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Title: The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994

Abstract

In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.

Authors:
Publication Date:
Research Org.:
South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry
Sponsoring Org.:
USDOE, Washington, DC (United States)
OSTI Identifier:
10175474
Report Number(s):
DOE/ER/13296-10
ON: DE94017151; TRN: 94:007747
DOE Contract Number:  
FG09-84ER13296
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: Jan 1994
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 14 SOLAR ENERGY; ORGANOMETALLIC COMPOUNDS; CHEMICAL REACTIONS; ENERGY STORAGE; OSMIUM COMPOUNDS; RHENIUM COMPOUNDS; ALKYNES; PROGRESS REPORT; TRANSITION ELEMENT COMPOUNDS; ORGANIC SULFUR COMPOUNDS; ULTRAVIOLET RADIATION; VISIBLE RADIATION; PHOTOCHEMISTRY; 400201; 140505; 400500; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES; PHOTOCHEMICAL, PHOTOBIOLOGICAL, AND THERMOCHEMICAL CONVERSION

Citation Formats

Adams, R D. The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994. United States: N. p., 1994. Web. doi:10.2172/10175474.
Adams, R D. The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994. United States. https://doi.org/10.2172/10175474
Adams, R D. 1994. "The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994". United States. https://doi.org/10.2172/10175474. https://www.osti.gov/servlets/purl/10175474.
@article{osti_10175474,
title = {The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994},
author = {Adams, R D},
abstractNote = {In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.},
doi = {10.2172/10175474},
url = {https://www.osti.gov/biblio/10175474}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 1994},
month = {Sat Jan 01 00:00:00 EST 1994}
}