The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994
Abstract
In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.
- Authors:
- Publication Date:
- Research Org.:
- South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry
- Sponsoring Org.:
- USDOE, Washington, DC (United States)
- OSTI Identifier:
- 10175474
- Report Number(s):
- DOE/ER/13296-10
ON: DE94017151; TRN: 94:007747
- DOE Contract Number:
- FG09-84ER13296
- Resource Type:
- Technical Report
- Resource Relation:
- Other Information: PBD: Jan 1994
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 14 SOLAR ENERGY; ORGANOMETALLIC COMPOUNDS; CHEMICAL REACTIONS; ENERGY STORAGE; OSMIUM COMPOUNDS; RHENIUM COMPOUNDS; ALKYNES; PROGRESS REPORT; TRANSITION ELEMENT COMPOUNDS; ORGANIC SULFUR COMPOUNDS; ULTRAVIOLET RADIATION; VISIBLE RADIATION; PHOTOCHEMISTRY; 400201; 140505; 400500; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES; PHOTOCHEMICAL, PHOTOBIOLOGICAL, AND THERMOCHEMICAL CONVERSION
Citation Formats
Adams, R D. The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994. United States: N. p., 1994.
Web. doi:10.2172/10175474.
Adams, R D. The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994. United States. https://doi.org/10.2172/10175474
Adams, R D. 1994.
"The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994". United States. https://doi.org/10.2172/10175474. https://www.osti.gov/servlets/purl/10175474.
@article{osti_10175474,
title = {The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994},
author = {Adams, R D},
abstractNote = {In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.},
doi = {10.2172/10175474},
url = {https://www.osti.gov/biblio/10175474},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 1994},
month = {Sat Jan 01 00:00:00 EST 1994}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.