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Title: Biodesulfurization of mild gasification liquid products. Technical report, December 1, 1992--February 28, 1993

Technical Report ·
DOI:https://doi.org/10.2172/10151073· OSTI ID:10151073
 [1];  [2]
  1. Institute of Gas Technology, Chicago, IL (United States)
  2. Illinois Clean Coal Inst., Carterville, IL (United States)

The mild gasification of coal, as being developed at IGT and elsewhere, is a promising new technology that can convert coal to multiple products: gas, solid, and liquids. Mild gasification liquids can be used as feedstock to make transportation fuels and chemicals. However, the sulfur content and aromaticity of mild gasification liquids limits their usefulness and biodesulfurization can potentially decrease both sulfur content and aromaticity. The objective of this project is to investigate the feasibility of using biodesulfurization to upgrade the quality of mild gasification liquids. During the current quarter a laboratory-scale mild gasification reactor was used to produce additional liquid derived from IBC-105 coal. The liquid has an organic sulfur content of 2.88%. The biocatalyst is apparently inhibited by chemical constituents in the light oil fraction of mild coal gasification liquids, but functions quite well in other liquid fractions or in unfractionated mild coal gasification liquid. Even when excess biocatalyst is used, approximately 12% of the organosulfur compounds appear to be recalcitrant to biodesulfurization. Biodesulfurization tests utilizing membrane fragments purified from IGTS8 and freeze-dried IGTS8 cell preparations added directly to mild coal gasification liquids have been performed. The processing and analysis of those samples is currently under way.

Research Organization:
Illinois Dept. of Energy and Natural Resources, Springfield, IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
FC22-92PC92521
OSTI ID:
10151073
Report Number(s):
DOE/PC/92521-T12; ON: DE93013631
Resource Relation:
Other Information: PBD: 1993
Country of Publication:
United States
Language:
English