Probing flame chemistry with MBMS, theory, and modeling. Annual progress report, July 15, 1991--July 14, 1992
The program objective is to establish kinetics of combustion and molecular weight growth in C{sub 3} hydrocarbon flames as part of an ongoing study of flame chemistry. Specific reactions to be studies are (1) the oxidation reactions of O and OH with C{sub 3}`s and (2) the growth reactions of C{sub 3}H{sub 5} and C{sub 3}H{sub 3} with themselves and with unsaturated hydrocarbons. Our approach combines molecular-beam mass spectroscopy (MBMS) experiments which give concentrations of stable species and free radicals in low-pressure flat flames; theoretical predictions of rate constants by thermochemical kinetics, Biomedical Quantum-RRK, RRKM, and master- equation theory; and whole-flame modeling using full mechanisms of elementary reactions. Detailed MBMS flame data are the principal results of the first nine months of the grant. Spatial profiles of temperature, area expansion ratio, and mole fraction have been mapped in two low-pressure flat flames, one fuel-lean ({phi} = 0.229) and the other fuel-rich ({phi} = 1.64) in propene/oxygen/argon. Species identities and trends suggest certain chemical pathways, but reaction theory and flame modeling are beginning to provide specific, quantitative insights into oxidation and growth chemistry. 5 refs., 23 figs., 1 tab.
- Research Organization:
- Massachusetts Univ., Amherst, MA (United States). Dept. of Chemical Engineering
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-91ER14192
- OSTI ID:
- 10137201
- Report Number(s):
- DOE/ER/14192-1; ON: DE92011433
- Resource Relation:
- Other Information: PBD: Mar 1992
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
02 PETROLEUM
FLAMES
COMPUTERIZED SIMULATION
HYDROCARBONS
COMBUSTION KINETICS
MOLECULAR BEAMS
MASS SPECTROSCOPY
RADICALS
COMBUSTION PRODUCTS
REACTION INTERMEDIATES
PROGRESS REPORT
400800
025000
COMBUSTION, PYROLYSIS, AND HIGH-TEMPERATURE CHEMISTRY
COMBUSTION