[Mechanistic examination of organometallic electron transfer reactions: Annual report, 1989]
Our mechanistic examination of electron transfer reactions between organometallic complexes has required data from our stopped-flow infrared spectrophotometer that was constructed in the first year. Our research on organometallic electron transfer reaction mechanisms was recognized by an invitation to the Symposium on Organometallic Reaction Mechanisms at the National ACS meeting in Miami. We have obtained a reasonable understanding of the electron transfer reactions between metal cations and anions and between metal carbonyl anions and metal carbonyl dimers. In addition we have begun to obtain data on the outer sphere electron transfer between metal carbonyl anions and coordination complexes and on reactions involving cluster anions.
- Research Organization:
- State Univ. of New York, Buffalo, NY (United States). Research Foundation
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-87ER13775
- OSTI ID:
- 10139447
- Report Number(s):
- DOE/ER/13775-T1; ON: DE92012538
- Resource Relation:
- Other Information: PBD: [1989]
- Country of Publication:
- United States
- Language:
- English
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