Supported organometallic complexes, surface chemistry, spectroscopy, and catalysis. Progress report, September 15, 1992--November 14, 1993
Goal is to elucidate and understand the surface chemistry and catalytic properties of well-defined, highly-reactive organometallic molecules (principally based upon abundant actinide, lanthanide, and early transition elements) adsorbed on metal oxides and halides. Nature of adsorbed species is probed by a battery of chemical and physicochemical techniques, to understand the nature of the molecule-surface coordination chemistry and how this can give rise to extremely high catalytic activity. A complementary objective is to delineate the scope and mechanisms of the heterogeneous catalytic reactions, as well as to relate them both conceptually and functionally to model systems generated in solution.
- Research Organization:
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-86ER13511
- OSTI ID:
- 10141422
- Report Number(s):
- DOE/ER/13511-7; ON: DE93011930
- Resource Relation:
- Other Information: PBD: Apr 1993
- Country of Publication:
- United States
- Language:
- English
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