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Title: Results of vitrifying Fernald OU-4 wastes

Conference ·
OSTI ID:10143466
 [1];  [2]
  1. Pacific Northwest Lab., Richland, WA (United States)
  2. Battelle Memorial Inst., Columbus, OH (United States)

Three silos in Operable Unit 4 (OU-4) at the Feed Materials Production Center in Fernald, Ohio, contain residues from the processing of pitchblende ores. Silos 1 and 2, designated as K-65, contain the depleted ore with a BentoGrout cap over the material to reduce radon emanation, while Silo 3 contains calcined residue from processing solutions. The residues in the three silos contain radium, uranium, uranium daughters, and heavy metals (primarily lead). Vitrification tests were carried out on various mixtures of the above materials and the resulting glasses were analyzed. The vitrified residues all tested ``non-hazardous`` by the Toxicity Characteristic Leachate Procedure (TCLP) and demonstrated a high degree of durability by the Product Consistency Test (PCT). The specific gravity and radon emanation of both the vitrified and non-vitrified residue were measured. Volume reductions ranging from 50 to 68 percent were obtained while the radon emanation rate was reduced by a factor of about 500,000. Radon emanation from the vitrified residue is of the same order of magnitude as emanation from natural building materials such as brick or concrete.

Research Organization:
Pacific Northwest Lab., Richland, WA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
10143466
Report Number(s):
PNL-SA-21856; CONF-930205-50; ON: DE93010167
Resource Relation:
Conference: Waste management `93,Tucson, AZ (United States),28 Feb - 4 Mar 1993; Other Information: PBD: Feb 1993
Country of Publication:
United States
Language:
English