Sorption and chemical transformation of PAHs on coal fly ash. Technical progress report No. 1, [October--December 1991]
The objective of this research is to characterize the interactions of coal fly ash with polycyclic aromatic hydrocarbons (PAHs) and their derivatives, and to understand the influence of the surface properties of coal ash (and other atmospheric particles) on the chemical transformations of polycyclic aromatic compounds. Studies to be carried out in this project include: (1) Fractionation of heterogeneous coal fly ash samples into different particle types varying in size and chemical composition (carbonaceous, mineral-magnetic, and mineral nonmagnetic); (2) Measurement of the rates of chemical transformation of PAHs and PAH derivatives (especially nitro-PAHs) and the manner in which the rates of such processes are influenced by the chemical and physical properties of coal fly ash particles; (3) Chromatographic and spectroscopic studies of the nature of the interactions of coal fly ash particles with PAHs and PAH derivatives; (4) Characterization of the fractal nature of fly ash particles (via surface area measurements) and the relationships of ``surface roughness`` of fly ash particles to the chemical behavior of PAHs sorbed on coal ash particles; (5) Identification of the major products of chemical transformation of PAHs on coal ash particles, and examination of any effects that may exist of the nature of the coal ash surface on the identities of PAH transformation products; and (6) Studies of the influence of other sorbed species on the chemical behavior of PAHs and PAH derivatives on fly ash surfaces. PAHs are deposited, under controlled laboratory conditions, onto coal ash surfaces from the vapor phase, in order to mimic the processes by which PAHs are deposited onto particulate matter in the atmosphere.
- Research Organization:
- Tennessee Univ., Knoxville, TN (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG22-91PC91306
- OSTI ID:
- 10131010
- Report Number(s):
- DOE/PC/91306-1; ON: DE92010028
- Resource Relation:
- Other Information: PBD: [1991]
- Country of Publication:
- United States
- Language:
- English
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