monitoring of stacks. Stack effluent can be extracted and analyzed in less than one minute with conventional FTIR spectrometers. Passive-remote FTIR spectrometers can detect certain emission gases over 1 km away from a stack. The authors discuss advances in both extractive and passive-remote FTIR technology. Extractive systems are being tested with EPA protocols, which will soon replace periodic testing methods. Standard operating procedures for extractive systems are being developed and tested. Passive-remote FTIR spectrometers have the advantage of not requiring an extracted sample; however, they have less sensitivity. We have evaluated the ability of commercially available systems to detect fugitive plumes and to monitor carbon monoxide at a coal-fired power plant.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
10189290
Report Number(s):
ANL/CMT-ACL/CP-80970; CONF-9310197-1; ON: DE94001424; TRN: 94:000040
Resource Relation:
Conference: Air and Waste Management Association`s (AWMA) international specialty conference,Atlanta, GA (United States),11-14 Oct 1993; Other Information: PBD: [1993]
Country of Publication:
United States
Language:
English